[H_2N(C_2H_4)_2NH_2]_4(H_3O)[PMo_2~VMo_6~(VI)V_4~(IV)O_(40)(V~(IV)O)_2]·H_2O: A New Highly Reduced, Bicapped Pseudo-Keggin Vanadylpolymolybdophosphate

Ｐｏｌｙｏｘｏｍｅｔａｌａｔｅｓ (ＰＯＭｓ)ｃｏｎｔａｉｎｉｎｇＫｅｇｇｉｎｍｏｉ ｅｔｉｅｓｈａｖｅｂｅｅｎｒｅｃｅｉｖｉｎｇｅｘｔｅｎｓｉｖｅａｔｔｅｎｔｉｏｎｉｎｒｅｃｅｎｔｙｅａｒｓｏｗｉｎｇｔｏｔｈｅｉｒｇｒｅａｔｆｕｎｄａｍｅｎｔａｌａｎｄｐｒａｃｔｉｃａｌｉｎｔｅｒ ｅｓｔ .1Ｅｓｐｅｃｉａｌｌｙｔｈｅｕｎｕｓｕａｌｅｌｅｃｔｒｏｎｉｃｐｒｏｐｅｒｔｙ (ｈｉｇｈｎｅｇａｔｉｖｅｃｈａｒｇｅｓ) ,ｏｎｅｏｆｔｈｅｍｏｓｔｉｍｐｏｒｔａｎｔｐｒｏｐｅｒｔｉｅｓｏｆＰＯＭｓ ,ｈａｓｐｏｔｅｎ…     

Yb3+/Er3+共掺(MLaFn)x(M=0,K;n=3,4;x=1,1.5)纳米材料的控制合成及其上转换发光性质

采用水热与溶剂热结合的方法,在乙二醇-正己醇体系中,通过调节KF与RE(RE=La,Yb,Er)的量比、反应温度和反应时间实现了由LaF_3(六角相)到KLaF_4(立方相、六角相)晶型的控制合成。借助透射电子显微镜(TEM)和X射线粉末衍射(XRD)对样品的结构和微观形貌进行表征。结果表明,当KF/RE比例为2. 25时,制备的样品为片状的六角相LaF_3纳米颗粒;当KF/RE比例为3. 00时,得到具有近似球形的立方相KLaF_4纳米颗粒;当KF/RE比例为4. 25时,得到了六角相(KLaF_4)_(1. 5)纳米颗粒。上转换发射光谱显示:所有的样品在近红外光(980 nm)激发下,均有3个明显的发射峰,在522 nm、544 nm处分别对应于Er~(3+)的~4S_(3/2),~2H_(11/2)→~4I_(15/2)能级跃迁,655 nm处属于Er~(3+)的~4F_(9/2)→~4I_(15/2)能级跃迁。     

The onset of thermal runaway in partially insulated or cooled reactors

The conditions for the onset of thermal runaway in partiallyinsulated or cooled reactors are investigated. The temperaturein the reactor is taken to satisfy a nonlinear elliptic equationand the reaction is modelled by an Arrhenius heat generationterm with finite activation energy. To determine the onset ofthermal runaway, the method of matched asymptotic expansionsis used to derive expressions for the critical Frank-Kamenetskiiparameter _c() for reactors containing either a small coolingrod or having a small cooling patch on their boundary. The theoryused to determine _c() is an extension of the results of Wardand Keller (1991). These previous results of Ward and Kellerare also extended to the case of finite activation energiesby using a numerical scheme to evaluate the coefficients inthe asymptotic results for _c(). In some special cases, the asymptoticexpansions for _c() are compared with numerical results for _c(),and clear agreement is found.     

西藏拉萨市周边温棚蔬菜样品中农药残留量的研究

用农药残毒速测仪和气相色谱 火焰光度检测器（GC FPD）2种方法对拉萨市周边4个温室蔬菜基地抽样采集的26个蔬菜样品测定其农药残留量.结果,用速测仪检测出7个蔬菜样品中有农药残留存在.为进一步验证其结果,参考国家农业标准NY/T 761-2008,建立了气相色谱火焰光度(GC-FPD)检测蔬菜样品中敌敌畏、氧化乐果、二嗪农、乐果、甲基对硫磷、马拉硫磷、对硫磷、水胺硫磷、喹硫磷9种有机磷农药残留的分析方法,建立的气相色谱分析方法：检出限为0.039 7～0.182 0 μg·mL^-1、回收率为51.64%～91.04%、方法的精密度为1.61%～10.80%.用该方法对农药残留超标的蔬菜样品进行分析,结果未检测到上述9种有机磷农药的残留.实验结果为从事农药残留检测工作者在分析方法的选择和评价拉萨市蔬菜农药残留状况提供参考.     

