On the low-temperature properties of

Magnetic, electrical transport and heat capacity measurements have been performed on polycrystalline sample of the compound TmRu₂Si₂, which crystallizes with the tetragonal ThCr₂Si₂-type crystal structure. The results show paramagnetic behaviour down to 0.3 K, at variance with the literature data. On the basis of the collected data, possible origins of non-magnetic behaviour are discussed. Mixed valence of Tm ions or hybridisation between Tm 4f and Ru 4d states are the most probable reasons for paramagnetic behaviour of the TmRu₂Si₂.     

Insight into the Folding and Cooperative Multi-Recognition Mechanism in Supramolecular Anion-Binding Catalysis

H-bond donor catalysts able to modulate the reactivity of ionic substrates for asymmetric reactions have gained great attention in the past years, leading to the development of cooperative multidentate H-bonding supramolecular structures. However, there is still a lack of understanding of the forces driving the ion recognition and catalytic performance of these systems. Herein, insight into the cooperativity nature, anion binding strength, and folding mechanism of a model chiral triazole catalyst is presented. Our combined experimental and computational study revealed that multi-interaction catalysts exhibiting weak binding energies (≈3–4 kcal mol⁻¹) can effectively recognize ionic substrates and induce chirality, while strong dependencies on the temperature and solvent were quantified. These results are key for the future design of catalysts with optimal anion binding strength and catalytic activity in target reactions.     

Geometrical,electrical, and energetic parameters of hetero-disubstituted cumulenes and polyynes in the presence and absence of the external electric field

Structural Chemistry - Cumulenes and polyynes have the potential to be applied as linear, sp-hybridized, one-dimensional all-carbon nanowires in molecular electronics and optoelectronics. The...     

Clinical Trials and Basic Research in Photodynamic Diagnostics and Therapies from the Center for Laser Diagnostics and Therapy in Poland

The purpose of this review is to present an overview of the development of photodiagnostic and photodynamic therapy (PDD and PDT) techniques in Poland. The paper discusses the principles of PDD, including fluorescent techniques in determining precancerous conditions and cancers of the skin, digestive tract, bladder and respiratory tract. Methods of PDT of cancer will be discussed and the current state of knowledge as well as future trends in the development of photodynamic techniques will be presented, including the possibility of using photodynamic antimicrobial therapy. Research pioneers in photodynamic medicine such as Thomas Dougherty are an inspiration for the development of methods of PDD and PDT in our Clinic. The Center for Laser Diagnostics and Therapy in Bytom, Poland, promotes the propagation of PDD and PDT through the training of clinicians and raising awareness among students in training and the general public. Physicians at the Center are engaged in photomedical research aimed at clinical implementation and exploration of new avenues in photomedicine while optimizing existing modalities. The Center promotes dissemination of clinical results from a wide range of topics in PDD and PDT and serving as representative authorities of photodynamic medicine in Poland and Europe.     

On the fundamental theorem of algebra for polynomial equations over real composition algebras

A topological proof is given that real compositions algebras of finite dimension greater than one are algebraically closed under polynomial equations with a tame tail.     

On unstable and unoptimal prediction

We consider the notion of prediction functions (or predictors) studied before in the context of randomness and stochasticity by Ko, and later by Ambos‐Spies and others. Predictor is a total computable function which tries to predict bits of some infinite binary sequence. The prediction error is defined as the limit of the number of incorrect answers divided by the number of answers given so far. We discuss indefiniteness of prediction errors for weak 1‐generics and show that this phenomenon affects certain c.e. sequences as well. On the other hand, a notion of optimal predictor is considered. It is shown that there is a sequence for which increasingly better predictors exist but for which no predictor is optimal.     

On quadratic bond-order decomposition within molecular orbital space

A simple method of analysing and localization of canonical molecular orbitals for particular chemical bond using the MO-resolved bond-order decomposition scheme is presented. An alternative definition of classical bond order orbitals is provided and links to communication theory of the chemical bond are outlined and briefly discussed. The introduced procedure of decomposition of quadratic bond orders allows one to analyse two- as well as three- center chemical bonds within the framework of the same theory.     

Modified PZT ceramics as a material that can be used in micromechatronics

Results on investigations of the PZT type ceramics with the following chemical composition: Pb_0.94Sr_0.06(Zr_0.50 Ti_0.50)_0.99 Cr_0.01O₃ (PSZTC) which belongs to a group of multicomponent ceramic materials obtained on basis of the PZT type solid solution, are presented in this work. Ceramics PSZTC was obtained by a free sintering method under the following conditions: T _sint = 1250 °C and t _sint = 2 h. Ceramic compacts of specimens for the sintering process were made from the ceramic mass consisting of a mixture of the synthesized PSZTC powder and 3% polyvinyl alcohol while wet. The PSZTC ceramic specimens were subjected to poling by two methods: low temperature and high temperature. On the basis of the examinations made it has been found that the ceramics obtained belongs to ferroelectric-hard materials and that is why it may be used to build resonators, filters and ultrasonic transducers.