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排序方式: 共有264条查询结果,搜索用时 31 毫秒
31.
32.
D. M. Rein L. Shavit‐Hadar R. L. Khalfin Y. Cohen K. Shuster E. Zussman 《Journal of Polymer Science.Polymer Physics》2007,45(7):766-773
The electrospinning method has been employed to fabricate ultrafine nanofibers of ultrahigh‐molecular‐weight polyethylene for the first time with a mixture of solvents of different dielectric constants and conductivities. The possibility of producing highly oriented nanofibers from ultrahigh‐molecular‐weight polymers suggests new ways of fabricating ultrastrong, porous, and single‐component nanocomposite fibers with improved properties. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 766–773, 2007 相似文献
33.
34.
G. Rein 《Archive for Rational Mechanics and Analysis》1997,140(4):335-351
We consider the Vlasov‐Poisson system in a cosmological setting as studied in [18] and prove nonlinear stability of homogeneous
solutions against small, spatially periodic perturbations in the L
∞‐norm of the spatial mass density. This result is connected with the question of how large scale structures such as galaxies
have evolved out of the homogeneous state of the early universe.
(Accepted June 28, 1996) 相似文献
35.
Rein C Pszon-Bartosz K Stibius KB Bjørnholm T Hélix-Nielsen C 《Langmuir : the ACS journal of surfaces and colloids》2011,27(2):499-503
Fluid polymeric biomimetic membranes are probed with atomic force microscopy (AFM) using probes with both normal tetrahedrally shaped tips and nanoneedle-shaped Ag(2)Ga rods. When using nanoneedle probes, the collected force volume data show three distinct membrane regions which match the expected membrane structure when spanning an aperture in a hydrophobic scaffold. The method used provides a general method for mapping attractive fluid surfaces. In particular, the nanoneedle probing allows for characterization of free-standing biomimetic membranes with thickness on the nanometer scale suspended over 300-μm-wide apertures, where the membranes are stable toward hundreds of nanoindentations without breakage. 相似文献
36.
Tang C Ulijn RV Saiani A 《Langmuir : the ACS journal of surfaces and colloids》2011,27(23):14438-14449
We have investigated the self-assembly behavior of fluorenyl-9-methoxycarbonyl (Fmoc)-FG, Fmoc-GG, and Fmoc-GF and compared it to that of Fmoc-FF using potentiometry, fluorescence and infrared spectroscopy, transmission electron microscopy, wide-angle X-ray scattering, and oscillatory rheometry. Titration experiments revealed a substantially shifted apparent pK(a) transition for Fmoc-FG, Fmoc-GG, and Fmoc-GF. The apparent pK(a) values observed correlated with the hydrophobicity (log P) of the Fmoc-dipeptide molecules. Fmoc-GG and Fmoc-GF were found to self-assemble only in their protonated form (below their apparent pK(a)), while Fmoc-FG formed self-assembled structures above and below its apparent pK(a). Fmoc-GG and Fmoc-FG were found to form hydrogels below their apparent pK(a) transitions in agreement with the entangled fibers morphologies revealed by TEM. Unlike Fmoc-FF and Fmoc-GG, Fmoc-FG showed unusual gelation behavior as gels were found to form upon heating. Fmoc-GF formed precipitates instead of a hydrogel below its apparent pK(a) in agreement with the formation of micrometer scale sheetlike structures observed by TEM. The fact that all four Fmoc-dipeptides were found to self-assemble suggests that the main driving force behind the self-assembly process is a combination of the hydrophobic and π-π interactions of the fluorenyl moieties with a secondary role for hydrogen bonding of the peptidic components. The nature of the peptidic tail was found to have a pronounced effect on the type of self-assembled structure formed. This work indicates that the substitution of phenylalanine by glycine significantly impacts on the mode of assembly and illustrates the versatility of aromatic peptide amphiphiles in the formation of structurally diverse nanostructures. 相似文献
37.
Roerdink Lander M Ibragimova S Rein C Vogel J Stibius K Geschke O Perry M Hélix-Nielsen C 《Langmuir : the ACS journal of surfaces and colloids》2011,27(11):7002-7007
Lipid bilayers are intrinsically fragile and require mechanical support in technical applications based on biomimetic membranes. Tethering the lipid bilayer membranes to solid substrates, either directly through covalent or ionic substrate-lipid links or indirectly on substrate-supported cushions, provides mechanical support but at the cost of small molecule transport through the membrane-support sandwich. To stabilize biomimetic membranes while allowing transport through a membrane-support sandwich, we have investigated the feasibility of using an ethylene tetrafluoroethylene (ETFE)/hydrogel sandwich as the support. The sandwich is realized as a perforated surface-treated ETFE film onto which a hydrogel composite support structure is cast. We report a simple method to prepare arrays of lipid bilayer membranes with low intrinsic electrical conductance on the highly permeable, self-supporting ETFE/hydrogel sandwiches. We demonstrate how the ETFE/hydrogel sandwich support promotes rapid self-thinning of lipid bilayers suitable for hosting membrane-spanning proteins. 相似文献
38.
39.
Guillermo Rein Amnon Bar-Ilan A. Carlos Fernandez-Pello Janet L. Ellzey Jose L. Torero David L. Urban 《Proceedings of the Combustion Institute》2005,30(2):2327-2334
Results are presented from a model of forward smoldering combustion of polyurethane foam in microgravity. The transient one-dimensional numerical-model is based on that developed at the University of Texas at Austin. The conservation equations of energy, species, and mass in the porous solid and in the gas phases are numerically solved. The solid and the gas phases are not assumed to be in thermal or in chemical equilibrium. The chemical reactions modeled consist of foam oxidation and pyrolysis reactions, as well as char oxidation. The model has been modified to account for new polyurethane kinetics parameters and radial heat losses to the surrounding environment. The kinetics parameters are extracted from thermogravimetric analyses published in the literature and using Genetic Algorithms as the optimization technique. The model results are compared with previous tests of forward smoldering combustion in microgravity conducted aboard the NASA Space Shuttle. The model calculates well the propagation velocities and the overall smoldering characteristics. Direct comparison of the solution with the experimental temperature profiles shows that the model predicts well these profiles at high temperature, but not as well at lower temperatures. The effect of inlet gas velocity is examined, and the minimum airflow for ignition is identified. It is remarkable that this one-dimensional model with simplified kinetics is capable of predicting cases of smolder ignition but with no self-propagation away from the igniter region. The model is used for better understanding of the controlling mechanisms of smolder combustion for the purpose of fire safety, both in microgravity and normal gravity, and to extend the unique microgravity data to wider conditions avoiding the high cost of space-based experiments. 相似文献
40.
Dieter Rein 《Zeitschrift für Physik A Hadrons and Nuclei》1973,259(3):205-216
Applying two different Lorentz-covariant quark models, one of them being essentially nonrelativistic, chiral symmetry breaking parameters of strong interaction will be calculated. Also attention will be paid to meson decays. The model retaining relativistic spinor structure for quark-antiquark wave functions turns out to be more appropriate than the nonrelativistic one. 相似文献