微波消解-CTAB增敏-HG-ICP-AES法测定中药黄芪中的痕量铅

采用微波消解技术处理样品,建立了CTAB增敏-氢化物发生-电感耦合等离子体发射光谱法(HG-ICP-AES)测定中药黄芪中痕量铅的分析方法。讨论了微波消解试剂、微波消解参数对消解效果的影响,系统地研究了氢化物发生的最佳条件。采用HNO₃+H₂O₂+H₂O为微波消解最佳试剂,在选定的最佳氢化物发生条件下,铅的线性范围为0.23～800 μg·L-1, 相关系数为0.999 9,检出限为0.23 μg·L-1,相对标准偏差为1.02%, 样品加标回收率为98.8%～100.1%。结果表明,微波消解法处理中草药,具有快速、简便、节省试剂、消解完全等特点,测定结果的精密度和准确度令人满意。     

TiO_2/石墨烯/Ag复合结构SERS实验

基于氧化物半导体的光催化特性,能够降解有机物分子,使表面增强拉曼散射基底得以重复使用。提出了银纳米颗粒有效修饰覆盖有石墨烯的二氧化钛纳米棒阵列(TiO_2/石墨烯/Ag)复合结构作为表面增强拉曼散射基底,并对其进行了实验研究。利用水热法制备了二氧化钛纳米棒阵列;采用湿法转移石墨烯和光照还原方法制备了TiO_2/石墨烯/Ag复合结构。用罗丹明6G(R6G)分子作为探测分子,结果表明:随着紫外光照沉积时间增加,探针分子的拉曼信号先增强后减弱;计算得到最大增强因子值约为2.6×106。此外,还对TiO_2/石墨烯/Ag复合结构的紫外自清洁特性进行了初步实验,结果表明,紫外光照射20min后,其拉曼强度下降到42.3%,具有一定的紫外清洁效果。     

两个玻色-爱因斯坦凝聚体间相互作用的数值研究

本文采用辛算法数值求解一维含时Gross-Pitaevskii(GP)方程.研究了存在陷俘势和撤掉陷俘势时两个凝聚体间的相互作用.发现当存在陷俘势时两个凝聚体间发生弹性碰撞;在零时刻撤掉陷俘势时两个凝聚体间发生干涉现象;当t=2时撤掉陷俘势两个凝聚体间发生了复杂现象.     

First-Principles Study of Electronic Properties in PbS（1^-00） with Vacancy Defect

Electronic properties of both Pb and S vacancy defects in PbS（1^-00） have been studied using the first-principles density functional theory （DFT） calculations with the plane-wave pseudopotentials. It is found that the density of states （DOS） near the top of the valence band and the bottom of the conduction band is significantly modified by these defects. Our calculation indicates that in the case of S vacancy defects the Fermi energy shifts to the conduction band making it as an n-type PbS （donor）. However, in the case of Pb vacancy, because of the appreciable change of the DOS, the system acts as a p-type PbS （accepter）. In addition, the structural relaxation shows that the defect leads to outward relaxation of the nearest-neighbouring atoms and inward relaxation of the next-nearest neighbouring atoms.     

环形光束的非线性传输及聚焦特性研究

针对用于产生光镊的环形光束,利用分步傅里叶-贝塞尔变换算法,对二维环形超高斯光束的非线性传输及聚焦过程进行了数值模拟,给出了环形光束聚焦场附近的光强分布,并分析了非线性调制对聚焦性质(包括焦面中心光强、焦面光强的横向分布、轴上光强和光束质量)的影响.研究表明,从聚焦角度来看,非线性调制中的位相调制比振幅调制对环形光束聚焦性质的影响程度要大;从非线性传输角度来看,随着非线性介质长度的增加,位相调制和振幅调制对环形光束聚焦性质各有不同程度的加剧,其中非线性作用对振幅调制的影响要比位相调制明显.     

“神龙一号”加速器束流输运系统研制

文章系统介绍了“神龙一号”直线感应加速器束流输运系统的研制过程和取得的成果, 重点阐述了螺线管线圈、二极校正线圈、多功能腔等关键单元部件的设计、传输元件的磁轴测量和准直安装、束线的总体布局、束流调试等研究内容. 束流调试结果表明, 该束流传输线的设计是成功的, 并且具有较宽的动态适应范围. 最后, 结合束流调试的经验, 提出了一些建议供以后工作参考.     

原子吸收光谱法和ICP-AES测定水中钠的比较

测定水中钠的含量,ICP-AES具有直接进样、测量稳定、校准曲线线性范围宽等特点;而原子吸收光谱法需要加入消电离剂硝酸铯或氯化铯,实际操作麻烦.该方法经过t检验证明与标准方法无显著性差异,加标回收率为96.9%-104%,可以代替原子吸收光谱法,相对标准偏差各为0.7%、0.8%.     

Quantum Phase Transition and Ferromagnetic Spin Correlation in Parallel Double Quantum Dots

We investigate electronic transport through a parallel double quantum dot （DQD） system with strong on-site Coulomb interaction, as well as the interdot tunnelling. By applying numerical renormalization group method, the ground state of the system and the transmission probability at zero temperature are obtained. For a system of quantum dots with degenerate energy levels and small interdot tunnel coupling, the spin correlations between the DQDs is ferromagnetic, and the ground state of the system is a spin-1 triplet state. The linear conductance will reach the unitary limit （2e^2/h） due to the Kondo effect at low temperature. As the interdot tunnel coupling increases, there is a quantum phase transition from ferromagnetic to anti-ferromagnetic spin correlation in DQDs and the linear conductance is strongly suppressed.     

An All-Solid-State Tunable Dual-Wavelength Ti：Sapphire Laser with Quasi-Continuous-Wave Outputs

A high power dual-wavelength Ti：sapphire laser system with wide turning range and high efficiency is described, which consists of two prism-dispersed resonators pumped by an a11-solid-state frequency-doubled Nd：YAG laser. Tunable dual-wavelength outputs, with one wavelength range from 750nm to 795nm and the other from 80Ohm to 850nm, have been demonstrated. With a pump power of 23 W at 532nm, a repetition rate of 6.5kHz and a pulse width of 67.6ns, the maximum dual-wavelength output power of 5.6 W at 785.3nm and 812.1 run, with a pulse width of 17.2ns and a line width of 2nm, has been achieved, leading to an optical-to-optical conversion efficiency of 24.4%.     

MCe03:Eu3+(M=Sr,Ba)的合成及发光性质研究

利用高温固相反应法合成了Eu3 掺杂的MCeO3(M=Sr,Ba)发光粉末样品,采用X射线衍射技术和荧光光谱等测试手段分别对其物相组成和发光性质进行了研究.X射线衍射结果显示,Eu3 离子容易替代MCeO3品格中M2 离子的位置.荧光光谱测试结果表明,Eu3 掺杂的SrCeO3和BaCeO3样品在紫外波段存在着非常宽的吸收带,峰值分别位于311和320 nm左右,它们属于Ce4 -O2-的电荷迁移带,SrCeO3和BaCeO3基质与Eu3 离子之间存在着能量转移.在MCeO3:Eu3 样品中,Eu3 的发射主要来自于5D0激发态能级,其中以磁偶极跃迁D0-7F1发射强度为最大;此外样品中还存在着较高的5D1激发态能级的辐射跃迁.SrCeO3:Eu3 样品的发射强度远大于BaCeO3:Eu3 样品.