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101.
    
Aqueous Zn-Iodine (I2) batteries are attractive for large-scale energy storage. However, drawbacks include, Zn dendrites, hydrogen evolution reaction (HER), corrosion and, cathode “shuttle” of polyiodines. Here we report a class of N-containing heterocyclic compounds as organic pH buffers to obviate these. We evidence that addition of pyridine /imidazole regulates electrolyte pH, and inhibits HER and anode corrosion. In addition, pyridine and imidazole preferentially absorb on Zn metal, regulating non-dendritic Zn plating /stripping, and achieving a high Coulombic efficiency of 99.6 % and long-term cycling stability of 3200 h at 2 mA cm−2, 2 mAh cm−2. It is also confirmed that pyridine inhibits polyiodines shuttling and boosts conversion kinetics for I/I2. As a result, the Zn-I2 full battery exhibits long cycle stability of >25 000 cycles and high specific capacity of 105.5 mAh g−1 at 10 A g−1. We conclude organic pH buffer engineering is practical for dendrite-free and shuttle-free Zn-I2 batteries.  相似文献   
102.
A small array was obtained from three reactive cruciform fluorophores in six different solvents. The array discerned 10 different aromatic carboxylic acids by protonation-induced fluorescence shifts, which were recorded by digital photography. This simple array can discern acids that have closely spaced pK(a) values.  相似文献   
103.
We give a duality for the variety of bounded distributive lattices that is not full (and therefore not strong) although it is full but not strong at the finite level. While this does not give a complete solution to the “Full vs Strong” Problem, which dates back to the beginnings of natural duality theory in 1980, it does solve it at the finite level. One consequence of this result is that although there is a Duality Compactness Theorem, which says that if an alter ego of finite type yields a duality at the finite level then it yields a duality, there cannot be a corresponding Full Duality Compactness Theorem. Received October 1, 2002; accepted in final form November 10, 2004.  相似文献   
104.
Is every full duality strong? We show that the answer is ‘no’, thereby answering a question that goes back to the earliest foundations of the theory of natural dualities. Received July 3, 2006; accepted in final form September 8, 2006.  相似文献   
105.
The realm of natural dualities that are known to be full but not strong at the finite level is a very small one, consisting of a single example. This example, based on the three-element bounded distributive lattice, was presented by Davey, Haviar and Willard [8]. In this paper, we extend this realm to the class of all natural dualities based on a finite non-boolean bounded distributive lattice. Received June 15, 2005; accepted in final form November 26, 2005.  相似文献   
106.
We investigate ways in which certain binary homomorphisms of a finite algebra can guarantee its dualisability. Of particular interest are those binary homomorphisms which are lattice, flat-semilattice or group operations. We prove that a finite algebra which has a pair of lattice operations amongst its binary homomorphisms is dualisable. As an application of this result, we find that every finite unary algebra can be embedded into a dualisable algebra. We develop some general tools which we use to prove the dualisability of a large number of unary algebras. For example, we show that the endomorphisms of a finite cyclic group are the operations of a dualisable unary algebra.  相似文献   
107.
108.
Building on the most current work in the theory of natural dualities, we continue the study of strong dualities for the quasi-variety generated by a finite algebra. We investigate ten different versions of what we would like to mean by a good duality. Each version concerns, among other things, a specific restriction on the type of the structures in the dual category which insures that the dual structures will in a useful sense be simple. Through each investigation we seek a theorem characterizing, in terms of finitely verifiable conditions, those finite algebras generating a quasi-variety which admits a strong duality meeting the given restrictions. Our study includes a careful treatment of coproducts, logarithmic dualities and strong dualities by various unary structures.Dedicated to the memory of Alan DayPresented by J. Sichler.Research supported by a 1992 ARC Grant (Davey).  相似文献   
109.
    
A 1,4,7,10-tetraazacyclododecane (cyclen) variant bearing two thiosemicarbazone pendant groups has been prepared. The ligand forms complexes with Mn2+, Co2+ and Zn2+. X-ray crystallography of the Mn2+, Co2+ and Zn2+ complexes showed that the ligand provides a six-coordinate environment for the metal ions. The Mn2+ and Zn2+ complexes exist in the solid state as racemic mixtures of the Δ(δ,δ,δ,δ)/Λ(λ,λ,λ,λ) and Δ(λ,λ,λ,λ)/Λ(δ,δ,δ,δ) diastereomers, and the Co2+ complex exists as the Δ(δ,δ,δ,δ)/Λ(λ,λ,λ,λ) and Δ(λ,λ,λ,δ)/Λ(δ,δ,δ,λ) diastereomers. Density functional theory calculations indicated that the relative energies of the diastereomers are within 10 kJ mol−1. Magnetic susceptibility of the complexes indicated that both the Mn2+ and Co2+ ions are high spin. The ligand was radiolabelled with gallium-68, in the interest of developing new positron emission tomography imaging agents, which produced a single species in high radiochemical purity (>95%) at 90 °C for 10 min.  相似文献   
110.
We give an example of a five-element unary algebra which is entropic but does not admit a natural duality. Received September 26, 2000; accepted in final form April 4, 2001.  相似文献   
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