氧碘化学激光器增益谱线的实验研究

 利用可调谐二极管激光器为探测光源, 直接测量了氧碘化学激光器的增益谱线的精细结构及其各谱线所占比例。同时用碘原子吸收池标定了六条谱线。     

氧碘化学激光器UR-90腔光束质量研究

 概括了光束质量的表示方法, 由衍射极限倍数的定义出发, 提出重点在于选取光斑直径, 而且可把光斑测量归结到电子测试仪对剪切电平的测量上。给出了电子测试仪的测试原理, 由所测光斑直径计算了氧碘化学激光器U R290腔的光束质量指标—衍射极限倍数, 达到了1.2～1.6倍衍射极限, 最后进行了误差讨论。     

丝蛋白分子的红外光谱研究

本文记录并研究了桑蚕丝、柞蚕丝、天蚕丝和天柞杂交蚕丝等几类共42种蚕丝样品的红外光谱,确定了柞丝类和桑丝类两大类蚕丝样品在红外光谱方面的差别。从而为鉴别蚕丝样品的种类建立起一种简便易行的方法。通过对各类样品的红外光谱数据处理,计算了某些谱带的相对强度比,获得了一些半定量的规律性结果。     

液相色谱中的半峰宽规律

本文介绍通过相同组分、不同配比冲洗剂等度和梯度冲洗样品的实验,首次发现在液相色谱中,溶质的色谱峰半宽度与保留值间存在同一线性关系;在梯度冲洗时流出组分的色谱峰半宽度与虚拟保留值间同样存在线性关系。该结果证明,我们提出的组分在柱末端有相近的以长度为量纲的谱带半宽度的正确性,同时该结果对梯度最佳分离条件的预测亦很有益。     

Recognition Interactions of Metal-complexing Imprinted Polymer

Molecularly imprinted polymer, exhibiting considerable enantioselectivity for L-mandelic acid, was prepared using metal coordination-chelation interaction. By evaluating the recognition characteristics in the chromatographic mode, the recognition interactions were proposed: specific and nonspecific metal coordination-chelation interaction and hydrophobic interaction were responsible for substrate binding on metal-complexing imprinted polymer; while the selective recognition only came from specific metal coordination-chelation interaction and specific hydrophobic interaction.     

Estimation of the Bezout number for piecewise algebraic curve

A piecewise algebraic curve is a curve determined by the zero set of a bivariate spline function.In this paper.a coniecture on trianguation is confirmed The relation between the piecewise linear algebraiccurve and four-color conjecture is also presented.By Morgan-Scott triangulation, we will show the instabilityof Bezout number of piecewise algebraic curves. By using the combinatorial optimization method,an upper     

A Green Synthesis of 2-Ethylanthraquinone by Dehydration of 2-(4''''-ethylbenzoyl) benzoic Acid over Solid Acid Catalysts

2-EAQ is an important intermediate for the synthesis of hydrogen peroxide, pharmaceu- ticals, pesticides, and dyes. With the increasing demand for hydrogen peroxide, it needs to enhance the yields of 2-EAQ. However, in the conventional process, concentrated H2SO41-2 is employed as the catalyst in the dehydration of BE acid for the synthesis of 2-EAQ, which produces a series of environmental impacts and safety concerns. For these reasons, a substitute process, which has little or no hazard…     

非水溶性药物潜在靶蛋白筛选方法探索

针对化学蛋白质组学在筛选非水溶性药物的靶蛋白中存在的问题,建立了以非水溶性药物颗粒为载体的靶蛋白筛选方法.通过避免药物固定化,不仅可以保留全部的药物官能团,而且减少了蛋白质在固载基质上的非特异性吸附,可提高获得数据的可信度.将非溶性药物地塞米松颗粒直接与人小细胞肺癌H446细胞提取蛋白质通过间歇性振荡孵育24h,然后采用缓冲液清洗药物颗粒,最后对药物颗粒特异性结合的蛋白质进行酶解和分离鉴定.结果表明,筛选出41个潜在的药物靶蛋白,参与了与DEX药物作用机理相关的多种蛋白质代谢通路和糖代谢通路,同时还发现部分蛋白质参与了帕金森症疾病过程.     

块对偶Toeplitz算子的乘积

本文刻画了向量值Bergman空间上块对偶Toeplitz算子有界性和紧性,给出了块对偶Toeplitz算子的乘积是块对偶Toeplitz算子的充要条件.     

Highly active bifunctional salenTi(Ⅳ) catalysts for asymmetric cyanosilylation of aldehydes and TMSCN

A novel enantiopure salen ligand bearing a diphenylphosphine oxide on the 3-position of one aromatic ring was synthesized and combined with Ti(Oi-Pr)_4 as a monometallic bifunctional catalyst for asymmetric cyanosilylation reaction of aldehydes with tnmethylsilyl cyanide(TMSCN).The catalyst system exhibited excellent activity and moderate enantioselectivity.The addition of TMSCN to 4-nitrobenzaldehyde in the presence of 1 mol%catalyst loading could complete within 10 min at ambient temperature. An intram...