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941.
A new method for the determination of nine haloacetic acids (HAAs) with ion chromatography (IC) coupled to inductively coupled plasma mass spectrometry (ICP-MS) was developed. With the very hydrophilic anion-exchange column and steep gradient of sodium hydroxide, the nine HAAs could be well separated in 15 min. After suppression with an ASRS suppressor that was introduced in between IC and ICP-MS, the background was much decreased, the interference caused by sodium ion present in eluent was removed, and the sensitivities of HAAs were greatly improved. The chlorinated and brominated HAAs could be detected as 35ClO and 79Br without interference of the matrix due to the elemental selective ICP-MS. The detection limits for mono-, di-, trichloroacetic acids were between 15.6 and 23.6 microg/l. For the other six bromine-containing HAAs, the detection limits were between 0.34 and 0.99 microg/l. With the pretreatment of OnGuard Ag cartridge to remove high concentration of chloride in sample, the developed method could be applied to the determination of HAAs in many drinking water matrices.  相似文献   
942.
Alkanethiolate self-assembled monolayers (SAMs) of varied chain lengths were adsorbed upon Au-coated nerve microelectrodes and employed as protein-resistant spacers. The microelectrode spiraled as a cuff type can be used for restoring motor function via electrical stimulation on the peripheral nerve system; however, an increase of electrode impedance might occur during implantation. In this work, a thin-film SAMs treatment upon Au/polyimide (PI) surface of the microelectrode provided a hydrophobic characteristic, which retarded protein adsorption at the initial stage and subsequent pileup (or thickening) process. The protein-resistant effect exhibited comparable SAMs of different chain lengths adsorbed upon Au/PI surfaces. The increase of electrode impedance as a function of protein deposition time was mainly correlated with the addition of reactance that was associated with the pileup thickness of the deposited protein. Particularly, the SAMs-modified surface was capable to detach a significant portion of the accumulated protein from the protein-deposited SAMs/Au/PI, whereas the protein-deposited layers exhibited firm adhesion upon Au/PI surface. It is therefore very promising to apply thin-film SAMs adsorbed upon Au-coated surface for bioinvasive devices that have the need of functional electrical stimulations or sensing nerve signals during chronic implantation.  相似文献   
943.
A novel and convenient route for the synthesis of biologically potent and rare L-hexose derivatives from D-glucose is described. Conversion of diacetone-alpha-D-glucose (14) into 1,2:3,5-di-O-isopropylidene-beta-L-idofuranose (19) was efficiently carried out in two steps. Orthogonal isopropylidene rearrangement of compound 19 led to 1,2:5,6-di-O-isopropylidene-beta-L-idofuranose (27), which underwent regioselective epimerization at the C3 position to give the L-talo- and 3-functionalized L-idofuranosyl derivatives. Hydrolysis of compound 19 under acidic conditions furnished 1,6-anhydro-beta-L-idopyranose (35) in excellent yield, which was successfully transformed into the corresponding L-allo, L-altro, L-gulo, and L-ido derivatives via regioselective benzylation, benzoylation, triflation and nucleophilic substitution as the key steps. Applications of these 1,6-anhydro-beta-L-hexopyranoses as valuable building blocks to the syntheses of 4-methylcoumarin-7-yl-alpha-L-iduronic acid and the disaccharide moieties of bleomycin A(2) as well as heparan sulfate are highlighted.  相似文献   
944.
在硼氢化钾碱性溶液中对金属氢化物(MH)电极的表面进行化学还原处理,提高了MH电极的放电容量、活化性能和电催化活性.用其为负极组装的AA型MH-Ni电池进行了封口化成,电池放电容量达到1150mAh,5C下电池的放电容量达到0.2C下容量的80%以上,电池在1C100%DOD(放电深度)充放电条件下,循环寿命由原来的100次左右提高到200次以上  相似文献   
945.
The emulsifier-free emulsion polymerizations of styrene in the presence of about 1 wt% (related to styrene) of the water soluble comonomer, sodium methallyl sulfonate (NaMS), which has short hydrophobic group and strong hydrophilic ionic group, and of the initiator, potassium persulfate, are carried out. Under constant ionic strength, the number density of polymer particles (Np) is found to depend on 0.5-power of the initiator concentration and shows a minimum in the comonomer concentration plot. Under constant concentration of monomer, comonomer and initiator, Np is found to depend on ?1.1-power of the ionic strength. In the earlier period, the presence of styrene oligomer having MW about 1000 and water soluble poly(NaMS) or copolymer with high NaMS content suggests a micellar nucleation mechanism, by which the styrene oligomer behaves as emulsifier and the poly(NaMS) can either stabilize or destabilize the existing particles, depending on its concentration in the aqueous phase. The particle size is rather uniform having an uniformity very close to 1 (ca. 1.001) throughout the entire process. It is much larger than that of the conventional emulsion polymerization or emulsifier-free emulsion polymerization with the other comonomers by about 3 to 4 times in diameter or 27 to 64 times in volume, leading to that the average radical number in the particle could be much greater than 0.5. The (conversion)2/3 versus time plot is found to be linear from 6 to 50% conversion. During this period, for the conversion from 10 to 40% the polymerization rate increases twice but the particle volume increases four-fold. In addition, MWD shows bimodal (excluding the styrene oligomer peak in the earlier period) during the growth period. But the lower MW peak shifts to higher MW and become larger, while the higher MW peak decreases, and finally the MWD becomes single mode after 58.6% conversion. These results suggest a “gradient polymerization” or “transition stage to core-shell structure” in the earlier stage of particle growth and a “shell part polymerization” in the later stage.  相似文献   
946.
