Reinvestigation of the OP4-(Li/Na)CoO2-layered system and first evidence of the (Li/Na/Na)CoO2 phase with OPP9 oxygen stacking

The composition and synthesis conditions of the (Li/Na)CoO(2) phase with an ordered 1:1 Li/Na stacking alternating with CoO(2) slabs were determined from a careful study of the P2-Na(～0.7)CoO(2)-O3-LiCoO(2) system. An in situ X-ray diffraction (XRD) thermal study emphasizes the metastable character of this phase that can be stabilized only by very fast quenching. Its composition, (Li(0.42)Na(0.37))CoO(2), is significantly different from the ideally expected one, (Li(0.50)Na(0.35))CoO(2), and its structure, confirmed by Rietveld refinement of the XRD pattern, presents an ideal alternate ordering of lithium, cobalt, and sodium layers within OP4-type oxygen packing. The presence of vacancies in both alkali-ion layers was confirmed by electrochemical intercalation of lithium and sodium. For the first time, a new type of layered oxide exhibiting OPP9-type oxygen packing was evidenced. Between the CoO(2) slabs, alkali ions are intercalated in the following order: Li(octa)-Na(prism)-Na(prism). This material crystallizes in the R3m space group with a(hex) = 2.828 ? and c(hex) = 46.85 ? cell parameters.     

Spectres de photoelectrons des alcynes

The ultraviolet photoelectron spectra (UPS) of 11 monosubstituted and 25 disubstituted aliphatic alkynes have been recorded using He(I) radiation. The inductive effects of 15 saturated alkyl substituents on the first ionisation potential (emission of a photoelectron from a π orbital of the triple bond) were studied, and correlated with Taft's polar constants (σ*). An attribution of the second ionisation potential has been proposed, which accords with previous experimental results on both alkenes and carbonyl compounds. Some vibrational frequencies of molecular ions have been determined for the least-branched 15 alkynes.     

Polarographie radiochimique des solutions acides de TeIV

With ¹²¹Te (T_1/2=17 days) radiochemical polarography of [Te^IV]≤10^?9M is possible with negligible surface coverage. Deposition of Te is diffusion controlled. The potential range of Te⁰ formation is limited at negative potential by its reduction to HTe^?.     

An optimization-based heuristic for the robotic cell problem

This study investigates an optimization-based heuristic for the robotic cell problem. This problem arises in automated cells and is a complex flow shop problem with a single transportation robot and a blocking constraint. We propose an approximate decomposition algorithm. The proposed approach breaks the problem into two scheduling problems that are solved sequentially: a flow shop problem with additional constraints (blocking and transportation times) and a single machine problem with precedence constraints, time lags, and setup times. For each of these problems, we propose an exact branch-and-bound algorithm. Also, we describe a genetic algorithm that includes, as a mutation operator, a local search procedure. We report the results of a computational study that provides evidence that the proposed optimization-based approach delivers high-quality solutions and consistently outperforms the genetic algorithm. However, the genetic algorithm delivers reasonably good solutions while requiring significantly shorter CPU times.     

Antioxidant Activity of Bioactive Peptide Fractions from Germinated Soybeans Conjugated to Fe3O4 Nanoparticles by the Ugi Multicomponent Reaction

The conjugation of biomolecules to magnetic nanoparticles has emerged as promising approach in biomedicine as the treatment of several diseases, such as cancer. In this study, conjugation of bioactive peptide fractions from germinated soybeans to magnetite nanoparticles was achieved. Different fractions of germinated soybean peptides (>10 kDa and 5–10 kDa) were for the first time conjugated to previously coated magnetite nanoparticles (with 3-aminopropyltriethoxysilane (APTES) and sodium citrate) by the Ugi four-component reaction. The crystallinity of the nanoparticles was corroborated by X-ray diffraction, while the particle size was determined by scanning transmission electron microscopy. The analyses were carried out using infrared and ultraviolet–visible spectroscopy, dynamic light scattering, and thermogravimetry, which confirmed the coating and functionalization of the magnetite nanoparticles and conjugation of different peptide fractions on their surfaces. The antioxidant activity of the conjugates was determined by the reducing power and hydroxyl radical scavenging activity. The nanoparticles synthesized represent promising materials, as they have found applications in bionanotechnology for enhanced treatment of diseases, such as cancer, due to a higher antioxidant capacity than that of fractions without conjugation. The highest antioxidant capacity was observed for a >10 kDa peptide fraction conjugated to the magnetite nanoparticles coated with APTES.     

The project scheduling problem with production and consumption of resources: A list-scheduling based algorithm

The paper deals with algorithms for applying classical list scheduling to a project scheduling problem where the units of resources are produced or consumed at the occurrence of precedence-related events. It is shown that the feasibility variant of the project scheduling problem is NP-complete. Moreover, polynomial-time scheduling algorithms are devised for the three cases where the occurrence time sequence of all events or the consuming events or the producing events is given in advance. By enumerating these sequences (called linear orders), one obtains a list-scheduling based algorithm for minimizing the makespan of a project scheduling problem with production and consumption of resources.     

TCF selenium preconcentration in geological materials for determination at sub-mugg(-1) with INAA (Se/TCF-INAA)

In geological samples, Se concentration ranges from 1 × 10⁻⁹ g g⁻¹ up to 1 × 10⁻³ g g⁻¹. The analytical difficulty at low concentration (<1 μg g⁻¹), is one of the main reasons why the geological cycle of Se is poorly known. The analytical method that consisted of preconcentration of Se with thiol cotton fiber (TCF) followed by graphite furnace atomic absorption spectrometry (GFAAS) has been modified by finishing with instrumental neutron activation analysis (INAA). The modified technique involves sample dissolution (HF-HNO₃-H₂O₂) and evaporation to dryness at low temperature (55-60 °C) to avoid selenium volatilization. Se^VI is converted to Se^IV by adding 6 M HCl to the dry residuum and the solution is then heated in a covered boiling bath (95-100 °C). The solution is diluted to obtain 0.6 M HCl and then collected on TCF. The TCF is placed in a polyethylene vial for irradiation in the SLOWPOKE II reactor (Montréal) for 30 s at a neutron flux of 10¹⁵ m⁻² s⁻¹. The 162 keV peak of ^77mSe (half-life 17.36 s) is read for 20 s after a decay of 7 s. The amount of sample to be dissolved is controlled by two competing effects. To obtain low detection limits, a larger amount of sample should be dissolved. On the other hand, the TCF could become saturated with chalcophile elements when large sample is used. Sulfur is a good indicator of the amount of Se and chalcophile elements present. In S poor sample (<100 μg g⁻¹) 3.0 g of sample was used and the L_D was ∼2 ng g⁻¹. In S high samples (>1.5% S) 0.05 g of sample was used and the L_D was ∼120 ng g⁻¹. The present work also includes suggested Se concentration for eight international geological reference materials (IGRM) that compare favorably with literature values.