全文获取类型
收费全文 | 1876篇 |
免费 | 372篇 |
国内免费 | 288篇 |
专业分类
化学 | 1402篇 |
晶体学 | 68篇 |
力学 | 64篇 |
综合类 | 15篇 |
数学 | 270篇 |
物理学 | 717篇 |
出版年
2024年 | 8篇 |
2023年 | 63篇 |
2022年 | 68篇 |
2021年 | 98篇 |
2020年 | 105篇 |
2019年 | 108篇 |
2018年 | 92篇 |
2017年 | 88篇 |
2016年 | 109篇 |
2015年 | 120篇 |
2014年 | 140篇 |
2013年 | 173篇 |
2012年 | 198篇 |
2011年 | 200篇 |
2010年 | 108篇 |
2009年 | 117篇 |
2008年 | 130篇 |
2007年 | 111篇 |
2006年 | 80篇 |
2005年 | 66篇 |
2004年 | 65篇 |
2003年 | 35篇 |
2002年 | 42篇 |
2001年 | 31篇 |
2000年 | 33篇 |
1999年 | 27篇 |
1998年 | 12篇 |
1997年 | 20篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 8篇 |
1993年 | 8篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1988年 | 1篇 |
1987年 | 8篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1971年 | 2篇 |
排序方式: 共有2536条查询结果,搜索用时 15 毫秒
141.
Heuristic algorithms for a vehicle routing problem with simultaneous delivery and pickup and time windows in home health care 总被引:1,自引:0,他引:1
This paper addresses a vehicle scheduling problem encountered in home health care logistics. It concerns the delivery of drugs and medical devices from the home care company’s pharmacy to patients’ homes, delivery of special drugs from a hospital to patients, pickup of bio samples and unused drugs and medical devices from patients. The problem can be considered as a special vehicle routing problem with simultaneous delivery and pickup and time windows, with four types of demands: delivery from depot to patient, delivery from a hospital to patient, pickup from a patient to depot and pickup from a patient to a medical lab. Each patient is visited by one vehicle and each vehicle visits each node at most once. Patients are associated with time windows and vehicles with capacity. Two mixed-integer programming models are proposed. We then propose a Genetic Algorithm (GA) and a Tabu Search (TS) method. The GA is based on a permutation chromosome, a split procedure and local search. The TS is based on route assignment attributes of patients, an augmented cost function, route re-optimization, and attribute-based aspiration levels. These approaches are tested on test instances derived from existing VRPTW benchmarks. 相似文献
142.
本文给出了一类退缩的拟线性椭圆型方程-Div「↓u|^p-2↓u+F(x,u)」=B(x,u,↓u)在W^1,p(Ω)中弱解的C^1,λloc(Ω)正则性,其中Ω为R^N中行一区域。 相似文献
143.
作为一种有可能作为永久信息存储的材料,合成出一种新的双偶氮材料(BA1)。当样品被波长为532nm的光激发时,几乎大部分BA1分子从反-反态转化到顺-顺态,产生了光致双折射。因此,研究了BA1分子掺杂的PMMA薄膜的光致双折射和透过信号与入射光强度的关系。实验结果表明:透过信号强度随着泵浦光的增强而增强。通过偏振态互相平行(SS)和垂直(SP)的两束偏振光用来研究偏振全息存储,结果表明SP光栅形成的衍射信号要比SS光栅的衍射信号强很多。 相似文献
144.
Peng Xi Yuqing Duan Pengfei Fei Lei Xia Ran Liu Bowen Cheng 《European Polymer Journal》2012,48(7):1295-1303
Based on the phase change theory, a novel tetrahydroxy compound (THCD) was designed and prepared. Depending on the spatial structure of the tetrahydroxy compound, a form-stable thermoplastic polyurethane solid–solid phase change material (TPUPCM) was synthesized via employing PEG as soft segments, while multi-benzene ring structure made by 4,4′-diphenylmethane diisocyanate and tetrahydroxy compound as hard segments. The composition and structure of THCD and TPUPCM, the TPUPCM’s the weight average molecular weight and number average molecular weight, dissolving and melting abilities, phase change behaviors, thermal performances and crystalline morphology were investigated by Fourier transform infrared spectrometer, 1H nuclear magnetic resonance spectrometer, multiangle laser light scattering apparatus, differential scanning calorimentry, dynamic mechanical thermal analysis, thermogravimetry analysis system, wide-angle X-ray diffraction, polarizing optical microscopy. The results show that the solid–solid phase change material owns excellent phase change properties and a broad processing temperature range. The heating cycle phase change enthalpy is 137.4 J/g, and the cooling cycle phase change enthalpy is 127.6 J/g. The started decomposition temperature and the maximum decomposition temperature are at 323.5 and 396.2 °C, respectively. Furthermore, the solid–solid phase change material is dissolvable, meltable and can be processed directly, and has great potential applications in thermal energy storage. 相似文献
145.