The reaction of phenyl lithium acetylide (2) with 2,6-diphenylpyrylium perchlorate (1) is solvent dependent. With diethyl ether as solvent, the isolated product differed from that previously reported and is reassingned as 2,6-diphenyl-4-phenylacetylenyl-4H-pyran (5). On the other hand, in THF the title compound (6) was obtained; its structure confirmed by single-crystal x-ray crystallography.  相似文献   
947.
本文采用家兔肺泡巨噬细胞(AM)存活率和细胞过氧化脂质(LPO)值为测定指标,研究了硅氧的聚合度对其细胞毒性的影响。结果表明:各种聚合度的硅氧都有一定的细胞毒性,聚合度愈大,细胞毒性也愈大。胶体SiO_2的粒径增大,其细胞毒性降低。十硅酸盐及粒径小于5nm的硅溶胶的细胞毒性大于α-石英。聚合度小于6的低聚硅酸及其盐、粒径18nm以上的硅溶胶以及硅胶H的毒性皆小于α-石英。本实验细胞存活率降低和过氧化脂质值升高的趋势基本一致,这表明硅氧可能主要与细胞表面膜作用,膜上磷脂等表面活性物质被氧化和变性,从而导致细胞损伤。  相似文献   
948.
The 2,5-dimethylthiophene (2,5-Me2T) ligand in the isomers Cp*Ir(η4-2,5-Me2T) (1) and Cp*Ir(C,S-2,5-Me2T) (2) is activated to react with the dimers Cp(CO)2M?M(CO)2Cp[M?Mo (3), W (4)] to give complexes (5,6) in which the thiophene is coordinated to three metals. Oxidation of 5 with Cp2Fe+ removes the Mo dimer to give Cp*Ir(η5-2,5-Me2T)2+. Reaction of 5 with CO displaces the Mo as [CpMo(CO)3]2 to give Cp*Ir(CO)(C,S-2,5-Me2T) (7). Ultraviolet photolysis of 1 provides a convenient route to the ring-opened isomer 2. Despite the remarkable nature of the thiophene coordination in 5 and 6, its reactivity does not suggest new pathways that would lead to the hydrodesulfurization of thiophenes.  相似文献   
949.
采用小沸点仪测定了马来酸酐和1,2-环己烷二羧酸二异丁酯二元系统在不同配料组成条件下的温度与压力数据,并通过内插法得到不同压力下的温度与配料组成的数据.进一步采用单纯形法优化NRTL方程参数,推算了平衡气液相组成,发现该二元系统具有最高压力恒沸点,且该恒沸点随压力的变化显著.当压力降低至20 kPa时, 由温度随气相组成的变化趋势知该恒沸点将趋于消失.  相似文献   
950.
The first successful attempt to construct 3D supramolecular frameworks with high-nuclear 3d-4f heterometallic clusters as a node is reported. The self-assembly of Ln3+, Cu2+ and amino acid in solution leads to the formation of two polymers, 35-nuclear complex [Sm6Cu29] 1 with a primitive cubic net-like structure and 36-nuclear complex [Nd6Cu30] 2 with a face-centred cubic network type structure. Glycine and L-proline, respectively, were used as ligands. It should be noted that 2 has a chiral framework. X-ray structure analyses show that 1 crystallizes in the triclinic P1 space group (a=19.6451(8), b=20.4682(8), c=20.7046(8) A, alpha=89.453(1), beta=66.290(1), gamma=68.572(1) degrees, V=7003.0(5) A3 and Z=1) and 2 belongs to the cubic P2(1)3 space group (a=b=c=32.4341(3) A, V=34 119.7(5) A3 and Z=4). Both complexes utilize Ln6Cu24 octahedral clusters as nodes and trans-Cu(amino acid)2 groups as bridges. Electrical conductivity measurements reveal that both polymers behave as semiconductors.  相似文献   
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