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41.
42.
Theodor Milek Patrick Duchstein Gotthard Seifert Prof. Dr. Dirk Zahn Dr. 《Chemphyschem》2010,11(4):847-852
A recently developed atomistic simulation scheme for investigating ion aggregation from solution is transferred to the morphogenesis of metal clusters grown from the vapor and layers deposited on a substrate surface. Both systems are chosen as benchmark models for intense motif reorganization during aggregate/layer growth. The applied simulation method does not necessarily involve global energy minimization after each growth event, but instead describes crystal growth as a series of structurally related configurations which may also include local energy minima. Apart from the particularly favorable high‐symmetry configurations known from experiments and global energy minimization, we also demonstrate the investigation of transient structures. In the spirit of Ostwald’s step rule, a continuous evolution of the aggregate/layer structure during crystal growth is observed. 相似文献
43.
The mechanistic details of the pressure-induced B1-B2 phase transition of rubidium chloride are investigated in a series of transition path sampling molecular dynamics simulations. The B2→B1 transformation proceeds by nucleation and growth involving several, initially separated, nucleation centers. We show how independent and partially correlated nucleation events can function within a global mechanism and explore the evolution of phase domains during the transition. From this, the mechanisms of grain boundary formation are elaborated. The atomic structure of the domain-domain interfaces fully support the concept of Bernal polyhedra. Indeed, the manifold of different grain morphologies obtained from our simulations may be rationalized on the basis of essentially only two different kinds of Bernal polyhedra. The latter also play a crucial role for the B1→B2 transformation and specific grain boundary motifs are identified as preferred nucleation centers for this transition. 相似文献
44.
Negative electrorheological responses induced by micro-particle electrorotation in two-dimensional Couette flow geometries are analyzed by a set of continuum modeling field equations originating from anti-symmetric/couple stress theories in the finite spin viscosity small spin velocity (FSV) limit. Analytical solutions are obtained for the first time to express the spin velocity, linear velocity, and effective viscosity in terms of the electric field strength, driving shear rate, boundary condition selection parameter, and spin viscosity. Good agreement is achieved between the FSV theoretical predictions presented herein and the experimental measurements reported in recent literature for the effective viscosity for low driving shear rates. 相似文献
45.
Shahriar KhushrushahiMarkus Zahn 《Journal of magnetism and magnetic materials》2011,323(10):1302-1308
Ferrofluid spin-up flow is studied within a sphere subjected to a uniform rotating magnetic field from two surrounding spherical coils carrying sinusoidally varying currents at right angles and 90° phase difference. Ultrasound velocimetry measurements in a full sphere of ferrofluid shows no measureable flow. There is significant bulk flow in a partially filled sphere (1-14 mm/s) of ferrofluid or a finite height cylinder of ferrofluid with no cover (1-4 mm/s) placed in the spherical coil apparatus. The flow is due to free surface effects and the non-uniform magnetic field associated with the shape demagnetizing effects. Flow is also observed in the fully filled ferrofluid sphere (1-20 mm/s) when the field is made non-uniform by adding a permanent magnet or a DC or AC excited small solenoidal coil. This confirms that a non-uniform magnetic field or a non-uniform distribution of magnetization due to a non-uniform magnetic field are causes of spin-up flow in ferrofluids with no free surface, while tangential magnetic surface stress contributes to flow in the presence of a free surface.Recent work has fitted velocity flow measurements of ferrofluid filled finite height cylinders with no free surface, subjected to uniform rotating magnetic fields, neglecting the container shape effects which cause non-uniform demagnetizing fields, and resulting in much larger non-physical effective values of spin viscosity η′∼10−8−10−12 N s than those obtained from theoretical spin diffusion analysis where η′≤10−18 N s. COMSOL Multiphysics finite element computer simulations of spherical geometry in a uniform rotating magnetic field using non-physically large experimental fit values of spin viscosity η′∼10−8−10−12 N s with a zero spin-velocity boundary condition at the outer wall predicts measureable flow, while simulations setting spin viscosity to zero (η′=0) results in negligible flow, in agreement with the ultrasound velocimetry measurements. COMSOL simulations also confirm that a non-uniform rotating magnetic field or a uniform rotating magnetic field with a non-uniform distribution of magnetization due to an external magnet or a current carrying coil can drive a measureable flow in an infinitely long ferrofluid cylinder with zero spin viscosity (η′=0). 相似文献
46.
Yu.M. Azhniuk A.V. Gomonnai Yu.I. Hutych V.V. Lopushansky I.I. Turok V.O. Yukhymchuk D.R.T. Zahn 《Journal of Crystal Growth》2010,312(10):1709-1716
Variation of the chemical composition of ternary CdS1−xSex nanocrystals grown in borosilicate glass depending on the thermal treatment is studied by resonant Raman spectroscopy. It is shown that only for the nanocrystals with roughly equal content of substitutive S and Se chalcogen atoms (0.4<x<0.6) the nanocrystal composition is independent of the thermal treatment parameters. In other cases an increase of the thermal treatment temperature (625–700 °C) and duration (2–12 h) results in a considerable increase of the predominant chalcogen content in the nanocrystals. 相似文献
47.
48.
Ohne Zusammenfassung 相似文献
49.
V. Sivakov G. Andrä C. Himcinschi U. Gösele D.R.T. Zahn S. Christiansen 《Applied Physics A: Materials Science & Processing》2006,85(3):311-315
One-dimensional (1D) silicon (Si) nanostructures were grown by electron-beam evaporation catalyzed by gold nanoparticles on silicon substrates following the vapor–liquid–solid growth mechanism. We report three strikingly different growth morphologies of the 1D Si nanostructures and discuss their formation. The morphology of the silicon nanostructures strongly depends on gold layer thickness, annealing temperature before deposition and growth temperature during the deposition. The formation of nanoscale silicon features such as nanobelts, nanowires and nanowhiskers was observed. The nanoscale silicon features were characterized by transmission and scanning electron microscopy using imaging, diffraction and energy-dispersive X-ray spectroscopy, atomic force microscopy and UV micro-Raman spectroscopy. PACS 68.37.Lp; 68.70.+w; 78.30.-j; 81.15.Jj 相似文献
50.
Ohne Zusammenfassung
Die R?ntgenuntersuchungen konnten wir im Physikalisch-Chemischen Institut der Universit?t Heidelberg durchführen. Herrn Dozenten
Dr. Borchert sind wir für das freundliche Entgegenkommen zu besonderem Dank verpflichtet. Herrn Prof. Dr. H. Nowotny, Wien,
danken wir für wertvolle Diskussionen. 相似文献