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71.
72.
Mixing small molecule gelators is a promising route to prepare useful and exciting materials that cannot be accessed from any of the individual components. Here, we describe pH-triggered hydrogelation by mixing of two non-gelling amphiphiles. The intermolecular interactions among the molecules can be tuned either by controlling the degree of ionization of the components or by a preparative pathway, which enables us to control material properties such as gel strength, gel stiffness, thermal stability, and an unusual shrinking/swelling behaviour.The properties of a charge complementary multicomponent gel can be tuned either by pH change or by varying the preparative pathway. 相似文献
73.
J. S. Dave George Kljrian A. P. Prajapati 《Molecular Crystals and Liquid Crystals》2013,570(1):385-389
Compounds containing naphthalene moiety are synthesized and the liquid crystalline properties studied by texture observations. The mesomorphic properties of these compounds are compared with related compounds to understand the influence of broad units such as naphthalene on mesomorphism. It is observed that there is a limit to which the end alkoxy group can be extended in a mesogen. The method of preparation, and properties of these compounds are given. 相似文献
74.
Shantanu Dave 《Monatshefte für Mathematik》2013,170(2):121-145
We consider distributions on a closed compact manifold $M$ as maps on smoothing operators. Thus spaces of maps between ${{\Psi }^{\!-\!\infty }}(M)$ and $\mathcal{C ^{\infty }}(M)$ are considered as generalized functions. For any collection of regularizing processes we produce various algebras of generalized functions and equivariant embeddings of distributions into such algebras. The regularity for such generalized functions is provided in terms of a certain tameness of maps between graded Frechét spaces. This also recovers the singularity behaviour of distributions (singular support/wavefront sets) in terms of certain subalgebras of the algebra of generalized functions. This notion of regularity is compared with the regularity in Colombeau algebras in the $\mathcal{G }^{\infty }$ sense. 相似文献
75.
Eric Shinn Alfred Hübler Dave Lyon Matthias Grosse Perdekamp Alexey Bezryadin Andrey Belkin 《Complexity》2013,18(3):24-27
The efficiency of conventional techniques used to harvest energy in nuclear reactors lies around 35%. This limit exists, because the nuclear energy is converted to electrical energy via heat engines. We study an alternative approach where the kinetic energy of nuclear reaction products is directly converted into electric energy in a stack of charged capacitors with a gap size of 500 nm and graphene electrodes. Graphene is expected to be chemically and mechanically stable in high‐radiation environments, because its tensile strength of 130 GPa is very large, about 100 times larger than most metals. The dielectric strength of such nanocapacitors exceeds 1 GV/m, because avalanching is suppressed at small gap sizes. In a 1 GV/m electric field charged nuclear reaction products, such as 5.6 MeV alpha particles, come to rest in of a stack with 5000 nanocapacitors. We show that during the deceleration process more than 90% of kinetic energy of charged nuclear reaction products is converted to electric energy and stored as electric energy in the stack. Each stack is 2.5‐mm thick and produces a high‐voltage DC current. A device with a 1‐Ci241Am source is expected to generate 22 mW of electric power. 相似文献
76.
Dave Anderson Mathieu Florence Zinovy Reichstein 《Comptes Rendus Mathematique》2013,351(23-24):871-875
Let G be a split simple group of type over a field k, and let be its Lie algebra. Answering a question of J.-L. Colliot-Thélène, B. Kunyavski?, V.L. Popov, and Z. Reichstein, we show that the function field is generated by algebraically independent elements over the field of adjoint invariants . 相似文献
77.
