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排序方式: 共有391条查询结果,搜索用时 15 毫秒
31.
Peter D. Mlynek Masaki Kawano Michael A. Kozee Lawrence F. Dahl 《Journal of Cluster Science》2001,12(1):313-338
Reactions of [Ni6(CO)12]2- (1) with CuBr2 have given rise in small yields (10%) to the first example of a close-packed copper-nickel carbonyl cluster; its formulation as [CuxNi35-x(CO)40]5- (with x=3 or 5) is based upon a low-temperature CCD X-ray crystallographic determination coupled with an elemental analysis and X-ray fluorescence measurements. This air-unstable black pentaanion (2) together with one co-crystallized bromide anion, six [NMe4]+ counterions, and one solvated acetone molecule comprise the crystallographic independent part in a monoclinic unit cell of P21/n symmetry (with Z=4). The geometrically unprecedented 35-atom hcp M(A)2M(B)3Ni30 polyhedron of pseudo-D3h symmetry consists of a central 15-atom equilateral 4M(B)3Ni12 triangle that is capped on both sides by two symmetry-related 10-atom equilateral 3M(A)Ni9 triangles. The 35-atom M(A)2M(B)3Ni30 core is encapsulated by 40 COs, whose connectivities, due to an extra CO ligand on one of the three triangular sides, reduce the pseudo D3h symmetry of the metal core to Cs. An elemental analysis via AA and X-ray fluorescence measurements resulted in Cu/Ni ratios of 3.2/31.8 and 3.7/31.3, respectively, that are consistent with the metal core being either Cu5Ni30 (i.e., M(A)=M(B)=Cu) or Cu3Ni32 (i.e., M(A)=Ni; M(B)=Cu). Several attempts to determine the actual stoichiometry of the metal core by use of electrospray FT/MS/ICR measurements were unsuccessful. The maximum metal-core diameter of 2 is ca. 0.41 nm parallel and 0.85 nm perpendicular to the principal 3-fold axis. 相似文献
32.
van Der Voort M Rella CW van Der Meer LF Akimov AV Dijkhuis JI 《Physical review letters》2000,84(6):1236-1239
We present results of the first vibrational photon-echo, transient-grating, and temperature dependent transient-bleaching experiments on a-Si:H. Using these techniques, and the infrared light of a free electron laser, the vibrational population decay and phase relaxation of the Si-H stretching mode were investigated. Careful analysis of the data indicates that the vibrational energy relaxes directly into Si-H bending modes and Si phonons, with a distribution of rates determined by the amorphous host. Conversely, the pure dephasing appears to be single exponential, and can be modeled by dephasing via two-phonon interactions. 相似文献
33.
H. Mukundan Y. Modarres-Sadeghi J.M. Dahl F.S. Hover M.S. Triantafyllou 《Journal of Fluids and Structures》2009,25(4):617-628
Long flexible cylinders (e.g., risers, tendons and mooring lines) exposed to the marine environment encounter ocean currents leading to vortex-induced vibration (VIV). These oscillations, often driven at high frequencies over extended periods of time, may result in structural failure of the member due to fatigue damage accumulation. Recent developments in instrumentation and installation of data acquisition systems on board marine risers have made accurate measurement of riser responses possible. This paper aims at using the data from these data acquisition devices (typically strain gages and accelerometers) in order to understand the evolution of the riser VIV, with the final aim of estimating the fatigue damage. For this purpose we employ systematic techniques to reconstruct riser VIV response using the data from the available sensors. The reconstructed riser response allows estimation of the dynamic axial stresses due to bending and consequently the estimates of the fatigue damage along the entire riser. The above methods can take into account the fatigue damage arising from complicated riser motions involving the presence of traveling waves even with the use of very few sensors. An alternate approach using a Van der Pol wake oscillator model is also explored to obtain fatigue life estimates caused by riser VIV. 相似文献
34.
Correlation forms for electrons of the same spin small molecules are analyzed by taking the LiH molecule as an example. The analyses are carried out on the basis of the reduced density matrix theory and for both the ground state and the first excited state. It turns out that although there is a certain similarity, the correlated motions of parallel-spin electrons in this four-electron molecule are more complicated than those found for the two-electron molecule. The correlation forms are not always constant. They vary essentially from one state to another, but are insensitive to fairly large changes of the internuclear distance for a given state. 相似文献
35.
Geir Dahl 《Linear algebra and its applications》2009,430(8-9):2457-2463
36.
Barber ZW Giorgetta FR Roos PA Coddington I Dahl JR Reibel RR Greenfield N Newbury NR 《Optics letters》2011,36(7):1152-1154
The optical frequency sweep of an actively linearized, ultrabroadband, chirped laser source is characterized through optical heterodyne detection against a fiber-laser frequency comb. Frequency sweeps were measured over approximately 5 THz bandwidths from 1530 nm to 1570 nm. The dominant deviation from linearity resulted from the nonzero dispersion of the fiber delay used as a reference for the sweep linearization. Removing the low-order dispersion effects, the residual sweep nonlinearity was less than 60 kHz rms, corresponding to a constant chirp with less than 15 ppb deviation across the 5 THz sweep. 相似文献
37.
Wee Ong Siew Seong Shan Yap Cécile Ladam Øystein Dahl Turid Worren Reenaas Teck Yong Tou 《Applied Physics A: Materials Science & Processing》2011,104(3):877-881
Nanosecond-pulsed KrF (248 nm, 25 ns) and Nd:YAG (1064 nm, 532 nm, 355 nm, 5 ns) lasers were used to ablate a polycrystalline
Si target in a background pressure of <10−4 Pa. Si films were deposited on Si and GaAs substrates at room temperature. The surface morphology of the films was characterized
using scanning electron microscopy (SEM) and atomic force microscopy (AFM). Round droplets from 20 nm to 5 μm were detected
on the deposited films. Raman Spectroscopy indicated that the micron-sized droplets were crystalline and the films were amorphous.
The dependence of the properties of the films on laser wavelengths and fluence is discussed. 相似文献
38.
39.
A. Hellman K. Honkala I.N. Remediakis á. Logadóttir A. Carlsson S. Dahl C.H. Christensen J.K. N?rskov 《Surface science》2009,603(10-12):1731-1739
A recently published first-principles model for the ammonia synthesis on an unpromoted Ru-based catalyst is extended to also describe ammonia decomposition. In addition, further analysis concerning trends in ammonia productivity, surface conditions during the reaction, and macro-properties, such as apparent activation energies and reaction orders are provided. All observed trends in activity are captured by the model and the absolute value of ammonia synthesis/decomposition productivity is predicted to within a factor of 1–100 depending on the experimental conditions. Moreover it is shown: (i) that small changes in the relative adsorption potential energies are sufficient to get a quantitative agreement between theory and experiment (Appendix A) and (ii) that it is possible to reproduce results from the first-principles model by a simple micro-kinetic model (Appendix B). 相似文献
40.
Preben Dahl Vestergaard 《Graphs and Combinatorics》1991,7(2):197-204
The graphs whose spanning unicyclic subgraphs partition into exactly two isomorphism classes are characterized.This work is a continuation of [6] where graphs with one isomorphism class of spanning unicyclic graphs are characterized. The analogous question for spanning trees was posed in [10] and graphs with one isomorphism class of spanning trees were characterized in [2], [3], [4], [7], [11] while graphs with two isomorphism classes of spanning trees were characterized in [4], [5]. Related topics are treated in [1], [8], [9]. 相似文献