一类非线性振动系统改进状态空间模型及其数值方法

导出了一类非线性振动系统的改进状态空间模型，提出了相应的数值计算方法，并利用迭代法有效地提高了计算精度。该数值方法与传统的Houbolt、Wilson-θ、Newmark-β法以及连续线性化模型及其Taylor变换法^[3,4]相比，具有更高的求解精度和效率。文末给出了非线性单摆、强迫Duffing方程、强迫Van Der Pol方程以及两自由度非线性弹簧摆这几类典型非线性方程的数值计算结果，并与文献[5-8]进行对比，进一步说明了该方法在计算精度和效率两方面的优越性。     

气相色谱-质谱联用法测定动物组织中氯霉素、氟甲砜霉素和甲砜霉素的残留量

建立了气相色谱-负离子化学电离源质谱同时测定动物组织中氯霉素(CAP)、甲砜霉素(TAP)和氟甲砜霉素(FF)残留量的方法。样品用乙酸乙酯提取,正己烷分配去脂肪,再用Florisil柱进一步净化,甲苯作为反应介质,用N,O-双(三甲基硅基)三氟乙酰胺(BSTFA)-三甲基氯硅烷(TMCS)(体积比为99∶1)进行硅烷化处理,用间硝基氯霉素(m-CAP)作为内标进行测定。CAP的检测限可达到0.03 μg/kg,TAP和FF的检测限可达到0.2 μg/kg;上述3种药物的标准曲线的线性相关系数均大于0.99。CAP,FF和TAP的批内测定的精密度(以相对标准偏差表示)依次为5.5%,10.4%和8.8%;批间测定的精密度依次为7.4%,20.7%和19.1%。回收率为80.0%~111.5%,相对标准偏差为1.2%~15.4%。该方法前处理步骤简单,处理后杂质干扰少,灵敏度高,适用性强,可用于猪肉及禽类、水产品等多种动物组织中氯霉素类药物残留的检测。     

Rough singular integral operators on Hardy-Sobolev spaces

The authors study the singular integral operator TΩ,αf(x)=p.v.∫R^nb(|y|Ω(y′)|y|^-n-αf(x-y)dy, defined on all test functions f, where b is a bounded function, α＞0, Ω(y′) is an integrable function on the unit sphere S^n-1 satisfying certain cancellation conditions. It is proved that, for n/(n α)＜p＜∞,TΩ,α is a bounded operator from the Hardy-Sobolev space H^pα to the Hardy space H^p. The results and its applications improve some theorems in a previous paper of the author and they are extensions of the main theorems in Wheeden‘s paper(1969). The proof is based on a new atomic decomposition of the space H^pα by Han, Paluszynski and Weiss(1995). By using the same proof,the singluar integral operators with variable kernels are also studied.     

坚果及其制品中匹克司残留量气相色谱测定法

确立了坚果及其制品中匹克司残留量的气相色谱测定方法试样采用甲醇提取，经ＰＴ－硅镁柱净化，ＧＣ－ＥＣＤ测定，方法简便，快速灵敏，检出限０．０２＊１０＾－３ｇ／ｋｇ，添加回收率８７．４％－９３．２％，相对标准偏差４．４％－６．８８％．。     

Elastic and plastic deformations of nickel nanowires under uniaxial compression

Using atomistic molecular dynamics simulation with a Sutton–Chen many body potential, we studied the structural evolution and deformation mechanisms of nickel nanowires under homogeneous uniaxial compressions. Nickel nanowires with helical multi-shell structure and fcc-like crystalline structures have been considered. Elastic and plastic behaviors of nickel nanowires under compression were observed and their elastic limits were determined. Our simulations show that the nickel nanowires with helical multi-shell structure have greater yield strength than that of macroscopic solid. Above elastic limit, the plastic deformation of the nanowires shows behavior that is associated with superplasticity. The final atomic structures for the two kinds of nanowires are resemblant crystalline-like.     

Structural evolution and electronic properties of germanium-doped boron clusters and their anions: GeBn0/− (n = 6–20)

Journal of Nanoparticle Research - The creation of metal oxide aerogels is a demanded and developing area of science. Aerogel materials have a high specific surface area and can be used in a wide...     