Hiroshi Shinotsuka Shigeo Tanuma Cedric J. Powell Dave R. Penn 《Surface and interface analysis : SIA》2019,51(4):427-457
We have calculated inelastic mean free paths (IMFPs) for 42 inorganic compounds (AgBr, AgCl, AgI, Al2O3, AlAs, AlN, AlSb, cubic BN, hexagonal BN, CdS, CdSe, CdTe, GaAs, GaN, GaP, GaSb, GaSe, InAs, InP, InSb, KBr, KCl, MgF2, MgO, NaCl, NbC0.712, NbC0.844, NbC0.93, PbS, PbSe, PbTe, SiC, SiO2, SnTe, TiC0.7, TiC0.95, VC0.76, VC0.86, Y3Al5O12, ZnS, ZnSe, and ZnTe) for electron energies from 50 eV to 200 keV. These calculations were made with energy-loss functions (ELFs) obtained from measured optical constants for 15 compounds while calculated ELFs were utilized for the other 27 compounds. Checks based on ELF sum rules showed that the calculated ELFs were superior to the measured ELFs that we had used previously. Our calculated IMFPs could be fitted to a modified form of the relativistic Bethe equation for inelastic scattering of electrons in matter for energies from 50 eV to 200 keV. The average root-mean-square (RMS) deviation in these fits was 0.60%. The IMFPs were also compared with a relativistic version of our predictive Tanuma-Powell-Penn (TPP-2M) equation. The average RMS deviation in these comparisons was 10.7% for energies between 50 eV and 200 keV. This average RMS deviation is almost the same as that found in a similar comparison for a group of 41 elemental solids (11.9%) although relatively large deviations were found for cubic BN (65.6%) and hexagonal BN (34.3%). If these two compounds are excluded in the comparisons, the average RMS deviation becomes 8.7%. We found generally satisfactory agreement between our calculated IMFPs and values from other calculations and from experiments. 相似文献
78.
O'Dell LA Gunawidjaja PN Holland MA Mountjoy G Pickup DM Newport RJ Smith ME 《Solid state nuclear magnetic resonance》2008,33(1-2):16-24
The HfO2-SiO2 system is attracting interest as a possible new dielectric material in semiconductor devices. Knowledge of the location of hafnium within the silica network and the effect hafnium has on the structure will be central to the successful use of this material system in this application. Here, sol-gel techniques have been used to manufacture (HfO2)x(SiO2)1-x samples (x=0.1, 0.2 and 0.4, each heat treated at 250, 500 and 750 degrees C) and these have been characterised by magic angle spinning (MAS) NMR (1H, 13C, 17 O, 29Si), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis. 29Si MAS NMR showed that increasing the hafnia content decreases the connectivity of the silicate network, i.e. increases the range of differently connected SiO4 (Qn) units with more having increased numbers of non-bridging oxygens (i.e. lower n). FTIR and 17 O MAS NMR showed unequivocally that the x=0.4 sample phase-separated at higher temperatures, while in the x=0.1 sample the hafnium was homogeneously mixed into the SiO2 phase without any phase separation. 相似文献
79.
Castricum HL Sah A Kreiter R Blank DH Vente JF ten Elshof JE 《Chemical communications (Cambridge, England)》2008,(9):1103-1105
Unprecedented hydrothermal stability in functional membranes has been obtained with hybrid organic-inorganic nanoporous materials, enabling long-term application in energy-efficient molecular separation, including dehydration up to at least 150 degrees C. 相似文献
80.
Efthymia Paparistodemou Richard Noss Dave Pratt 《International Journal of Computers for Mathematical Learning》2008,13(2):89-110
This article describes how children use an expressive microworld to articulate ideas about how to make a game seem fair with
the use of randomness. Our aim in this study is to disentangle different flavours of fairness and to find out how children
used each flavour to make sense of potentially complex behaviour. In order to achieve this, a spatial computer game was designed
to enable children to examine the consequences of their attempts to make the game fair. The study investigates how 23 children,
aged between 5.5 and 8 years, engaged in constructing a crucial part of a mechanism for a fair spatial lottery machine (microworld).
In particular, the children tried to construct a fair game given a situation in which the key elements happened randomly.
The children could select objects, determine their properties, and arrange their spatial layout in the machine. The study
is based on task-based interviewing of children who were interacting with the computer game. The study shows that children
have various cognitive resources for constructing a random fair environment. The spatial arrangement, the visualisation and
the manipulations in the lottery machine allow us gain a view into the children’s thinking of the two central concepts, fairness
and randomness. The paper reports on two main strategies by which the children attempted to achieve a balance in the lottery
machine. One involves arranging the balls symmetrically and the other randomly. We characterize the nature of the thinking
in these two strategies: the first we see as deterministic and the latter as stochastic, exploiting the random collisions
of the ball. In this article we trace how the children’s thinking moved between these two perspectives.
相似文献
Dave PrattEmail: |