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111.
Daniel Hork Nataliya Benedyk 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5827-5837
Fine magnetite nanoparticles, both electrostatically stabilized and nonstabilized, were synthesized in situ by precipitation of Fe(II) and Fe(III) salts in alkaline medium. Magnetic poly(glycidyl methacrylate) (PGMA) microspheres with core‐shell structure, where Fe3O4 is the magnetic core and PGMA is the shell, were obtained by dispersion polymerization initiated with 2,2′‐azobisisobutyronitrile (AIBN), 4,4′‐azobis(4‐cyanovaleric acid) (ACVA), or ammonium persulfate (APS) in ethanol containing poly(vinylpyrrolidone) or ethylcellulose stabilizer in the presence of iron oxide ferrofluid. The average microsphere size ranged from 100 nm to 2 μm. The effects of the nature of ferrofluid, polymerization temperature, monomer, initiator, and stabilizer concentration on the PGMA particle size and polydispersity were studied. The particles contained 2–24 wt % of iron. AIBN produced larger microspheres than APS or ACVA. Polymers encapsulating electrostatically stabilized iron oxide particles contained lower amounts of oxirane groups compared with those obtained with untreated ferrofluid. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5827–5837, 2004 相似文献
112.
Sándor G?r?g 《Analytical sciences》2004,20(5):767-782
The development during the last 15 years and the state-of-the-art in the analysis of bulk steroid hormone drugs and hormone-like structures and pharmaceutical formulations made thereof are summarized. Other steroids (sterols, bile acids, cardiac glycosides, vitamins D) as well as biological-clinical aspects and pharmacokinetic and metabolic studies are excluded from this review. The state-of-the-art is summarized based on comparisons of monographs in the latest editions of the European Pharmacopoeia, United States Pharmacopoeia and the Japanese Pharmacopoeia. This is followed by sections dealing with new developments in the methodology for the fields of spectroscopic and spectrophotometric, chromatographic, electrophoretic and hyphenated techniques as well electroanalytical methods. The review is terminated by two problem-oriented sections: examples on impurity and degradation profiling as well as enantiomeric analysis. 相似文献
113.
Yoshio Suzuki Noriyuki Tanji Chikako Ikeda Aki Honda Kenji Ookubo Daniel Citterio Suzuki Koji 《Analytical sciences》2004,20(3):475-482
Novel labeling reagents, called MS probes, which possess a positively charged quaternary amine moiety and can transform a neutral analyte into a charged compound by simply mixing with the analyte and allowing the mixture to stand from several minutes to 30 min at room temperature or while heating to 50 degrees C, were designed and synthesized for the highly sensitive detection of carbonyl, alcohol, carboxylic acid and primary amine samples by electrospray ionization mass spectrometry (ESI-MS). The positively charged products can be detected with high sensitivity in an ESI-MS system, which is the most popular liquid MS instrument. All of the labeled products showed a remarkably large increase in the molecular-ion peak abundance detection sensitivity of over 500-fold at picomolar concentration levels compared to that of unlabeled analytes in an ESI-MS system. These MS probes, used together with liquid MS detection, are widely applicable as a convenient method for the highly sensitive detection of less than picomolar levels of analytes, and therefore greatly enhance the power of ESI-MS analysis. 相似文献
114.
Su Nee Tan Daniel Fornasiero Rossen Sedev John Ralston 《Colloids and surfaces. A, Physicochemical and engineering aspects》2004,250(1-3):307-315
The foam behaviour of low molecular weight polypropylene glycols (PPG) was investigated as a function of concentration and molecular weight (190–2000 g mol−1). For each polypropylene glycol, foam stability increases with concentration and passes through a maximum, beyond which foamability is suppressed as the solubility limit of the glycol is exceeded and droplets of glycol form. Light-scattering data as well as static and dynamic surface tension results provide the key information leading to these interpretations. A maximum in foamability was observed for the PPG molecules with increasing molecular weight (caused by a change in molecular conformation at the interface). This suppresses the Marangoni effect and leads to a decrease in foam stability. 相似文献
115.
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117.
The exponential functional of simple, symmetric random walks with negative
drift is an infinite polynomial Y = 1 + ξ1 + ξ1ξ2 + ξ1ξ2ξ3 + ⋯ of independent
and identically distributed non-negative random variables. It has moments that are
rational functions of the variables μ
k
= E(ξ
k
) < 1 with universal coefficients. It
turns out that such a coefficient is equal to the number of permutations with descent
set defined by the multiindex of the coefficient. A recursion enumerates all numbers
of permutations with given descent sets in the form of a Pascal-type triangle.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
118.
Periodica Mathematica Hungarica - In our paper we study the usage of partially defined Boolean functions (PDBFs) for generating cryptographically strong Boolean functions. A PDBF can be considered... 相似文献
119.
A note on a generalized Douglas space 总被引:1,自引:0,他引:1
Periodica Mathematica Hungarica - 相似文献
120.
In each of three consecutive years, 16 teachers were admitted to a program in which they participated in a study group to reform their teaching practices in mathematics. The 48 (total) elementary school teachers in this program were selected to ensure diversity of setting— urban and suburban, as well as public and parochial. Teachers routinely met with the study group for 1 year, engaging in follow‐up activities after that year. Surveys, interviews, and site visits showed that teachers underwent significant changes in their knowledge, beliefs, and teaching practices and were attempting to implement reform consistent with current standards. Teachers with 11 to 25 years of experience demonstrated the greatest changes. Long‐term effects of the program and its impact on colleagues within the building and district have yet to be studied. 相似文献