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S. A. Shevelev I. L. Dalinger V. I. Gulevskaya T. I. Cherkasova V. M. Vinogradov B. I. Ugrak A. M. Starosotnikov 《Chemistry of Heterocyclic Compounds》1999,35(3):363-373
Dehydrobromination of N-arylhydrazones of bromonitroformaldehyde (at 20°C) in the presence of alkali and ammonium salts of strong mineral acids, HNO3, silica gel, and Al2O3 forms mesoionic 3-aryl-1,2,3,4-oxatriazol-5-ones (3-arylazasydnones). The effect of the electronic properties of the aryl substituent on the course of the reaction is evaluated. This evaluation is used to develop a general method for preparing 3-arylazasydnones with various substituents including novel 3-hetarylazasydnone derivatives of pyrazole, 1,2,4-triazole and pyridine. Aromatic electronic effects (I, R, m, p) of the mesionic 1,2,3,4-oxatriazol-5-on-3-yl moiety are determined by19F NMR. A scheme is proposed for the dehydrobromination of the bromonitroformaldehyde N-arylhydrazones that includes the intermediate N-aryl-C-(nitro) nitrilimines, ArN––N=C+NO2, with subsequent isomerization of the latter into 3-arylazasydnones.N. D. Zelinskii Institute of Organic Chemistry of the Russian Academy of Sciences, Moscow 117913, RussiaTranslated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 413–424, March, 1999. 相似文献
23.
L. A. Trukhacheva V. I. Levina N. B. Grigor’ev A. P. Arzamastsev I. L. Dalinger I. A. Vatsadze G. P. Popova S. A. Shevelev V. G. Granik 《Russian Chemical Bulletin》2005,54(12):2813-2819
Alkaline hydrolysis of mono-and dinitro derivatives of five-membered heterocycles, viz., pyrazole, imidazole, 1,2,4-triazole, and isoxazole, is accompanied by the elimination of the nitro group in the form of
a nitrite anion. The hydrolysis kinetics was studied by the polarographic and photometric methods. The experimentally determined
hydrolysis rate constants depend on the nature of the heterocycle. A possible mechanism for hydrolytic transformations of
the compounds under study was proposed on the basis of the calculated thermodynamic parameters of the reaction (Δ G
≠, ΔH
≠, ΔS
≠).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2719–2725, December, 2005. 相似文献
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A. A. Zaitsev I. O. Kortusov I. L. Dalinger V. V. Kachala G. P. Popova S. A. Shevelev 《Russian Chemical Bulletin》2009,58(10):2118-2121
4-Methyl-3,5-dinitropyrazole prepared by nitration of 1,4-dimethylpyrazole readily reacts with methoxymethyl chloride and
methyl vinyl ketone in acetonitrile in the presence of a base giving 1-methoxymethyl-4-methyl-3,5-dinitropyrazole and 4-methyl-3,5-dinitro-1-(3-oxobutyl)pyrazole,
respectively. The action of the thioglycolanilide anion on 4-methyl-3,5-dinitro-1-(3-oxobutyl)pyrazole results only in the
removal of 1-protecting group and the formation of 2-[(3-oxobutyl)thio]acetanilide, while the action of anionic S-nucleophiles
on 1-methoxymethyl-4-methyl-3,5-dinitropyrazole leads to the substitution products of the 5-NO2 group in which the methoxymethyl group can be removed by acid hydrolysis. 相似文献
27.
Liquid-phase synthesis of combinatorial libraries based on 7-trifluoromethyl-substituted pyrazolo[1,5-a]pyrimidine scaffold 总被引:1,自引:0,他引:1
Dalinger IL Vatsadse IA Shevelev SA Ivachtchenko AV 《Journal of combinatorial chemistry》2005,7(2):236-245
The parallel solution-phase synthesis of more than 2200 7-trifluoromethyl-substituted pyrazolo[1,5-a]pyrimidine and 4,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine carboxamides on a 50-100-mg scale has been accomplished. Key reactions include assembly of the pyrazolo[1,5-a]pyrimidine ring by condensation of 5-aminopyrazole derivatives with the corresponding trifluoromethyl-beta-diketones. The libraries from libraries were then obtained in good yields and purities using solution-phase acylation and reduction methodologies. Simple manual techniques for parallel reactions using special CombiSyn synthesizers were coupled with easy purification procedures (crystallization from the reaction mixtures) to give high-purity final products. The scope and limitations of the developed approach are discussed. 相似文献
28.
Aye Aye Mar Ali Koohang Nathan D.Majewski Erika L.Szotek David A.Eiznhamer Michael T.Flavin 《中国化学快报》2009,(10)
28-Carboxymethoxy lupane tritepenoids 3 and 4 were synthesized by alkylation of betulin with the THP protected 2- hydroxyethyl iodide followed by oxidation and reduction.Direct reaction of betulin(5) or betulone(10) with ethyl bromoacetate led to 28-O-acylation,instead of 28-O-alkylation.The targeted compounds 3 and 4 were not cytotoxic at the highest concentration tested(75μmol/L),suggesting that elongation of the chain length at the 28-position in both betulinic acid(1) and betulonic acid(2) was detrim... 相似文献
29.
Dalinger I. L. Cherkasova T. I. Popova G. P. Shkineva T. K. Vatsadze I. A. Shevelev S. A. Kanishchev M. I. 《Russian Chemical Bulletin》2009,58(2):410-413
For the first time pyrazole containing three nitro groups in the pyrazole cycle, viz., 1,3,4-tri-nitropyrazole, was obtained by N-nitration of 3,4-dinitropyrazole. 1,3,4-Trinitropyrazole enters the cine-substitution reaction of N-nitro group under the action of 0-, N-, and C-nucleophyls under mild conditions. Thus, general method of synthesis of 5-substituted
3,4-dinitropyrazoles containing free NH fragment was worked out. 相似文献
30.
Mozhaitsev E. S. Ponomarev K. Y. Patrusheva O. S. Medvedko A. V. Dalinger A. I. Rogachev A. D. Komarova N. I. Korchagina D. V. Suslov E. V. Volcho K. P. Salakhutdinov N. F. Vatsadze S. Z. 《Russian Journal of Organic Chemistry》2020,56(11):1969-1981
Russian Journal of Organic Chemistry - A number of chiral chelating conjugates combining a bispidine central backbone and one or two pinene side fragments were synthesized. It was shown for the... 相似文献