全文获取类型
收费全文 | 1077篇 |
免费 | 26篇 |
国内免费 | 4篇 |
专业分类
化学 | 550篇 |
晶体学 | 26篇 |
力学 | 55篇 |
数学 | 109篇 |
物理学 | 367篇 |
出版年
2022年 | 14篇 |
2021年 | 14篇 |
2020年 | 12篇 |
2019年 | 11篇 |
2018年 | 13篇 |
2017年 | 17篇 |
2016年 | 32篇 |
2015年 | 15篇 |
2014年 | 22篇 |
2013年 | 60篇 |
2012年 | 47篇 |
2011年 | 60篇 |
2010年 | 45篇 |
2009年 | 41篇 |
2008年 | 65篇 |
2007年 | 45篇 |
2006年 | 58篇 |
2005年 | 46篇 |
2004年 | 32篇 |
2003年 | 26篇 |
2002年 | 25篇 |
2001年 | 19篇 |
2000年 | 23篇 |
1999年 | 14篇 |
1998年 | 10篇 |
1997年 | 13篇 |
1996年 | 14篇 |
1995年 | 19篇 |
1994年 | 20篇 |
1993年 | 28篇 |
1992年 | 24篇 |
1990年 | 7篇 |
1989年 | 12篇 |
1988年 | 9篇 |
1987年 | 10篇 |
1986年 | 5篇 |
1985年 | 10篇 |
1984年 | 13篇 |
1983年 | 8篇 |
1982年 | 9篇 |
1981年 | 10篇 |
1980年 | 14篇 |
1979年 | 10篇 |
1978年 | 10篇 |
1977年 | 6篇 |
1976年 | 7篇 |
1974年 | 6篇 |
1973年 | 6篇 |
1964年 | 5篇 |
1955年 | 5篇 |
排序方式: 共有1107条查询结果,搜索用时 15 毫秒
101.
An efficient and direct procedure for the synthesis of amidoalkyl-2-naphthol derivatives has been described. The process employs a three-component cyclocondensation reaction in one-pot using β-naphthol, aromatic aldehyde and acetamide or benzamide in the presence of silica chloride accelerated by ultrasound giving the product in excellent yield in very short duration. 相似文献
102.
D. Madhavi LathaV.G.K.M. Pisipati C. Rama Chandra PrabhuP.V. Datta Prasad 《Journal of Molecular Liquids》2011,164(3):187-190
The thermodynamic parameters like Moelwyn-Hughes parameter (C1), reduced molar volume (V~), isochoric temperature coefficient of internal pressure (X), Huggin's parameter (F), Gruneisen parameter (Γp), isothermal microscopic Gruneisen parameter, Sharma parameter (So), fraction free volume (f) and (A?) a dimensionless thermal parameter, etc and the Beyer's nonlinearity parameter (B/A) were deduced employing the thermal expansion coefficient derived from density data for the homologues series of compounds terephthalyidene-bis-p-n-alkyl anilines, TBnA with n = 5 to 10,12,14,16 and 18. Further, it is found that the variation of molecular radius, Mr increases with the increase of alkyl chain number, with a core radius of 4.78 Å and the increment for methylene unit is 0.086 Å . The results were discussed with the body of the data available. 相似文献
103.
D. Madhavi LathaV.G.K.M. Pisipati J. Lalitha KumariP.V. Datta Prasad 《Journal of Molecular Liquids》2011,163(1):14-19
Different thermodynamic parameters are estimated from volume expansion coefficient, α for a number of N-(p-n-alkoxybenzylidene)-p-n-butyloxyanilines, nO.O4 compounds in isotropic phase (at TIN + 5 °C) and in liquid crystalline phases. The variation of different thermodynamic parameters with the alkoxy chain length in nO.O4 series and their variation with the temperature in individual liquid crystal compounds are discussed. The parameters like available volume (Va), inter molecular free length (Lf) and molecular radius (Mr) are also computed from density, and refractive index for these nO.O4 compounds and the nature of molecular free length and molecular radius are analyzed and discussed. 相似文献
104.