Explosive transitions to synchronization in weighted static scale-free networks

We present a systemical study on the thermodynamic and physical properties of Ti₂CoIn and Ti₂NiIn by using first-principles calculations. Both alloys are found to be half-metallic ferromagnets with a total spin magnetic moment per formula unit of 2.00 and 3.00μ _B . The stability is evaluated from the physical, chemical and mechanical points of view. The Curie temperature is estimated to be 553.16 K for Ti₂CoIn and 1008.59 K for Ti₂NiIn, which is well-above the room temperature. In addition, the half-metallicity of Ti₂CoIn and Ti₂NiIn is retained when the lattice constants are changed by ?12.58% to 6.76% and ?13.08% to 4.36%, respectively. Finally, using a quasiharmonic Debye model which exhibits Ti₂CoIn has a higher thermal stability than Ti₂CoIn within a limited temperature (0–500 K). Thus, the present calculations show that Ti₂CoIn and Ti₂NiIn have a great application potential in the spin valve and magnetic tunnel junction.     

气相色谱/质谱-选择离子检测法同时测定大米中的25种持久性有机污染物

利用超声波提取、固相萃取净化对样品进行前处理,然后采用气相色谱/质谱-选择离子检测模式对大米中的25种持久性有机污染物进行了分析。色谱条件:DB-35MS毛细管色谱柱(30 m×0.25 mm i.d.×0.25 μm);载气为氦气,流速1 mL/min;进样口温度300 ℃;不分流进样,进样量1 μL;柱温为程序升温模式。质谱条件:电子轰击电离源,70 eV;采集方式为选择离子方式,扫描质量范围50~450 u。实验采用保留时间以及定性、定量特征离子的丰度比定性,采用峰面积外标法定量,制作了25种持久性有机污染物的标准工作曲线。不同浓度水平的添加回收率试验表明,25种持久性有机污染物的添加回收率为81.99%～100.60%,相对标准偏差为2.37%～18.48%,除异狄氏剂、反式氯丹和顺式氯丹的检测限分别为20,30和20 ng/g外,其他有机污染物的检测限为0.1～5 ng/g。该方法的灵敏度、准确度和精密度均符合农药多残留测定技术的要求。     

Determination of Impurity Silicon in Anticancer Drug (Ge-132) by Electrothermally Atomised Atomic Absorption Spectrometry with Optical Temperature Control Accessory

The present paper describes the ashing and atomization processes in silicon analysis by electrothermally atomised atomic absorption spectrometry(EAAAS) with an uncoat-ed graphite tube, a pyrolytically coated graphite tube and a tungsten-coated graphitetube. The sensitivity and linear range of three graphite tubes were compared. By using optical temperature control accessory, the signals are enhanced by a factor of 2 and the germanium interferences in the determination of silicon are eliminated. The effects of time constant and carrier gas flow-rate on the determination of silicon were also tested. The sample can be directly analyzed in its aqueous solution without any pretreatment. The measurements of samples containing 0. 2 μg/mL and 0. 4 μg/mL silicon were run ten times and the variation coefficient is 4. 9% and 2.6%, respectively. The recovery tests for carboxyethyl germanium sesquioxide(Ge-132) synthesized and imported were performed, and the recoveries are 97. 0% and 110%, respectively. Keywords     

A simple capacitor model and first-principles study of carbon-doped zigzag ZnO nanoribbons

Using density-functional-theory calculations, we study electronic and magnetic properties of zigzag ZnO nanoribbons (ZZnONRs) with a single carbon atom substituting O. We find that the formation energy of carbon dopant depends strongly on the position: the carbon atom doped close to O edge is most favorable energetically for H-passivated ZZnONRs, whereas the doped carbon atom prefers to locate near Zn edge on bare ZZnONRs. These features are explained using a simple capacitor model. We also find that the substitutional carbon defect induces spontaneous magnetization and manipulates the electronic properties of ZZnONRs, independent of the ribbon width ($N$). In particular, H-passivated $N$-ZZnONRs ($4<N<9$) exhibit two successive transitions from semiconductor to metal via half-metal as the doping proceeds gradually from O edge to Zn edge.