Synthesis of Two Novel Rhenium（I） Bipyridyl Photosensitive Dyes

Two novel rhenium(I) 2, 2′-bipyridyl complexes, [(4,4′-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and [(4,4′-di-COOEt-bipy) Re (CO)3 (NCS)], a model complex [(4,4′-di-COOEt-bipy) Re (CO)3 (pyridine)PF6], were synthesized. Their ground state electronic spectra and emission spectra were measured in acetonitrile. The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN.     

N2（A）及N（2D）对IF（X）的传能研究

在微波放电系统中,对NH_3-F-F_2-CF_3I体系进行研究,结果表明,向IF(X)传能的诸多媒介中,N_2(A)及N(~2D)起着主要作用,并且这一结论在经微波激发后的N_2与CF_3I的直接反应中得到了进一步证实。     

~(13)C NMR法研究环氧戊烯醛的热异构化

本文利用~(13)C NMR方法研究顺式环氧戊烯醛(1)的热异构化。测定了1在受热前后的~(13)CNMR谱,标识了它和它的热异构化产物的~(13)C NMR谱线;通过对异构化过程的动力学考察,表明1的热转化遵从一级反应规律,分别求出了80,100,120和140℃下的反应速度常数,并估算了活化能;同时也监测了异构化产物的变化过程。     

Capillary Zone Electrophoresis Investigation of Interactions between Granulocyte-colony Stimulating Factor and Dextran Sulfate／Carrageenan Oligosaccharide

Granulocyte-colony stimulating factor (G-CSF) is an O-glycosylated glycoprotein. G-CSF stimulates the proliferation and differentiation of hematopoietic progenitor cells committed to the neutrophil/granulocyte lineage in a dose-dependent manner. The most important application of G-CSF is in the treatment of transient phases of leukopenia following chemotherapy and/or radiotherapy. Using capillary zone electrophoresis (CZE), former studies showed that G-CSF could interact with polysulfa…     

含分层损伤复合材料加筋层合板的分层扩展研究

建立了复合材料加筋结构的后屈曲和分层损伤扩展行为的数值模拟方法．基于Mindlin一阶剪切理论和von-Karman大挠度理论的层合板和层合梁单元，提出了含分层损伤复合材料加筋层合板分层扩展行为的有限元分析方法；利用虚裂纹闭合技术计算分层前缘的总能量释放率，并采用总能量释放率准则分层扩展判据，结合自适应网格移动技术，对在压缩载荷作用下的具有不同加筋形式，不同初始分层面积和形状的加筋板结构分层扩展行为进行了数值模拟研究，在分析中还考虑了加筋刚度、位置和分布，分层形状和大小、边界支撑强弱和分层前缘的接触效应对结构分层扩展行为的影响．本所提出的研究方法对工程界关于复合材料结构的设计具有重要意义．     

PRODUCTION OF LIGHT ALKENES FROM SYNGAS OVER Fe-MnO CATALYST SUPPORTED ON IIA METAL OXIDE

The alkene selectivity of CO hvdrogenation over Fe-MnO catalystis improved obviously by using NA metal oxide as catalyst support.Bettercatalytic pertformance of catalyst Fe-MnO/MgO can be achieved withaddition of LA metal as promoter.The selectivity is insensitive totemperature.but not to syngas space velocity.Two kinds of coking(I and Ⅱ)will form over the catalyst during CO hydrogenation.lt is interesting thatcoking(I)is favorable for production of light alkenes while cokiing(lI)is not.Other more.LA metal oxide supported Fe-MnO catalyst is able to inhibit thesecondary reactions of ethylene and hydrogenation of propylene.which isfavorable for the formation of light alkenes.     

Reaction kinetic behavior of different carbon monoxide adspecies on palladium-alumina during oxidation: an in-situ IR study

Carbon monoxide oxidation on Pd(10 w.t.%)-alumina was studied by in-situ infrared spectroscopy. It was found that the oxidation reactivities vary with different CO adspecies: linear COad > 2-fold bridged COad > multi-bridged COad.     

低温等离子体物理进展

概述了低温等离子体物理研究现状、发展及其应用      

结构设计中的混沌优化方法及其改进

在变尺度混沌优化方法研究中．结合结构优化问题的特点,提出了一种改进的混沌优化求解算法,用来解决带有多种约束条件的结构优化设计问题。在有限元分析和优化设计软件JEFIX中实现了上述算法．并通过数值算例讨论了变尺度混沌优化方法在结构优化中的可行性及存在的问题,得到了一些重要结论。     

Efficient and practical synthesis of (R)-2-methylpyrrolidine

An efficient, practical, and high yielding synthesis of (R)-2-methylpyrrolidine is described. The sequence allows for the scalable preparation of the target compound in just four synthetic steps and proceeds in 83% overall yield and >99% optical purity from readily available starting materials.