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991.
Daniele Del Giudice Matteo Valentini Gabriele Melchiorre Emanuele Spatola Prof. Stefano Di Stefano 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(26):e202200685
This work reports that the composition of a dynamic library (DL) of interconverting imines can be controlled over time in a dissipative fashion by the addition of an activated carboxylic acid used as a chemical fuel. When the fuel is added to the DL, which is initially under thermodynamic equilibrium, the composition of the mixture dramatically changes and a new, dissipative (out of equilibrium) state is reached that persists until fuel exhaustion. Thus, a transient dissipative dynamic library (DDL) is generated that, eventually, reverts back to the initial DL when the fuel is consumed, closing a DL→DDL→DL cycle. The larger the amount of added fuel, the longer the time spent by the system in the DDL state. The transimination reaction is shown to be an optimal candidate for the realization of a dissipative dynamic covalent chemistry (DDCvC). 相似文献
992.
Fabricio Bublitz Melina de Azevedo Mello Daniele Cocco Durigon Felipe Dornelles da Silva Artur Luis Hennemann Ernesto Schulz Lang 《无机化学与普通化学杂志》2019,645(5):544-550
In this paper we explore an amino functionalized selenolate unit for the synthesis of new multinuclear compounds with promising interesting properties and potential precursors of semiconductors. We present for the first time the X‐ray crystallographic structure of [Hg(SeC6H4NH2)2]2 · diox ( 1· diox) and its copper(I) derivatives: HgCu2X2(SeC6H4NH2)2(PPh3)4 · 4diox [X = Br ( 2· 4diox) and I ( 3· 4diox)]. The compounds 1 and 2 , 3 can be considered as the starting material and intermediates, respectively, for the synthesis of ternary HgII/Se/CuI nanoclusters. We also provide IR and NMR spectroscopic data and evaluate the optical features of these compounds by difuse reflectance UV/Vis spectroscopy. 相似文献
993.
Chiara Biagini Giorgio Capocasa Valerio Cataldi Daniele Del Giudice Prof. Luigi Mandolini Prof. Stefano Di Stefano 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(66):15205-15211
This work aimed to render phenomenologically autonomous the otherwise stepwise operation of a catenane-based molecular switch, which is chemically triggered by the decarboxylation of 2-cyano-2-phenylpropanoic acid ( 2 ). Given that any amount of 2 in stoichiometric excess with respect to the catenane is consumed in a side reaction, the authors resorted to the corresponding anhydride 5 , the slow hydrolysis of which, due to adventitious water in dichloromethane, continuously produces in situ the actual fuel 2 . As a consequence, the machine does not require a reloading after each cycle, but switches back and forth as long as fuel is present. 相似文献
994.
The purpose of this paper is to show that if a jet cue oJr(n,p), n p, p > 1, is not v-sufficient in Cr+1, there existsan infinite sequence (fi)iN* of realisations of o with mutuallynon-homeomorphic germs of varieties . Bochnak and Kuo [2, 5] showed it when p = 1 and thought thatthe same argument slightly modified can be used in the casep 2 [7, p. 225]. But when n p + 2, p > 1, we have to proceeddifferently. Moreover, it is necessary to prove separately theresult when n = p and n = p + 1. About C0-sufriciency and p> 1, Brodersen [3, p. 168] showed a similar theorem. 相似文献
995.
Enrique Benavent Alessandro Carrotta Angel Corberán José M. Sanchis Daniele Vigo 《European Journal of Operational Research》2007
In this paper we present several heuristic algorithms and a cutting-plane algorithm for the Windy Rural Postman Problem. This problem contains several important Arc Routing Problems as special cases and has very interesting real-life applications. Extensive computational experiments over different sets of instances are also presented. 相似文献
996.
A spin-statistics theorem and a PCT theorem are obtained in the context of the superselection sectors in Quantum Field Theory on a 4-dimensional spacetime. Our main assumption is the requirement that the modular groups of the von Neumann algebras of local observables associated with wedge regions act geometrically as pure Lorentz transformations. Such a property, satisfied by the local algebras generated by Wightman fields because of the Bisognano-Wichmann theorem, is regarded as a natural primitive assumption.Dedicated to Hans Borchers on the occasion of his seventieth birthdaySupported in part by MURST and CNR-GNAFA. 相似文献
997.
