Effect of poly(ethylene glycol) on the dielectric properties of poly(vinylidene fluoride)/BiFeO<Subscript>3</Subscript>/poly(ethylene glycol) composite films for electronic applications

In the present work a series of poly(vinylidene fluoride)/BiFeO₃/poly(ethylene glycol) composite films were prepared by solvent casting method with poly(vinylidene fluoride) as polymer matrix, bismuth ferrite as ceramic filler and poly(ethylene glycol) as binding agent as well as enhancer. The structural analysis of the composite films by X-ray diffraction confirms that the composites have a distorted rhombohedral structure. The micro-structural analysis shows that the use of poly(ethylene glycol)in the composite films enhances the homogeneity as well as compatibility of BiFeO₃ particles within the poly(vinylidene fluoride) matrix. The dielectric and electrical study done by impedance analyzer reveals that with an increase in poly(ethylene glycol) concentration, there is a subsequent increase in dielectric constant as well as AC electrical conductivity. Finally, the ferroelectric behavior of the composite confirms that the ferroelectric properties of the composites are enhanced by the addition of BiFeO₃ with an increase in poly(ethylene glycol) concentrations. These preliminary results give an idea for possible applications of this type of composites in the field of electronic applications.     

Effect of solvent on reactions of coordination complexes. Part 12: Kinetics and mechanism of chloride substitution reactions ofcis-(chloro)(2-aminoethanol)bis(ethylenediamine) cobalt(III) andcis-(chloro)(1-aminopropan-2-ol)-bis(ethylenediamine) cobalt(III) ions in acidic and basic ethylene glycol-water media

Summary The loss of chloride ion from the title complexes resulted in the predominant formation of the chelated amino-alcohol productscis-[Co(en)₂(NH₂CH₂CH(X)O/H)]^2+/3+ (X=H or Me). The kinetics of chloride release were investigated in aqueous ethylene glycol (EG) media (0 to 80% by wt of EG) at 40°–65°C in acidic media and at 20°–35°C in basic media. The rate constants decreased linearly with increasing mol fraction of the cosolvent. The plots of log kversus D _s ^–1 (S_s=bulk dielectric constant, k=first order or second order rate constants) were essentially linear with negative slopes for the reactions in an acidic medium, and tended to be curved for the base catalysed reactions. The activation enthalpies and entropiesversus X_EG (X_EG=mol fraction of EG) plots indicated extrema which might be associated with the effects of the solvent structural changes on these thermodynamic parameters. The observed solvent isotope effect at 50°C, [HClO₄]=0.010 mol dm^–3 for Cl^– release was lower than the value for the aquation ofcis-[Co(en)₂(alkylamine)Cl]²⁺ complexes reported in the literature. This is consistent with the lack of direct solvent molecule participation in the actual act of substitution at the cobalt(III) centre, as expected for a true intramolecular reaction.Part-11: A. C. Dash and J. Pradhan,Ind. J. Chem.,29A, 167 (1990).     

Dielectric response of methyl isobutyl ketone (MIBK) in apolar solvents: solute-solvent interactions

Dielectric constants of binary mixtures of MIBK, an extractant used in nuclear energy industry, with six apolar solvents i.e. benzene, dioxane, cyclohexane, carbon tetrachloride, p-xylene and n-heptane have been measured at 455 kHz. The data are used to evaluate the Eyring’s structural parameter, G*, in these systems to assess the nature of non-specific solute-solvent interaction. The value of G* is found to be influenced by the nature of the solvent.     

