THE MOMENTUM SELECTOR OF BIG CLOUD CHAMBER SET

Using a“preselection-register-operation for reselection”program,a selection systemof the Yunan big cloud chamber set used for cosmic ray reseach is projected andconstructed.A small on-line digital computation technigue is applied to the momentumselector of the system,and a special computation element is designed.According tothe deflection angle and momentum of a charged particle passing through the magniticfield,computation and logieal judgment can be done immediately for the track signal registered before.     

载有微量贵金属的n-TiO2电极的光电化学研究

利用在富氧和乏氧溶液中光照下与不光照下测得的极化曲线,研究了载有铂和银的TiO₂电极的光电化学行为及反应机理.在富氧溶液中,光照载有贵金属的TiO₂电极时,贵金属上发生氧的还原反应,其速度与光照与否无关;而在未被贵金属覆盖的电极表面上进行水或其它组份的光氧化;二者组成一对共轭反应,相当于短路的光电化学电池.共轭反应速度一般由氧的还原反应速度控制.增加贵金属的载量能使共轭反应速度增大,外电路中通过的电流等于这一对反应所引起的电流的代数和.根据对极化曲线的分析和界面阻抗的测量结果,可以确定载在TiO₂表面上的铂、银与基底之间的接触基本上是欧姆型的.光照下贵金属中的电子具有与半导体整体相同的费米能级.在含载有贵金属的TiO₂粉末的悬浮液中实现了CN^-和二乙胺的光氧化,其速度随贵金属载量变化的规律可用上述反应机理加以解释.     

COMPOSITE MODEL OF QUARKS AND LEPTONS WITH ELEMENTARY SCALARS

The model in Ref.[5] is modified to include three doublets of quarks and Leptons so as to recover quark-Lepton symmetry. The second model is constructed from two elementary scalars and a fermion and is therefore more economical.     

The Analytical Helicity Amplitudes for Z → 3γ, γγ → γZ and γZ → γγ via W-Loop,Charged Scalar-Loop

The analytic helicity amplitudes of Z → 3γ, γγ → γZ and γZ → γγ via W-loop and charged scalar-loop are presented. There is some difference between our results and those in Z. Phys. C60 (1993) 175 (E.W.N. Glover and A.G. Morgan) for Z → 3γ via W-loop and fermion-loop, which has different physical meanings.     

β-环糊精对氨基苯甲酸同分异构体的分子识别作用的研究

采用荧光光谱法系统研究了β-CD对o-, m, p-氨基苯甲酸同分异构体的分子识别作用,详细讨论了介质酸度对包合过程的影响,测定了它们之间形成包合物的包合常数,比较了β-CD对三者的包合能力,提出了相应的包合机理.用一维、二维核磁共振技术对包合部位进行了探讨,并结合分子力学计算以及计算机模拟技术提出了包合物的空间构型.分子力学计算得出的结果与NMR方法所得结果相吻合.     

强磁场碳黑催化法制备纳米新金刚石粉

在直流恒稳强磁场(10T)作用下,以纳米铁为催化剂,碳黑为碳源,在常压和1100℃下保温100min成功地制备出了类金刚石和新金刚石,并用XRD,TEM和Raman对制备的样品粉末进行表征．结果表明,样品粉末是由纳米类金刚石粉和石墨包覆新金刚石纳米颗粒组成,纳米类金刚石粉的大小为20nm,石墨包覆新金刚石的大小为100nm．     

离子色谱法测定硫脲中的钙离子

建立了离子色谱法测定硫脲中钙离子的方法。采用CS12A阳离子交换色谱柱,以甲基磺酸(16mmol/L)作为淋洗液,测定了硫脲样品中的钙离子,通过分析5批不同的样品,分别得到其钙值在270~410μg/g,加标回收率在97.2%~102.3%。方法无需复杂的样品前处理,分析方法干扰小,测定结果令人满意。     

基于三维离散元堆积碎石土细-宏观力学参数相关性研究

以室内三轴压缩试验为基础,运用PFC3D离散元软件生成含有不同形状碎石块的1∶1堆积碎石土数值模型,标定得到相应的细观参数(相对误差控制在10%以内)。改变细观参数,定量探讨其与宏观力学参数(粘聚力和内摩擦角)关系,得到细观参数与粘聚力、内摩擦角的细-宏观参数关系式,并对其可靠性进行了验证。研究发现,(1)粘聚力与接触粘结力、颗粒摩擦系数呈线性正相关;同时受粘结力比值M=σc/τc的影响,当M1时,粘聚力随着M的增加而线性增加;M≥4时,粘聚力趋于稳定。(2)内摩擦角与颗粒摩擦系数呈对数关系,与接触粘结力呈抛物线关系。(3)细-宏观参数关系式是在含水率为7%室内试验结果基础上研究得出,将关系式运用到含水率为9%和11%的室内试验结果进行标定验证:依据含水率为9%和11%室内试验得到的c和φ值,运用细-宏观参数关系式计算得到细观参数,经验证其数值-室内试验结果相对误差在10%以内,说明通过细-宏观力学关系式得到的细观参数符合精度要求,关系式可靠。为后续土石混合体数值试验研究者进行细观参数标定工作提供了参考依据。     

Influences of Temperature and Solvent Ions in Solution on States and Properties of Deoxyribonucleic Acid (DNA)

We here study the influences of the temperature and solvent ions in solution on the states and properties of DNA by a new dynamical model. This model admits three degrees of freedom per base-pair: two displacement variables related to the vibrations of the hydrogen atom in the hydrogen bonds and base (nucleotide), respectively, and an angular variable related to the rotation of each base, which delineate different forms of motion of the hydrogen atom and bases and the relations among them. In this model we stress specially the important role of the hydrogen atom in the hydrogen bonds of the bases in the dynamics of DNA. According to their properties of motion we give the Hamiltonian of the system and the corresponding equations of motion, and find out their soliton solutions. The solitons formed by the displacements of the hydrogen atoms and bases and their rotations are the excitation states arising from the energy absorbed by the DNA working at the biological temperature. We give further the free energy of the thermal excitation state in DNA system by transfer integral way and find out the corresponding specific heat. The specific heat increases with the increasing of the temperature and concentration of the solvent ions in the solution, but is not linear changes in the region of high temperature. If compared with experimental data, they are approximately consistent. Meanwhile we find that the solvent ion concentration influences seriously on the stability, states, and configurations of DNA.