全文获取类型
收费全文 | 373篇 |
免费 | 14篇 |
国内免费 | 2篇 |
专业分类
化学 | 288篇 |
晶体学 | 3篇 |
力学 | 8篇 |
数学 | 60篇 |
物理学 | 30篇 |
出版年
2024年 | 1篇 |
2023年 | 7篇 |
2022年 | 18篇 |
2021年 | 22篇 |
2020年 | 19篇 |
2019年 | 8篇 |
2018年 | 8篇 |
2017年 | 13篇 |
2016年 | 10篇 |
2015年 | 17篇 |
2014年 | 14篇 |
2013年 | 14篇 |
2012年 | 20篇 |
2011年 | 28篇 |
2010年 | 20篇 |
2009年 | 12篇 |
2008年 | 30篇 |
2007年 | 22篇 |
2006年 | 14篇 |
2005年 | 20篇 |
2004年 | 14篇 |
2003年 | 17篇 |
2002年 | 11篇 |
2001年 | 7篇 |
2000年 | 5篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1993年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有389条查询结果,搜索用时 0 毫秒
41.
Two unprecedented degraded sterols, aplykurodinone-1 (1) and -2 (2), have been isolated from the skin of the marine anaspidean Syphonota geographica, collected along the coasts of Greece. The structures and the relative stereochemistry were established by spectroscopic analysis and confirmed by chemical correlation with related known compounds. 相似文献
42.
ágnes Horváth István Hermecz Marianna Pongor-Csákvári Zoltán Mészáros József Kökösi Gábor Tóth áron Szöllósy 《Journal of heterocyclic chemistry》1984,21(1):219-224
The structures of the title compounds bearing a five-, six- or seven-membered A ring have been investigated by uv and 1H and 13C nmr spectroscopy. The imine-enol-enamine (I-II-III) tautomerism of these compounds depends greatly on the ring size. A significant solvent-dependence is observed only for the five-membered-ring compounds 1 and 2 , which in ethanolic solution exist predominantly in the imine form I, and in chloroform solution in the enol form II. The compounds with a six-membered A ring, 3 and 4 , are mainly in the enamine form III. On protonation, 3 and 4 change into the E and Z isomeric mixture of the enol tautomer II. The seven-membered-ring compound 5 is a mixture of the imine I and the enamine III tautomers. 相似文献
43.
A Highly Luminescent Tetramer from a Weakly Emitting Monomer: Acid‐ and Redox‐Controlled Multiple Complexation by Cucurbit[7]uril 下载免费PDF全文
Dr. Giacomo Bergamini Andrea Fermi Marianna Marchini Mirko Locritani Prof. Alberto Credi Prof. Margherita Venturi Prof. Fabrizia Negri Prof. Paola Ceroni Dr. Massimo Baroncini 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(23):7054-7060
The tetrahedral, shape‐persistent molecule 1 4+, containing four pyridylpyridinium units connected through a central carbon atom, exhibits unexpected photophysical properties including a substantially redshifted absorption (2350 cm?1) and a very strong fluorescence (Φem=40 %), compared with the monomer 2 + (Φem=0.4 %). Density functional theory calculations on the structure and spectroscopic properties of 1 4+ and 2 + show that exciton interactions, homoconjugation, and orbital nature account for the observed differences in their photophysical properties. The protonated tetramer binds four cucurbit[7]uril molecules and the host/guest interactions can be controlled by chemical (acid/base) as well as redox stimuli. 相似文献
44.
Marianna Csörnyei Paul D. Humke 《Journal of Mathematical Analysis and Applications》2005,305(2):546-559
Properties of first-return integrals of real functions defined on the unit interval are explored. In particular, first-return integrals are shown to be continuous but not absolutely continuous. 相似文献
45.
Veronica Zaconte Marco Casolino Luca Di Fino Chiara La Tessa Marianna Larosa Livio Narici Piergiorgio Picozza 《Radiation measurements》2010,45(2):168-172
The ALTEA (Anomalous Long Term Effects on Astronauts) detector was used to characterize the radiation environment inside the USLab of the International Space Station (ISS), where it measured the abundances of ions from Be to Fe. We compare the ALTEA results with Alteino results obtained in the PIRS module of the Russian segment of the ISS, and normalize to the high energy Si abundances given by Simpson. These are the first particle spectral measurements, which include ions up to Fe, performed in the USLab. The small differences observed between those made inside the USLab and the Simpson abundances can be attributed to the transport through the spacecraft hull. However, the low abundance of Fe cannot be attributed to only this process. 相似文献
46.
Addamo M Bellardita M Di Paola A Palmisano L 《Chemical communications (Cambridge, England)》2006,(47):4943-4945
Photoactive films consisting of pure anatase, brookite or rutile TiO2 were prepared by dip coating from water dispersions obtained by using TiCl4 as the precursor under similar mild experimental conditions. 相似文献
47.
In the context of augmented Lagrangian approaches for solving semidefinite programming problems, we investigate the possibility of eliminating the positive semidefinite constraint on the dual matrix by employing a factorization. Hints on how to deal with the resulting unconstrained maximization of the augmented Lagrangian are given. We further use the approximate maximum of the augmented Lagrangian with the aim of improving the convergence rate of alternating direction augmented Lagrangian frameworks. Numerical results are reported, showing the benefits of the approach. 相似文献
48.
Results of compactness for vector-valued F-seminormed function spaces and a general Vitali’s compactness criterion under the W-property are exhibited.
相似文献49.
Linear Complementarity Problems (LCPs) belong to the class of
\mathbbNP{\mathbb{NP}} -complete problems. Therefore we cannot expect a polynomial time solution method for LCPs without requiring some special property of the coefficient matrix. Our aim is to construct interior point algorithms which,
according to the duality theorem in EP (Existentially Polynomial-time) form, in polynomial time either give a solution of
the original problem or detects the lack of property P*([(k)\tilde]){\mathcal{P}_*(\tilde\kappa)} , with arbitrary large, but apriori fixed [(k)\tilde]{\tilde\kappa}). In the latter case, the algorithms give a polynomial size certificate depending on parameter [(k)\tilde]{\tilde{\kappa}} , the initial interior point and the input size of the LCP). We give the general idea of an EP-modification of interior point algorithms and adapt this modification to long-step path-following
interior point algorithms. 相似文献
50.
Hoimin Jung Mannkyu Hong Marianna Marchini Marco Villa Philipp S. Steinlandt Xiaoqiang Huang Marcel Hemming Eric Meggers Paola Ceroni Jiyong Park Mu-Hyun Baik 《Chemical science》2021,12(28):9673
The mechanism of [2 + 2] cycloadditions activated by visible light and catalyzed by bis-cyclometalated Rh(iii) and Ir(iii) photocatalysts was investigated, combining density functional theory calculations and spectroscopic techniques. Experimental observations show that the Rh-based photocatalyst produces excellent yield and enantioselectivity whereas the Ir-photocatalyst yields racemates. Two different mechanistic features were found to compete with each other, namely the direct photoactivation of the catalyst–substrate complex and outer-sphere triplet energy transfer. Our integrated analysis suggests that the direct photocatalysis is the inner working of the Rh-catalyzed reaction, whereas the Ir catalyst serves as a triplet sensitizer that activates cycloaddition via an outer-sphere triplet excited state energy transfer mechanism.The mechanism of [2 + 2] cycloadditions activated by visible light and catalyzed by bis-cyclometalated Rh(iii) and Ir(iii) photocatalysts was investigated, combining density functional theory calculations and spectroscopic techniques. 相似文献