The nonisothermal decomposition kinetics of Ginkgo biloba leaves polyprenol (GBP) and cleaved situation of its chemical bond during thermal decomposition process were first investigated using thermogravimetric (TG) and TG‐FTIR technology. The results of thermal decomposition kinetics revealed that the nonisothermal decomposition mechanism of GBP corresponds to first‐order chemical reaction with n = 1, integral form g(a) = –ln(1 – a) and differential form f(a) = 1 – a. TG‐FTIR results demonstrated that absorbance of –CH3, unsaturated C–H bond, =CH2, accumulated C=C, –OH, and so on constantly increased with thermal decomposition reaction went on. In addition, storage life of GBP was also evaluated. These data could provide theoretical guidance for purification under high temperature and other thermal application of GBP. 相似文献
146.
Self‐Assembly and Compartmentalization of Nanozymes in Mesoporous Silica‐Based Nanoreactors 下载免费PDF全文
Yanyan Huang Dr. Youhui Lin Xiang Ran Prof. Dr. Jinsong Ren Prof. Dr. Xiaogang Qu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(16):5705-5711
Herein, to mimic complex natural system, polyelectrolyte multilayer (PEM)‐coated mesoporous silica nanoreactors were used to compartmentalize two different artificial enzymes. PEMs coated on the surface of mesoporous silica could serve as a permeable membrane to control the flow of molecules. When assembling hemin on the surface of mesoporous silica, the hemin‐based mesoporous silica system possessed remarkable peroxidase‐like activity, especially at physiological pH, and could be recycled more easily than traditional graphene–hemin nanocompounds. The hope is that these new findings may pave the way for exploring novel nanoreactors to achieve compartmentalization of nanozymes and applying artificial cascade catalytic systems to mimic cell organelles or important biochemical transformations 相似文献
147.
Jincheng Mao Ran Li Yue He Xiaojiang Yang Dingli Wang Yang Zhang 《Russian Journal of Applied Chemistry》2016,89(4):663-669
We reported a highly effective Pd-catalytic system for the synthesis of diarylbenzenes through Suzuki-type reaction between equal amount of diiodoarenes and arylboronic acids. This preferential oxidative addition resulted in such high selectivity. 相似文献
148.
149.
Topological Aspects in an Interacting Mixture of a Charged and a Neutral Superfluid in Neutron Stars 下载免费PDF全文
By making use of the decomposition of U(1) gauge potential theory and the C-mapping method we discuss a mixture of interacting neutral and charged Bose condensates, which is supposed to be realized in the interior of neutron stars in the form of a coexistent neutron superfluid and protonie superconductor. We propose that this system possesses vortex line knotted solitons and the topological charges of vortex lines are characterized by the winding numbers of the C-mapping. Furthermore the spatial bifurcation of vortices is also discussed. 相似文献
150.
利用激光干涉测速技术(VISAR)测量LY12铝合金在20—34 GPa冲击压力下经历加载-卸载和加载-再加载过程的样品/窗口界面粒子速度剖面,采用AC方法确定了具有较高精度的动态屈服强度值.实验结果和文献发表的数据具有较好的一致性.通过以平面焊接方式制作组合飞片,克服了组合飞片在气炮发射过程中可能发生分离的技术困难,使铝的动态屈服强度测量压力范围从22 GPa扩展到了34 GPa.同时,根据对不同实验条件下的加载-再加载过程的比较,对再加载弹性前驱波的形成机理进行了讨论,认为位错是形成该现象的主要原因. 相似文献