全文获取类型
收费全文 | 17243篇 |
免费 | 759篇 |
国内免费 | 140篇 |
专业分类
化学 | 11427篇 |
晶体学 | 107篇 |
力学 | 515篇 |
数学 | 3022篇 |
物理学 | 3071篇 |
出版年
2023年 | 145篇 |
2022年 | 261篇 |
2021年 | 335篇 |
2020年 | 413篇 |
2019年 | 390篇 |
2018年 | 264篇 |
2017年 | 239篇 |
2016年 | 640篇 |
2015年 | 508篇 |
2014年 | 594篇 |
2013年 | 907篇 |
2012年 | 1176篇 |
2011年 | 1396篇 |
2010年 | 715篇 |
2009年 | 615篇 |
2008年 | 1051篇 |
2007年 | 999篇 |
2006年 | 999篇 |
2005年 | 895篇 |
2004年 | 761篇 |
2003年 | 544篇 |
2002年 | 543篇 |
2001年 | 210篇 |
2000年 | 176篇 |
1999年 | 160篇 |
1998年 | 137篇 |
1997年 | 138篇 |
1996年 | 184篇 |
1995年 | 124篇 |
1994年 | 128篇 |
1993年 | 137篇 |
1992年 | 109篇 |
1991年 | 105篇 |
1990年 | 85篇 |
1989年 | 79篇 |
1988年 | 91篇 |
1987年 | 82篇 |
1986年 | 82篇 |
1985年 | 116篇 |
1984年 | 118篇 |
1983年 | 81篇 |
1982年 | 132篇 |
1981年 | 138篇 |
1980年 | 112篇 |
1979年 | 97篇 |
1978年 | 127篇 |
1977年 | 112篇 |
1976年 | 90篇 |
1975年 | 84篇 |
1973年 | 84篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
992.
Nikolay Djourelov Corine Bas Daniel Sillou Rosario Benavente Ernesto Pérez María L. Cerrada 《Journal of Polymer Science.Polymer Physics》2010,48(18):1994-2002
Copolymers of propylene and 1‐octadecene synthesized by a metallocene catalyst were characterized by PALS, WAXD, DSC, and density measurements. The change in the sizes and the number density of free‐volume holes as a function of the 1‐octadecene content were compared to the master laws published for copolymers of propylene with α‐olefins of shorter lengths. It was found that the samples were separated into two groups. The first set of samples obeyed the master laws while the second group deviated. This behavior was explained by the difference in the copolymer structure. The WAXD analysis confirmed the separation as well. The deviation was explained as due to the mesomorphic crystalline structure of the second group of samples, in contrast to the monoclinic one for the first group, which was a result of the relatively fast cooling from the molten state and from the high comonomer molar content. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1994–2002, 2010 相似文献
993.
994.
Corrigendum: Effect of hexyl substituent groups on photophysical and electrochemical properties of the poly[(9,9‐dioctyfluorene)‐2,7‐Diyl‐alt‐(4,7‐bis (3‐hexylthien‐5‐Yl)‐2,1,3‐benzothiadiazole)‐2′,2″‐diyl] 下载免费PDF全文
995.
Dominik Koszelewski Daniel Paprocki Anna Brodzka Ryszard Ostaszewski 《Tetrahedron: Asymmetry》2017,28(6):809-818
A novel synthetic route to optically active saturated and unsaturated δ-lactones based on enzymatic kinetic resolution and ring-closing metathesis reactions has been proposed. The influence of temperature, co-solvent, organic additives and the substrate structure on the catalytic behavior of selected hydrolases was studied. The substantial impact of the organic co-solvent and surfactant type on the enzymatic activity and enantioselectivity was observed providing enantiomerically pure δ-hydroxy-α,β-unsaturated esters. The established protocol combining enzymatic kinetic resolution with ring closing metathesis was successfully applied in the synthesis of the enantiomerically pure (6R)-phenyl-5,6-dihydro-2H-pyran-2-one which plays crucial role in the synthesis of the number of bioactive compounds. 相似文献
996.
