Konversion der 238,6 keV-γ-Linie des ThB und Vergleich mit den Tabellen von Sliv und von Rose

The conversion ratiosK/L _I andK/L _II of the 238.6 keVγ transition of ThB have been measured with the new Heidelbergπ/2 √13Β-ray spectrometer. For this transition there are great discrepancies between the values as given bySliv andBand, and byRose. The experimental resultsK/L _I=5.96±0.26 andK/L _II=60.3±7.1 are in excellent agreement with the values ofSliv andBand.     

Electrons magnetic fields and background radio emission in the galaxy

Extensive data now available on the non-thermal background radio emission from different celestial directions, and recent measurements on the energy spectrum of cosmic ray electrons in the vicinity of the earth permit one to deduce information on the mean magnetic fields and cosmic electron spectra needed to exist in different regions of the Galaxy. It is found that in order to explain quantitatively the background radio brightness distributions from the Galaxy one needs (i) the same or nearly same electron spectrum that exists in the near interstellar space, to exist in almost all regions of Galactic space, (ii) a mean magnetic field close to 6×10^?6 Gauss in the Disc in the direction of the Anti-centre, (iii) a mean magnetic field close to 2·5×10^?6 Gauss in the radio Halo and (iv) a mean magnetic field probably close to 9·5×10^?6 Gauss towards the Galactic Ridge in the direction of the Centre. Some inferences are also drawn on the confinement of cosmic rays in the Galaxy.     

Gauge internal symmetry in extended supergravity

Extended supergravity theories with global O(2) and SO(3) internal symmetry have recently been constructed, and a mechanism which implements local O(2) and SO(3) gauge invariance is given here. The introduction of a minimal gauge coupling automatically leads to a $\text{spin}\text{-}\text{3}\text{2}$ mass and a cosmological term in order to preserve local supersymmetry. Local internal symmetry for a $\text{spin}\text{-}\text{3}\text{2}$ field is related to spontaneous breakdown of global supersymmetry. Perturbation theory results which confirm the physical consistency of the system are given.     

Mechanism of amine catalyzed isomerization of itaconic anhydride to citraconic anhydride: Citraconamic acid formation

The amine catalyzed isomerization of itaconic to citraconic anhydride has been investigated. Studies show that the rate of isomerization is dependent on the base strength and solvent media. Triethylamine causes complete isomerization within 5 min at room temperature in acetone or chloroform solvent, whereas aromatic tertiary amines such as pyridine and N,N-dimethylaniline require time perods as long as 23h at room temperature for almost complete isomerization. In the presence of aniline no isomerization occures even under acetone reflux conditions over a 24 h period. For the preparation of citraconamic acids from itaconic anhydrides and aliphatic diamines nuclear magnetic resonance and infrared spectroscopic evidence is presented to support the reaction path of initial isomerization of itaconic anhydride to citraconic anhydride followed by amine attack on the anhydride to form the corresponding cis-citraconamic acids. The mechanism of isomerization of itaconic to citraconic acids is proposed.     

1,3-Diyl trapping reactions. Fundamental investigations with application to the synthesis of linearly fused tricyclopentanoids

A comparison of the inter- and intramolecular diyl trapping routes to linearly fused tricyclopentanoids is presented. In addition, several of the factors which are responsible for the stereoselectivity which is associated with the intramolecular process are examined and it is concluded that conformational rather than electronic (secondary orbital) factors play the dominant role. It is shown that gem methyl groups located on the acyclic chain which joins the diyl and diylophile (in reference to 32 and 35, but not to 47) have no practical effect upon the outcome of the trapping reaction. The intramolecular process is stereospecific with respect to diylophile geometry, and highly stereoselective with respect to the ring junction stereochemistry. Finally, an abortive attempt to synthesize the marine natural product Δ⁹⁽¹²)-capnellene (19) as well as a successful synthesis of the mold metabolite d,l- hirsutene (18) is presented.     

Solvent effects on hydrogen bond formation

Enthalpies of solution have been used to calculate transfer enthalpies for phenol, pyridine, and DMSO between the solvent cyclohexane and the solvents CCl₄, benzene, and CHCl₃. By use of model compounds, enthalpies due to interactions with phenol, pyridine, and DMSO have been determined. These enthalpies are used to calculate the effect of solvation relative to cyclohexane on hydrogen bonded complexes in CCl₄ and benzene solvents. Correlations with enthalpies due to interactions and frequency shifts for the hydroxyl stretch in these solvents have also been made.     

Bornes quasi-inferieures et bornes superieures de la pression de ruine des coques de revolution par la methode des elements finis et par la programmation non-lineaire

This work is concerned with rigid-plastic limit analysis of shells of revolution subject to rotationally symmetric loadings. These shells, of arbitrary shape, are discretized into a series of finite elements, each being a conical shell. The von Mises condition, valid for sandwich shells, is used to compare the results obtained with existing values. After assembling the finite elements, the limit analysis program is reduced to a simple application of the non-linear programming technique where both the sequential unconstrained minimization technique (SUMT) and feasible conjugate direction (FCD) are utilized respectively for statically admissible and kinematically admissible approaches. Therefore, upper bounds and lower bounds of the collapse loads are found for some sample problems : conical, spherical, ellipsoidal, torispherical shells etc. These numerical results are illustrated and compared with existing ones described in the literature.     

Études calorimétriques en milieu solvant organique: II Enthalpies de dissolution et de dilution du boranate de lithium (LiBH4) et de l'alanate de lithium (LiAlH4) dans le tétrahydrofuranne

The enthalpies of dissolution and dilution of LiBH₄ and LiAlH₄ in THF have been determined.Dissolutions are exothermic. The endothermic dilution of LiAlH₄ suggests for this compound, either a dissociation or an association equilibrium.     

Mixed-mode failure of composite laminates with cracks

The behavior of quasi-isotropic graphite/epoxy laminates with cracks subjected to various biaxial-stress fields was studied experimentally. This was accomplished by uniaxial tensile loading of specimens with cracks of various orientations with the loading axis. It was found that the critical stress-intensity factor, based on a projected crack length increased by a characteristic damage dimension, is nearly constant with stress biaxiality and initial crack length. Paper was presented at V International Congress on Experimental Mechanics held in Montreal, Quebec, Canada on June 10–15, 1984.     

Measurement of frequency differences between visible laser lines up to 170GHz using metal-insulator-metal point contact diodes

Frequency differences of up to 170 GHz between a cw dye laser and a krypton laser at 568 nm were measured by mixing laser and microware radiation with a metalinsulator-metal point contact diode. Beat signals are well above noise and there is still great potential for improvement when better microwave oscillators are used. From the measurements reported it follows that the diode can be used for determining still higher frequency differences of visible laser radiation.