Confinement, average forces, and the Ehrenfest theorem for a one-dimensional particle

The topics of confinement, average forces, and the Ehrenfest theorem are examined for a particle in one spatial dimension. Two specific cases are considered: (i) A free particle moving on the entire real line, which is then permanently confined to a line segment or ‘a box’ (this situation is achieved by taking the limit V ₀?→?∞ in a finite well potential). This case is called ‘a particle-in-an-infinite-square-well-potential’. (ii) A free particle that has always been moving inside a box (in this case, an external potential is not necessary to confine the particle, only boundary conditions). This case is called ‘a particle-in-a-box’. After developing some basic results for the problem of a particle in a finite square well potential, the limiting procedure that allows us to obtain the average force of the infinite square well potential from the finite well potential problem is re-examined in detail. A general expression is derived for the mean value of the external classical force operator for a particle-in-an-infinite-square-well-potential, $\hat{F}$ . After calculating similar general expressions for the mean value of the position ( $\hat{X}$ ) and momentum ( $\hat{P}$ ) operators, the Ehrenfest theorem for a particle-in-an-infinite-square-well-potential (i.e., $\mathrm{d}\langle\hat{X}\rangle/\mathrm{d}t=\langle\hat{P}\rangle/M$ and $\mathrm{d}\langle\hat{P}\rangle/\mathrm{d}t=\langle\hat{F}\rangle$ ) is proven. The formal time derivatives of the mean value of the position ( $\hat{x}$ ) and momentum ( $\hat{p}$ ) operators for a particle-in-a-box are re-introduced. It is verified that these derivatives present terms that are evaluated at the ends of the box. Specifically, for the wave functions satisfying the Dirichlet boundary condition, the results, $\mathrm{d}\langle\hat{x}\rangle/\mathrm{d}t=\langle\hat{p}\rangle/M$ and $\mathrm{d}\langle\hat{p}\rangle/\mathrm{d}t=\mathrm{b.t.}+\langle\hat{f}\rangle$ , are obtained where b.t. denotes a boundary term and $\hat{f}$ is the external classical force operator for the particle-in-a-box. Thus, it appears that the expected Ehrenfest theorem is not entirely verified. However, by considering a normalized complex general state that is a combination of energy eigenstates to the Hamiltonian describing a particle-in-a-box with v(x)?=?0 ( $\Rightarrow\hat{f}=0$ ), the result that the b.t. is equal to the mean value of the external classical force operator for the particle-in-an-infinite-square-well-potential is obtained, i.e., $\mathrm{d}\langle\hat{p}\rangle/\mathrm{d}t$ is equal to $\langle\hat{F}\rangle$ . Moreover, the b.t. is written as the mean value of a quantity that is called boundary quantum force, f _B. Thus, the Ehrenfest theorem for a particle-in-a-box can be completed with the formula $\mathrm{d}\langle\hat{p}\rangle/\mathrm{d}t=\langle{{f_\mathrm{B}}}\rangle$ .     

Nature-Inspired Routing and Wavelength Assignment Algorithms for Optical Circuit-Switched Polymorphic Networks

Polymorphic optical networks simultaneously support several optical switching paradigms over a single physical network. In this way, they provide service differentiation at the optical layer by employing the most appropriate paradigm for each service. One type of such architecture is the optical circuit-switched polymorphic network (OCSPN), which combines optical circuit switching paradigms with different grades of dynamism. The performance of this network relies on the utilization of efficient routing and wavelength assignment (RWA) algorithms. In this article, we review the fundamentals of OCSPNs and present a set of efficient RWA algorithms based on ant colony optimization and genetic algorithms.     

β-Na（Y_（1.5-x-y）Na_（0.5））F_6：Yb_xTm_y纳米颗粒的合成及其上转换发光性质

本文采用水热合成法制备了β-Na（Y1.5-x-yNa0.5）F6：YbxTmy（x=0.2~1.0,y=0.001~0.008）纳米颗粒,并利用X射线粉末衍射仪、透射电子显微镜和F-4600荧光分光光度计表征了其样品的物相、形貌和发光性质.结果表明样品物相为六角相,颗粒平均直径约22nm,并探讨了Yb3＋和Tm3＋掺杂浓度对样品的上转换发光性质的影响,结果表明敏化剂Yb3＋的最佳掺杂浓度为60%,而激活剂Tm3＋的最佳掺杂浓度为0.6%.     

Thermal conductivity of open‐cell polyolefin foams

The thermal conductivity and the cellular structure of novel open‐cell polyolefin foams produced by compression molding and based on blends of an ethylene‐vinyl acetate copolymer (EVA) and a low‐density polyethylene (LDPE) have been studied in the temperature range between 24 and 50 °C. The experimental results have shown that the cellular structure of the analyzed materials has interconnected cells because of the presence of large and small holes in the cell walls, this structure being clearly different to the typical structure of open‐cell polyurethane foams. It has been found that at low temperatures the materials have a slightly higher thermal conductivity than closed‐cell polyolefin foams of similar densities. The different mechanisms of heat flow, conduction, convection, and radiation have been analyzed by using experimental measurements and a theoretical model. It has been proved that, in spite of having an open‐cell structure, the convention mechanism is negligible, being the radiation mechanism the one which made different the conductivity of materials with varying cellular structures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 212–221, 2008     

钒氧酞菁薄膜瞬态光电压性能的研究

本文分别用1064nm, 532nm和 355nm激发波长的YAG脉冲激光对所制备的phase Ⅱ结构钒氧酞菁膜Al\phase ⅡVOPc\ITO夹心电池进行瞬态光电压响应研究.随着3种波长激发光脉冲强度的增加, 瞬态光电压信号均增强. 激发光波长1064nm、532nm处于酞菁膜Q-带吸收区肩部, 光电压的极性与激发光入射方向无关, 均为负信号; 而激发光波长 355nm处于酞菁膜B-带, 光电压的极性与激发光入射方向有关, 从ITO极方向激发产生正电压信号, 从A1极激发产生负电压信号. 激发光波长对夹心电池的光电压产生有明显的作用, 光电压产生过程中应存在不同的机理. 这与前文^[1]对同一夹心电池稳态光电压响应研究所推断的结论一致.