Adrienne N. Dula Daniel F. Gochberg Mark D. Does 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2009,196(2):149-156
Calculations, analytical solutions, and simulations were used to investigate the trade-off of echo spacing and receiver bandwidth for the characterization of bi-exponential transverse relaxation using a multi-echo imaging pulse sequence. The Cramer–Rao lower bound of the standard deviation of the four parameters of a two-pool model was computed for a wide range of component T2 values and echo spacing. The results demonstrate that optimal echo spacing (TEopt) is not generally the minimal available given other pulse sequence constraints. The TEopt increases with increasing value of the short T2 time constant and decreases as the ratio of the long and short time constant decreases. A simple model of TEopt as a function of the two T2 time constants and four empirically derived scalars is presented. 相似文献
997.
Xiaotong Zhang Eranda Wanigasekara Zachary S. Breitbach Edra Dodbiba Daniel W. Armstrong 《Rapid communications in mass spectrometry : RCM》2010,24(8):1113-1123
In previous studies, new electrospray ionization mass spectrometry (ESI‐MS) approaches were developed for the highly sensitive detection of singly and doubly charged anions in positive mode ESI‐MS by using specially synthesized dicationic and tricationic ion‐pairing agents, respectively. By detecting the positively charged ion complex in the positive mode, limits of detection (LODs) for the anions can be lowered by several magnitudes. In this work, we used eighteen newly synthesized tetracationic ion‐pairing agents, constructed with different geometries, linkages and cation moieties, for the detection of eighteen triply charged anions of different structural motifs. The LODs for these anions were from ten to several thousand times lower in the positive selective ion monitoring (SIM) mode than in the negative mode. These tetracationic agents also were shown to be useful for the detection of ?1 and ?2 anions. In addition, the LODs for ?3 anions can be further lowered by monitoring the product fragments of the ion‐pairing complexes in the single reaction monitoring (SRM) mode. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
998.
Donald R. Hastie John Gray Vaughan S. Langford Robert G. A. R. Maclagan Daniel B. Milligan Murray J. McEwan 《Rapid communications in mass spectrometry : RCM》2010,24(3):343-348
The on‐line detection of gaseous peroxyacetyl nitrate (PAN) using selected ion flow tube mass spectrometry (SIFT‐MS) has been investigated using a synthetic sample of PAN in air at a humidity of ~30%. Using the H3O+ reagent ion, signals due to PAN at m/z 122, 77 and 95 have been identified. These correspond to protonated PAN, protonated peractetic acid and its water cluster, respectively. These products and their energetics have been probed through quantum mechanical calculations. The rate coefficient of H3O+ has been estimated to be 4.5 × 10?9 cm3 s?1, leading to a PAN sensitivity of 138 cps/ppbv. This gives a limit of detection of 20 pptv in 10 s using the [M+H]+ ion of PAN at m/z 122. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
999.
1000.
Polychlorodibenzo-p-dioxins, polychorodibenzofurans and “dioxin-like” polychlorinated biphenyls are widespread persistent organic pollutants sharing a similar toxicological pathway mediated by the aryl-hydrocarbon receptor (AhR). Since the confirmatory method for their measurement at trace levels in complex matrices (using isotopic dilution and gas chromatography-high resolution mass spectrometry) remains time and cost-consuming, growing efforts of the scientific community have been focused on the development of screening approaches, including AhR mediated assays. Unfortunately, AhR ligands are highly diverse and agonistic/antagonistic effects can be observed on procedural blanks and/or sample extracts. In this study, the influence of solvent grade quality on the response of a DNA-binding AhR mediated assay used for screening dioxins has been investigated. Our results demonstrated a very critical impact of this parameter with both strong agonistic and antagonistic effects observed for any tested solvent lot. A small silver nitrate silica column removed partly these interfering compounds and then can be recommended as final purification step. Some preferable grades can be identified and selected in order to guarantee the best possible performances. However, it appears necessary to test every new lot, even if a grade appeared previously compliant. 相似文献