The first representative of a new class of charge transfer complexes in o-quinone series for organic semiconductors

The first representative of a new class of charge transfer complexes for organic semiconductors was synthesized. The reaction of p-nitroaniline (PNA) with [1,10]-phenanthroline-5,6-dione (PD) results in the formation of a stable molecular charge transfer (CT) complex PNA₃-PD₂ in a ratio of 3:2. The structure of the molecular CT complex PNA₃-PD₂ was established by X-ray diffraction studies. Using the density functional theory method, it is shown that several types of intermolecular interactions are realized in the complex: between the PNA amino group and the nitro group of another PNA molecule, carbonyl groups, and PD nitrogen atoms. Complex PNA₃-PD₂ is stable only in solid form. The diffuse reflectance UV–vis spectrum of PNA₃-PD₂ crystal powder is characterized by the intense weakly structured long-wavelength absorption band up to 650 nm. Quantum chemical calculations of the electronic structure have shown that the complex PNA₃-PD₂ is a straight-band semiconductor with a band gap of 2.11 eV.     

Variational master equation approach to dynamics of magnetic moments

Non-equilibrium properties of a model system comprised of a subsystem of magnetic moments strongly coupled to a selected Bose field mode and weakly coupled to a heat bath made of a plurality of Bose field modes was studied on the basis of non-equilibrium master equation approach combined with the approximating Hamiltonian method. A variational master equation derived within this approach is tractable numerically and can be readily used to derive a set of ordinary differential equations for various relevant physical variables belonging to the subsystem of magnetic moments. Upon further analysis of the thus obtained variational master equation, an influence of the macroscopic filling of the selected Bose field mode at low enough temperatures on the relaxation dynamics of magnetic moments was revealed.     

Excitation efficiency of working transitions in copper-vapor lasers

The conditions under which the influence of the discharge circuitry inductance on the efficiency of pulsed-periodic copper-vapor lasers is weak are determined. It is shown that for efficient pumping of the lasing transitions of Cu atom in these lasers it is advisable to form an excitation pulse having steep edges of the voltage applied to the discharge tube with the duration spanning the pumping period and termination of the lasing process providing, at the same time, the conditions for aperiodic behavior of the discharge during the excitation pulse. Such a pumping pulse can be formed due to a partial discharge of the storage capacitor in the laser discharge circuit. It is also shown that under such conditions of excitation the efficiency of copper-vapor laser (CVL) with respect to the energy pumped into the active element can reach 10%.     

Turbulence investigations during ergodic divertor operation with induced 2/1 tearing mode

Within the last year of TEXTOR operation a major part of the experiments were dedicated to the interaction of the ergodized plasma edge, induced by the dynamic ergodic divertor (DED), with the core plasma. Systematic experiments are performed in the 3/1 configuration of the DED. Depending on , the DED generates a locked 2/1 mode in the plasma at a critical current in the DED coils. Different diagnostics were used to measure the plasma response in the core and edge. The investigations in this paper are focused on the measurement of density fluctuation and the analysis of the coherent-mode structure outside the q = 2 surface using O-mode poloidal correlation reflectometry. A reduction of the quasi-coherent mode amplitude and frequency is observed, caused by the 2/1 mode together with a decrease of the density scale length. Moreover, the deduced poloidal rotation velocity at the q = 3 surface changes from the electron to the ion diamagnetic drift direction with the onset of the 2/1 island. Also a reduction of the density fluctuations is observed as well as a decrease in the poloidal correlation length. From Ar-injection a delayed inward propagation of the emission maximum is observed for different Ar ionization stages when the 2/1 mode is generated.Similar experiments with a slowly rotating DED show that the steepened density gradients are spatially localized and confirm the hypothesis that the 2/1 mode is responsible for the observations.Presented at the Workshop Electric Fields Structures and Relaxation in Edge Plasmas, Nice, France, October 26–27, 2004.     

Theoretical interpretation of spin-polarized X-ray absorption spectra of Mn in MnP

On the basis of the multiple scattering approach in combination with the spin-polarized self-consistent potential calculation, an interpretation is proposed for the spin-polarized x-ray absorption spectra near the Mn K edge in MnP. The effect of the core vacancy potential on the spectra is analyzed and found to be insignificant. The method used for the calculations allowed the separation of the effect of the dipole transition matrix element on the spectra and the effect of the density of unoccupied electron states. It is shown that the transition matrix element causes an intensity redistribution only near the absorption jump, while the difference in the densities of states is most pronounced in the energy region 35–55 eV away from the main edge and leads to a shift in energy for the spectra corresponding to the two spin directions. The effect of the spin-dependent broadening caused by the dependence of the mean free path (as a function of energy) on the photoelectron spin is studied. It is shown that this factor considerably affects only the intensities of the peaks in the energy region lying within less than 12 eV from the main edge.     

Combined digital filtering of harmonic content of phase-shift keyed signals in the problem of estimation of the time delay

We propose a two-step method for digital filtering of phase-shift keyed signals filtering in the problem of determination of the time delay during the multichannel propagation. The first step is realized as an information-optimal linear filter with complex coefficients, while the second step, as a quadratic filter based on the minimum-variance criterion. The e.ciency of the proposed method is demonstrated for short PSK signals with various carrier frequencies against the background of additive and multiplicative noise. The developed algorithm can easily be implemented in real time on the basis of a digital signal processor. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 50, No. 3, pp. 255–264, March 2007.     

Measurements of the Dalitz plot parameters for K ± → π±π0π0 decays

The g, h, and k Dalitz plot parameters, which are coefficients in a series expansion of the squared module of the matrix element |M(u, v)|² ∝ 1 + gu + hu ² + kv ² (u, v are invariant variables), have been measured for K ^± → π^±π ⁰π⁰ decays using 35 GeV/c hadron beams at the IHEP (Protvino) accelerator. Dependences of parameters and fit quality on the π⁰π⁰ mass cut were investigated for the first time. It is shown that the expansion mentioned above does not fit the experimental data near the π⁺π^? mass threshold and that addition of the cubic terms only slightly improves the fit quality. This result indicates the important role of nonanalytical terms in the matrix element that are connected with pion rescattering. A comparison of our data with previous measurements is presented.     

Determination of the local atomic structure of the active center of bromoperoxidase protein via the analysis of x-ray absorption spectra

The existing model of the active center of bromoperoxidase protein, which has been obtained via x-ray diffraction methods, is defined more precisely. The processes occurring in the active center of this protein interacting with hydrogen peroxide are studied. It is shown that the existing model of the active center of bromoperoxidase is not sufficiently accurate. To study the adequacy of certain structural parameters of the active center, the atomic structure has been optimized using electron density functional theory. A new model of the active center of bromoperoxidase protein is proposed.