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51.
Fotsop DF Roussi F Leverrier A Bretéché A Guéritte F 《The Journal of organic chemistry》2010,75(21):7412-7415
A short, convergent, and selective synthesis of meiogynin A, an inhibitor of the antiapoptotic protein Bcl-xL, has been performed. This synthesis, based on a biomimetic approach, allowed the determination of its absolute configuration. Three isomers of meiogynin A have also been elaborated. One of these was found to be three times more potent than the natural compound. 相似文献
52.
Kamel Khimeche Abdallah Dahmani Ilham Mokbel 《The Journal of chemical thermodynamics》2010,42(7):829-833
The vapour pressures of liquid {3-diethylaminopropylamine (3-DEPA) + cyclohexane} were measured by a static method between T = (273.15 and 363.15) K at 10 K intervals. The excess molar volumes VE at 298.15 K and excess molar enthalpies HE at 303.15 K were also measured. The molar excess Gibbs free energies GE were obtained with Barker’s method and fitted to the Redlich–Kister equation. The Wilson equation was also used. Deviations between experimental and predicted GE and HE, by using DISQUAC model, were evaluated 相似文献
53.
Ahmed Mekki Kamel Khimeche Abdallah Dahmani 《The Journal of chemical thermodynamics》2010,42(8):1050-1055
A differential scanning calorimetry (d.s.c.) was used to determine binary (solid + liquid) phase equilibria (SLE) for four binary mixtures, viz. (n-nitrosodiphenylamine + diphenylamine), (2-nitrodiphenylamine + ethyl centralite), (2,4-dinitro-N-ethylaniline + methyl centralite), and (2,4-diphenylamine + 4,4′-dinitroethylcentralite). These compounds are used as stabilizers in gun powders and propellants. Results obtained with this technique are compared with those correlated by NRTL and ideal models. It was found out that all the systems are simple eutectic systems and deviations between experimental and predicted SLE results were observed. 相似文献
54.
In this paper the effective mass approximation and the k·p multi-band models, describing quantum evolution of electrons in
a crystal lattice, are discussed. Electrons are assumed to move in both a periodic potential and a macroscopic one. The typical
period e{\epsilon} of the periodic potential is assumed to be very small, while the macroscopic potential acts on a much bigger length scale.
Such homogenization asymptotic is investigated by using the envelope-function decomposition of the electron wave function.
If the external potential is smooth enough, the k·p and effective mass models, well known in solid-state physics, are proved
to be close (in the strong sense) to the exact dynamics. Moreover, the position density of the electrons is proved to converge
weakly to its effective mass approximation. 相似文献
55.
Search for a standard model Higgs boson in the H→ZZ→ℓ(+)ℓ(-)νν decay channel with the ATLAS detector
Aad G Abbott B Abdallah J Abdelalim AA Abdesselam A Abdinov O Abi B Abolins M Abramowicz H Abreu H Acerbi E Acharya BS Adams DL Addy TN Adelman J Aderholz M Adomeit S Adragna P Adye T Aefsky S Aguilar-Saavedra JA Aharrouche M Ahlen SP Ahles F Ahmad A Ahsan M Aielli G Akdogan T Åkesson TP Akimoto G Akimov AV Akiyama A Alam MS Alam MA Albert J Albrand S Aleksa M Aleksandrov IN Alessandria F Alexa C Alexander G Alexandre G Alexopoulos T Alhroob M Aliev M Alimonti G Alison J Aliyev M Allport PP 《Physical review letters》2011,107(22):221802
A search for a heavy standard model Higgs boson decaying via H→ZZ→→?(+)?(-)νν, where ?=e, μ, is presented. It is based on proton-proton collision data at √s=7 TeV, collected by the ATLAS experiment at the LHC in the first half of 2011 and corresponding to an integrated luminosity of 1.04 fb(-1). The data are compared to the expected standard model backgrounds. The data and the background expectations are found to be in agreement and upper limits are placed on the Higgs boson production cross section over the entire mass window considered; in particular, the production of a standard model Higgs boson is excluded in the region 340相似文献
56.