105.
Amitava Datta 《Pramana》1993,40(6):L503-L509
It is argued with the help of an illustrative model, that the inter species hierarchy among the fermion masses and the quark
mixing angles can be accommodated naturally in the standard model with (approximate) flavor democracy provided there are three
exactly massless neutrinos and four families of sequential quark-leptons with all members of the fourth family having roughly
equal masses. The special problem of light neutrino masses (if any) and possible solutions are also discussed. 相似文献
106.
A temperature-dependent integrated kinetics for the overall process of photosynthesis in green plants is discussed. The C4 plants are chosen and in these plants, the rate of photosynthesis does not depend on the partial pressure of O2. Using some basic concepts like chemical equilibrium or steady state approximation, a simplified scheme is developed for
both light and dark reactions. The light reaction rate per reaction center (R′
1) in thylakoid membrane is related to the rate of exciton transfer between chlorophyll neighbours and an expression is formulated
for the light reaction rate R′
1. A relation between R′
1 and the NADPH formation rate is established. The relation takes care of the survival probability of the membrane. The CO2 saturation probability in bundle sheath is also taken into consideration. The photochemical efficiency (ϕ) is expressed in terms of these probabilities. The rate of glucose production is given by R
glucose = (8/3)(R′
1
v
L
)ϕ(T)
g
(T) ([G3P]/[P
i]2
leaf)SS
Q
G3P→glucose where g is the activity quotient of the involved enzymes, and G3P represent glycealdehyde-3-phosphate in steady state. A Gaussian
distribution for temperature-dependence and a sigmoid function for de-activation are incorporated through the quotient g. In general, the probabilities are given by sigmoid curves. The corresponding parameters can be easily determined. The theoretically
determined temperature-dependence of photochemical efficiency and glucose production rate agree well with the experimental
ones, thereby validating the formalism. 相似文献
107.
We demonstrate the method of averaging for conservative oscillators which may be strongly nonlinear, under small perturbations including delayed and/or fractional derivative terms. The unperturbed systems studied here include a harmonic oscillator, a strongly nonlinear oscillator with a cubic nonlinearity, as well as one with a nonanalytic nonlinearity. For the latter two cases, we use an approximate realization of the asymptotic method of averaging, based on harmonic balance. The averaged dynamics closely match the full numerical solutions in all cases, verifying the validity of the averaging procedure as well as the harmonic balance approximations therein. Moreover, interesting dynamics is uncovered in the strongly nonlinear case with small delayed terms, where arbitrarily many stable and unstable limit cycles can coexist, and infinitely many simultaneous saddle-node bifurcations can occur. 相似文献
108.
109.
Topochemical Transformations of CaX2 (X=C,Si, Ge) to Form Free‐Standing Two‐Dimensional Materials
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Saied Md. Pratik A. Nijamudheen Prof. Dr. Ayan Datta 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(50):18454-18460
Topochemical transformations of layered materials CaX2 (X=Si, Ge) are the method of choice for the high‐yield synthesis of pristine, defect‐free two‐dimensional systems silicane and germanane, which have advanced electronic properties. Based on solid‐state dispersion‐corrected calculations, mechanisms for such transformations are elucidated that provide an in‐depth understanding of phase transition in these layered materials. While formation of such layered materials is highly favorable for silicane and germanane, a barrier of 1.2 eV in the case of graphane precludes its synthesis from CaC2 topochemically. The energy penalty required for distorting linear acetylene into a trans‐bent geometry accounts for this barrier. In contrast it is highly favorable in the heavier analogues, resulting in barrierless topochemical generation of silicane and germanane. Photochemical generation of the trans‐bent structure of acetylene in its first excited state (S1) can directly generate graphane through a barrierless condensation. Unlike the buckled structure of silicene, the phase‐h of CaSi2 with perfectly planar silicene layers exhibits the Dirac cones at the high symmetry points K and H. Interestingly, topochemical acidification of the cubic phase of calcium carbide is predicted to generate the previously elusive platonic hydrocarbon, tetrahedrane. 相似文献
110.