Daria Mamaeva Chantal Ripoll Claire Bony Marisa Teigell Florence E Perrin Bernard Rothhut Ivan Bieche Rosette Lidereau Alain Privat Valérie Rigau Hélène Guillon Florence Vachiery-Lahaye Daniele Noel Luc Bauchet Jean-Philippe Hugnot 《BMC neuroscience》2011,12(1):1-12
Background
Evidence suggests that rheumatoid arthritis (RA) may enhance or reduce the progression of Alzheimer's disease (AD). The present study was performed to directly explore the effects of collagen-induced rheumatoid arthritis (CIA) on amyloid plaque formation, microglial activation, and microvascular pathology in the cortex and hippocampus of the double transgenic APP/PS1 mouse model for AD. Wild-type or APP/PS1 mice that received type II collagen (CII) in complete Freund's adjuvant (CFA) at 2 months of age revealed characteristics of RA, such as joint swelling, synovitis, and cartilage and bone degradation 4 months later. Joint pathology was accompanied by sustained induction of IL-1β and TNF-α in plasma over 4 weeks after administration of CII in CFA.Results
CIA reduced levels of soluble and insoluble amyloid beta (Aβ) peptides and amyloid plaque formation in the cortex and hippocampus of APP/PS1 mice, which correlated with increased blood brain barrier disruption, Iba-1-positive microglia, and CD45-positive microglia/macrophages. In contrast, CIA reduced vessel density and length with features of microvascular pathology, including vascular segments, thinner vessels, and atrophic string vessels.Conclusions
The present findings suggest that RA may exert beneficial effects against Aβ burden and harmful effects on microvascular pathology in AD. 相似文献998.
999.
Artoni RF Gross MC Schneider CH Vicari MR de Almeida MC Matoso DA 《Micron (Oxford, England : 1993)》2008,39(8):1156-1159
New karyotypic data are presented for the Astyanax fasciatus species complex from four different locations on the Upper Tibagi River in the state of Paraná, Brazil. Chromosome markers were analyzed using conventional (Ag-NOR) and molecular (FISH with 18S biotinylated probes) methods. Two cytotypes were found in cell counts with diploid number 2n = 48 chromosomes and 2n = 50 chromosomes, previously denominated Cytotype A and B, respectively. Two specific patterns of Ag-NORs markers (ribosomal gene activity) were found, with intra-population and inter-population variations. Cytotype A exhibited two to three chromosomes with NOR sites in the metaphases analyzed. In Cytotype B specimens, up to three markers were found, demonstrating greater intra-population and inter-population variation. All individuals with only one chromosome pair with NORs were located in the telomeric region of the short arm of Chromosome 5. This characteristic was interpreted as ancestral for the species. Another identified pattern revealed a site in the telomeric region probably in the long arm of Chromosome 4 and another submetacentric chromosome with bitelomeric marks exclusively in specimens with 2n = 50 chromosomes. In the FISH analysis (ribosomal gene structure), five to seven markers were identified in Cytotype A and three to seven markers were identified in Cytotype B. Structural chromosome events and/or transposable elements are required to explain the ribosomal gene location diversity in these organisms. The results of the present study corroborate the hypothesis that the A. fasciatus of the Upper Tibagi River region constitute a species complex. 相似文献
1000.
Lin Zhang Daniele Cocco Nicholas Kelez Daniel S. Morton Venkat Srinivasan Peter M. Stefan 《Journal of synchrotron radiation》2015,22(5):1170-1181
To cover a large photon energy range, the length of an X‐ray mirror is often longer than the beam footprint length for much of the applicable energy range. To limit thermal deformation of such a water‐cooled X‐ray mirror, a technique using side cooling with a cooled length shorter than the beam footprint length is proposed. This cooling length can be optimized by using finite‐element analysis. For the Kirkpatrick–Baez (KB) mirrors at LCLS‐II, the thermal deformation can be reduced by a factor of up to 30, compared with full‐length cooling. Furthermore, a second, alternative technique, based on a similar principle is presented: using a long, single‐length cooling block on each side of the mirror and adding electric heaters between the cooling blocks and the mirror substrate. The electric heaters consist of a number of cells, located along the mirror length. The total effective length of the electric heater can then be adjusted by choosing which cells to energize, using electric power supplies. The residual height error can be minimized to 0.02 nm RMS by using optimal heater parameters (length and power density). Compared with a case without heaters, this residual height error is reduced by a factor of up to 45. The residual height error in the LCLS‐II KB mirrors, due to free‐electron laser beam heat load, can be reduced by a factor of ~11 below the requirement. The proposed techniques are also effective in reducing thermal slope errors and are, therefore, applicable to white beam mirrors in synchrotron radiation beamlines. 相似文献