N. Seeburrun H. H. Abdallah E. F. Archibong P. Ramasami 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2011,63(3):351-358
We hereby report a theoretical study on the equilibrium geometries, electronic structures and harmonic vibrational frequencies
of Ga2Se3, Ga3Se2 and their anions. The ground and low-lying excited states of Ga2Se3−, Ga2Se3, Ga3Se2− and Ga3Se2 are studied at the B3LYP and/or MP2 and CCSD(T) levels in conjunction with 6-311+G(d) and 6-311+G(2df) one particle basis
sets. Ga2Se2− adopts the C2v
kite geometry while Ga2Se3 has a ‘V’ geometry. Ga3Se2− has a three-dimensional ‘D3h
’ geometry and Ga3Se2 prefers the three-dimensional ‘C2v
’ structure. Electron detachment energies from the ground electronic states of the anions to several neutral states are reported
and discussed. At CCSD(T)//MP2 level, the adiabatic electron affinity (AEA) of Ga2Se3 is calculated to be 3.23 eV when using the 6-311+G(2df) basis set and that of Ga3Se2 is 2.77 eV with the 6-311+G(d) basis set. The findings of this research are analyzed and compared with gallium oxide and
sulfide analogues. 相似文献
57.
Mahmoud Hachemane Mohamed Abdelwahab Benbitour Abdallah Smida 《Foundations of Physics》1997,27(4):579-594
Along the lines of a previous work, the geometrical structure of Hibert bundles describing extended quantum free particles
is repeated with Galilei external and internal independent symmetries. Then, in order to introduce the interaction, this structure
is extended by replacing configuration and momentum spaces by the socelled spaces of trajectories and extended velocity boosts,
respectively. These provide representations giving the probability amplitudes for the particle to follow certain trajectories.
The interaction can be introduced in the transformation law from functions on the space of trajectories (free dynamics) to
functions on spacetime (intracting dynamics). This transformation law, which makes use of a universal distribution, is seen
as a functional in our work according to a quantum functional theory which generalizes the ideas of de Broglie. Intertwining
of induced representations gives the free propagator in the space of trajectories and, henceforth, the propagator with interaction
in space-time for the extended particle. 相似文献
58.
The vapour pressuresof liquid cyclohexane + N, N, N′, N′-tetramethylalkanediamine, (CH3)2 N(CH2)uN(CH3)2 (u = 1,2) + cyclohexane mixtures were measured by a static method between 303.15 and 343.15 K at 10 K intervals. The excess molar enthalpies at 303.15 K were also measured.
The molar excess Gibbs energies, calculated from the vapour-liquid equilibrium data, and the molar excess enthalpies compare satisfactorily with group contribution (DISQUAC) predictions.
The proximity effect of N atoms produces a regular decrease of the interactional parameters. 相似文献
59.
M.M. Elseweidy N.N. Younis S.E. Elswefy F.R. Abdallah S.I. El-Dahmy G. Elnagar 《Natural product research》2015,29(10):961-965
The anti-atherogenic potentials of total ginger (Zingiber officinale) extract (TGE) or curcuminoids extracted from turmeric (Curcuma longa), members of family Zingiberaceae, were compared in hypercholesterolaemia. Rabbits were fed either normal or atherogenic diet. The rabbits on atherogenic diet received treatments with TGE or curcumenoids and placebo concurrently for 6 weeks (n = 6). The anti-atherogenic effects of curcuminoids and ginger are mediated via multiple mechanisms. This effect was correlated with their ability to lower cholesteryl ester transfer protein activity. Ginger extract exerted preferential effects on plasma lipids, reverse cholesterol transport, cholesterol synthesis and inflammatory status. Curcuminoids, however, showed superior antioxidant activity. 相似文献
60.