Hydrogen Permeation Properties of Perovskite-type BaCe_(0.9)Mn_(0.1)O_(3-δ)Dense Ceramic Membrane

In recent years, mixed-conducting oxides, in which both protonic and electronic charge carriers exist, have received increasing attentions1. Ceramic membranes made of such materials are semipermeable to hydrogen at elevated temperatures. In the early 1980s, Iwahara et al. first reported protonic conduction in SrCeO3-based materials2. Later, BaCeO3 system was extensively studied because of its higher conductivities. However, the electronic conductivity of rare earth doped-BaCeO3 ceramic…     

A Novel Zirconium-Based Perovskite-Type Membrane Material for Oxygen Permeation

Zirconia with fluorite structure stabilized by doping rare earth or alkaline earth metal oxides such as Y2O3 and CaO (YSZ and CSZ) is a class of traditional mixed conducting membrane materials, which have been widely investigated for their high oxygen ionic conductivity and excellent chemical and thermal stability1-3. But the electronic conductivity of these materials is very small, unless operated with an internal or external circuitry, the oxygen flux through membranes in usual ranges of …     

A New Rapid Determination Method of Soil Organic Carbon Adsorption Coefficients of Pesticides with Soil Column Liquid Chromatography

Recent legislation in many countries requires extensive testing of all manufactured chemicals for environmental evaluation and registration. Among the requirements are water solubility, solvent (usually octanol) - water partition coefficient, soil adsorption and bioconcentration factors in aquatic organisms. Soil adsorption influences the extent of vaporization of a compound from the soil surface and its lateral (run-off) or vertical transport including groundwater contamination. Additionally,…     

Bcklund transformation, non-local symmetry and exact solutions for (2+1)-dimensional variable coefficient generalized KP equations

IntroductionDuring the study of water wave, many completely iategrable models were derived, such as(1+1)-dimensional KdV equation, MKdV equation, (2+1)-dimensional KdV equation, Boussinesq equation and WBK equations etc. Many properties of these models had been researched,such as BAcklund transformation (BT), converse rules, N-soliton solutions and Painleve property etc.II--8]. In this paper, we would like to consider (2+1)-dimensional variable coefficientgeneralized KP equation which …     

β-榄香烯振动光谱的量子化学从头计算

利用G98及GAMESS从头计算程序的RHF／6－31方法,对β－榄香烯的全部振动基频作了计算,并与实测红外光谱做了对比,归属了它们的振动模式,讨论了它们的特征基频,并对理论计算的振动频率进行了标度校正。     

Isolation and Purification of Unstable Iridoid Glucosides from Traditional Chinese Medicine by Preparative High Performance Liquid Chromatography Coupled with Solid-phase Extraction

An efficient preparative method was successfully developed for isolation and purification of unstable components from medicinal plant extracts, using a combined method of preparative high performance liquid chro-matography(HPLC) and solid-phase extraction(SPE). The aim of this study was to obtain an effective method with high preparative efficiency and importantly to avoid the transformation of unstable compounds. The preparative HPLC system was based on an LC/MS controlled four-channel autopurification sys...     

First-principles calculation of core-level binding energy shift in surface chemical processes

Combined with third generation synchrotron radiation light sources, X-ray photoelectron spectroscopy (XPS) with higher energy resolution, brilliance, enhanced surface sensitivity and photoemission cross section in real time found extensive applications in solid-gas interface chemistry. This paper reports the calculation of the core-level binding energy shifts (CLS) using the first-principles density functional theory. The interplay between the CLS calculations and XPS measurements to uncover the structures,...     

甲基吡啶侧链金属化和烷基化反应的研究

甲基吡啶侧链上的氢易于质子化被碱金属所取代,但传统的侧链金属化的方法,其实验操作都比较繁复。前文报道,吡啶与金属钠在乙醚回流中可形成吡啶自由基负离子钠络合物(C_5H_5N~-Na~ ),它是一种有效的金属     

NATIONAL STANDARD OF HEAT CAPACITY MEASUREMENT OF SOLIDS IN THE RANGE OF 4.2—90K——AN AUTOMATED ADIABATIC CALORIMETER FROM 25 TO 90K AND MOLAR HEAT CAPACITIES OF α-ALUMINA

The construction of an automated adiabatic calorimeter for heat capacity measurement ofsolids in the temperature range of 25- 90K is described in detail. The sample vessel of thecalorimeter has thin radial vanes which make no contact with its inner wall and are distrib-uted evenly, thus greatly improving the internal thermal equilibration of the vessel. Theprecision of temperature control for the adiabatic shields and electrical leads of the calori-metric system are heightened to a great extent by using the high precision ACD- 79 modeladiabatic controller specially developed by us for this purpose. Measurements of the heatcapacities of high purity α-Al_2O_3, one of the internationally-accepted standard referencematerials, agree with those of the National Bureau of Standards (NBS), USA within ±0.3%,demonstrating the reliability of this apparatus.     

傅里哀变换红外发射光谱法研究金属氧化物催化剂——Ⅰ.实验建立及氧化钼的还原-氧化研究

本文报导了傅里哀变换红外发射光谱法研究多相氧化物催化剂的实验装置的建立及实验条件的考察。设计加工了一个温度范围宽,可在各种气氛和真空条件下原位研究氧化物催化剂的红外发射池。以MoO_3为例,考察了样品厚度,测试温度对发射光谱的影响。当样品量小于1mm·cm~(-2)时,随样品量增加,谱峰强度线性增加,但峰形不发生变化。当样品量高于1mg.cm~(-2)时,随样品量增加,谱图严重畸变。随样品温度升高,谱峰强度近似线性增加。并用该方法研究了MoO_3在还原和再氧化过程中表面氧物种的变化。结果表明桥式MO?O?Mo物种比端基Mo=O物种较易还原,再氧化时,Mo=O物种比Mo?O?Mo物种优先形成。