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161.
162.
Reaction of acetylene dicarboxaldehyde monoacetal with substituted Meldrum’s acid leads good yields in 2-pyranones-4-carboxaldehydes substituted in position 3. 相似文献
163.
O. V. Koryakova V. V. Sattarova D. V. Sevenard O. G. Khomutov K. I. Pashkevich 《Russian Journal of General Chemistry》2003,73(1):141-144
The tautomeric equilibrium in substituted 5,6,7,8-tetrahydroquinazolines was studied by IR spectroscopy. The effect of various substitutents in the pyrimidine ring and the solvent on the state of the tautomeric equilibrium was evaluated. 相似文献
164.
O. Castaños 《Journal of Molecular Spectroscopy》2007,241(1):51-60
A simple algebraic approach to calculate general Franck-Condon overlaps is extended to evaluate non-Condon factors for two one-dimensional harmonic oscillators. The method is based on the use of eigenstates of the harmonic oscillator annihilation operator which allows to obtain in terms of a multi-dimensional Hermite polynomial the overlap of harmonic oscillator functions associated with different Born-Oppenheimer potentials. The presented approach is self-contained, only basic concepts of quantum mechanics associated with the harmonic oscillator system are needed. The obtained expression for the Franck-Condon overlaps is similar to the Ansbacher’s formula and equivalent to the one calculated by Malkin and Man’ko. However our final expression has the advantages that only real numbers are involved and it is straightforward to get the limit case of equal frequencies. Concerning the non-Condon factors two approaches leading to different formulas are considered, both of which reduce to triple sums of products of three Hermite polynomials. 相似文献
165.
Ana Luísa Daniel‐da‐Silva João Carlos Moura Bordado José Miguel Martín‐Martínez 《Journal of Polymer Science.Polymer Physics》2007,45(22):3034-3045
The degree of phase separation in several moisture‐cured poly(urethane urea)s (PUUs) was studied by FTIR spectroscopy, wide angle X‐ray diffraction (WAXD), and temperature‐modulated differential scanning calorimetry (TMDSC). This latter technique was shown to be particularly useful in analysing the degree of phase separation in PUU polymers. Both phase mixing and phase segregation coexisted in the PUUs and the degree of phase separation increased as the urea hard segment (HS) content in the PUU increased. The maximum solubility of urea HSs into the polyol soft segments (SSs) was achieved for 50 wt % urea HS content in diol‐based PUUs, whereas for triol‐based PUUs the highest solubility between HS and SS was reached for lower urea HS amount. Finally, the higher the urea HS content the higher the extent of phase separation in the PUU. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3034–3045, 2007 相似文献
166.
167.
Worm Müller Jac G. Otto Arno Behr und O. Hesse 《Fresenius' Journal of Analytical Chemistry》1884,23(1):82-85
Ohne Zusammenfassung 相似文献
168.
O. Haxel 《Zeitschrift für Physik A Hadrons and Nuclei》1939,112(11-12):681-688
169.
Koval'chukova O. V. Kuz'mina N. E. Strashnova S. B. Palkina K. K. Mordovina N. I. Zaitsev B. E. Nikitin S. V. 《Russian Journal of Coordination Chemistry》2003,29(2):123-128
Complexes of scandium, yttrium, and lanthanum nitrates with 3-chloro-9-hydroxy-2,4-dimethylpyrido[1,2-a]pyrimidinium perchlorate (HL1ClO4) and 9-hydroxy-2,4-dimethylpyrido[1,2-a]pyrimidinium perchlorate (HL2ClO4) were obtained. Their composition was formulated as Sc(LClO4)2(NO3) and M(LClO4)2(NO3)2 (L = L1 or L2; M = Y or La); structures for the complexes obtained were proposed. The crystal and molecular structure of HL1ClO4 was determined. Dissociation and complexation of HL1ClO4 and HL2ClO4 in aqueous ethanol were studied using the spectroscopic method. Ligand dissociation and complexation constants were calculated. It was shown that a chlorine-containing organic ligand only slightly changes the composition and stability of the metal complexes. 相似文献
170.
An upper bound for the best approximation of summable functions of several variables by trigonometric polynomials in the metric of L is determined in terms of Fourier coefficients. We consider functions representable by trigonometric series with certain symmetry of coefficients satisfying a multiple analog of the Sidon–Telyakovskii conditions. 相似文献