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121.
A transient molecular network model is built to describe the nonlinear viscoelasticity of polymers by considering the effect
of entanglement loss and regeneration on the relaxation of molecular strands. It is an extension of previous network theories.
The experimental data on three thermoplastic polymers (ABS, PVC and PA6) obtained under various loading conditions are used
to test the model. Agreement between the theoretical and experimental curves shows that the suggested model can describe successfully
the relaxation behavior of the thermoplastic polymers under different loading rates by using relatively few relaxation modes.
Thus the micromechanism responsible for strain-rate dependence of relaxation process and the origin of nonlinear viscoelasticity
may be disclosed.
The project supported by the National Natural Science Foundation of China and Doctorial Fund 相似文献
122.
Young-Bae Seu Taeg-Kyeong Lim Chang-Jin Kim Sun-Chul Kang 《Tetrahedron: Asymmetry》1995,6(12):3009-3014
Optically active epoxy alcohol, (R)-2-butyryloxymethylglycidol3 which is the precursor of a tert-alcohol chiral building block was obtained in high enantiomeric purity, 98.7% e.e., by lipase-catalyzed asymmetric hydrolysis using a phosphate buffer and organic co-solvent system in 95% of chemical yield. 相似文献
123.
The activity coefficients of NaBr in the NaBr–NaPropionate–H2O and NaBr–NaButyrate–H2O systems were determined from EMF measurements at constant total ionic strength of 0.1 0.5 1.0 1.5 2.0 and 2.5 mol-kg–1 and at 25° C. The activity coefficients were fitted using Scatchard, Pitzer and Lim equations. Finally the excess Gibbs free energy of these mixtures were also calculated. 相似文献
124.
The chemical mechanism of the precipitation of lead titanium peroxohydroxide particles in a solution of nitrilotriacetate (NTA) complexes of lead and titanium peroxo-hydroxide is envisioned as the interaction between cations of lead hydroxide and anions of polymeric titanium peroxo-hydroxide. 相似文献
125.
Weimin Han 《Mathematical Methods in the Applied Sciences》1994,17(7):487-508
The paper is devoted to a posteriori quantitative analysis for errors caused by linearization of non-linear elliptic boundary value problems and their finite element realizations. We employ duality theory in convex analysis to derive computable bounds on the difference between the solution of a non-linear problem and the solution of the linearized problem, by using the solution of the linearized problem only. We also derive computable bounds on differences between finite element solutions of the nonlinear problem and finite element solutions of the linearized problem, by using finite element solutions of the linearized problem only. Numerical experiments show that our a posteriori error bounds are efficient. 相似文献
126.
The Stokes motions of three-dimensional screw-sensed slender particles in a homogeneous shear field are investigated, including the effects of buoyancy. Conclusions are drawn about the possibility of achieving a separation of mixtures of right- and left-handed particles. The linearity of the Stokes equations allows complex flows to be solved by adding the effects of the several terms which describe the flow in which the particle is immersed. The homogeneous shear flow considered here consists of three such terms; solutions for a series of 12 unit motions are sufficient to determine the hydrodynamic resistance tensors. The forces and torques experienced by screw-sensed particles are calculated from these 51 resistance tensors, using slender-filament theory. The results allow an estimate of the range of buoyancy parameters for which gravitational sedimentation can be neglected. The fundamental component of the particle motion is a rotation, at approximately the same angular velocity as that of the fluid. Superimposed on this are variations, of large period, in the particle orientation. A phase plane analysis is used to find the terminal orientations. Very long calculation times are required for the phase portrait. An approximate method based on azimuthally-averaged equations is developed to avoid the requirements for long time integration. 相似文献
127.
In Hyoun Kim 《Journal of Mathematical Analysis and Applications》2007,335(1):260-267
In this paper it is shown that the spectrum σ, a set-valued function, is continuous when the function is restricted to the set of all ‘quasi-n-hyponormal’ operators acting on an infinite-dimensional separable Hilbert space, where a quasi-n-hyponormal operator is defined to be unitarily equivalent to an n×n upper triangular operator matrix whose diagonal entries are hyponormal operators. 相似文献
128.
微腔激光器的发展与应用 总被引:1,自引:0,他引:1
本文探讨了微腔激光器的分类、基本原理及特点,并简单介绍了目前几种微型激光器的发展及应用。 相似文献
129.
We investigate differential operators and their compatibility with subgroups of SL2n(R). In particular, we construct Rankin-Cohen brackets for Hilbert modular forms, and more generally, multilinear differential operators on the space of Hilbert modular forms. As an application, we explicitly determine the Rankin-Cohen bracket of a Hilbert-Eisenstein series and an arbitrary Hilbert modular form. We use this result to compute the Petersson inner product of such a bracket and a Hilbert modular cusp form. 相似文献
130.
Ju Yeon Woo Eun Hee Kim Byung Kyu Kim 《Journal of polymer science. Part A, Polymer chemistry》2007,45(23):5590-5596
Doping of conductive fullerene particles to the formulation of conventional holographic polymer dispersed liquid crystal‐induced dual effects of reducing both droplet coalescence and operating voltage. Fullerene induced an induction period which otherwise does not exist, followed by a gradual increase of diffraction efficiency to a saturation value being increased with increasing fullerene content. The increased diffraction efficiency was caused by the decreased droplet coalescence which was due to the hindered migration of LC by the fullerene particles. On the other hand, doped fullerene particles augmented the conductivity of polymer phase and hence the local electrical field imposed on LC droplet, which overcome the threshold for driving and reduced operating voltage and response times. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5590–5596, 2007 相似文献