Synergistic use of Knudsen effusion quadrupole mass spectrometry, solid-state galvanic cell and differential scanning calorimetry for thermodynamic studies on lithium aluminates

Three ternary oxides LiAl₅O₈(s), LiAlO₂(s) and Li₅AlO₄(s) in the system Li-Al-O were prepared by solid-state reaction route and characterized by X-ray powder diffraction method. Equilibrium partial pressure of CO₂(g) over the three-phase mixtures {LiAl₅O₈(s)+Li₂CO₃(s)+5Al₂O₃(s)}, {LiAl₅O₈(s)+5LiAlO₂(s)+2Li₂CO₃(s)} and {LiAlO₂(s)+Li₅AlO₄(s)+2Li₂CO₃(s)} were measured using Knudsen effusion quadrupole mass spectrometry (KEQMS). Solid-state galvanic cell technique based on calcium fluoride electrolyte was used to determine the standard molar Gibbs energies of formations of these aluminates. The standard molar Gibbs energies of formation of these three aluminates calculated from KEQMS and galvanic cell measurements were in good agreement. Heat capacities of individual ternary oxides were measured from 127 to 868 K using differential scanning calorimetry. Thermodynamic tables representing the values of Δ_fH⁰(298.15 K), S⁰(298.15 K) S⁰(T), C_p⁰(T), H⁰(T), {H⁰(T)-H⁰(298.15 K)}, G⁰(T), Δ_fH⁰(T), Δ_fG⁰(T) and free energy function (fef) were constructed using second law analysis and FACTSAGE thermo-chemical database software.     

Effect of Chemical reaction on MHD flow of a visco-elastic fluid through porous medium.

The effect of heat and mass transfer on free convective flow of a visco-elastic incompressible electrically conducting fluid past a vertical porous plate through a porous medium with time dependant oscillatory permeability and suction in the presence of a uniform transverse magnetic field, heat source and chemical reaction has been studied in this paper. The novelty of the present study is to analyze the effect of chemical reaction, time dependant fluctuative suction and permeability of the medium on a visco-elastic fluid flow. It is interesting to note that presence of sink contributes to oscillatory motion leading to flow instability. Further it is remarked that presence of heat source and low rate of thermal diffusion counteract each other in the presence of reacting species.     

Supply chain DEA: production possibility set and performance evaluation model

Performance evaluation is of great importance for effective supply chain management. The foundation of efficiency evaluation is to faithfully identify the corresponding production possibility set. Although a lot of researches have been done on supply chain DEA models, the exact definition for supply chain production possibility set is still in absence. This paper defines two types of supply chain production possibility sets, which are proved to be equivalent to each other. Based upon the production possibility set, a supply chain CRS DEA model is advanced to appraise the overall technical efficiency of supply chains. The major advantage of the model lies on the fact that it can help to find out the most efficient production abilities in supply chains, by replacing or improving inefficient subsystems (supply chain members). The proposed model also directly identifies the benchmarking units for inefficient supply chains to improve their performance. A real case validates the reasonableness and acceptability of this approach.     

A note on the MIR closure and basic relaxations of polyhedra

Anderson et al. (2005) [1] show that for a polyhedral mixed integer set defined by a constraint system Ax≥b, along with integrality restrictions on some of the variables, any split cut is in fact a split cut for a basic relaxation, i.e., one defined by a subset of linearly independent constraints. This result implies that any split cut can be obtained as an intersection cut. Equivalence between split cuts obtained from simple disjunctions of the form x_j≤0 or x_j≥1 and intersection cuts was shown earlier for 0/1-mixed integer sets by Balas and Perregaard (2002) [4]. We give a short proof of the result of Anderson, Cornuéjols and Li using the equivalence between mixed integer rounding (MIR) cuts and split cuts.     

Convergence in mean of some random Fourier series

For a symmetric stable process X(t,ω) with index α∈(1,2], f∈Lp[0,2π], p?α, and , we establish that the random Fourier-Stieltjes (RFS) series converges in the mean to the stochastic integral , where fβ is the fractional integral of order β of the function f for . Further it is proved that the RFS series is Abel summable to . Also we define fractional derivative of the sum of order β for an, An(ω) as above and . We have shown that the formal fractional derivative of the series of order β exists in the sense of mean.     

A new solution method for fuzzy chance constrained programming problem

This paper deals with an optimization model, where both fuzziness and randomness occur under one roof. The concept of fuzzy random variable (FRV), mean and variance of FRV is used in the model. In particular, the methodology is developed in the presence of FRV in the constraint. The methodology is verified through numerical examples.