A Novel Structure Observed on the Phospholipid Langmuir-Blodgett Bilayer by Atomic Force Microscopy

A novel roundish objects were observed directly by means of atomic force microscopy to be formed on dimyristoylphosphatidylcholoine (DMPC) Langmuir-Blodgeet bilayer films. The roundish structure may be resulted from the aggregation of DMPC molecules because of the collapse of DMPC liposomes formed on the interface of water/organic phase when they lose the water support.     

Collisionless Trapped Ion Temperature Gradient Instabilities

Under the fluid limit, the collisionless electrostatic trapped ion temperature gradient instabilities are investigated by retaining the trapped ion parallel compressibility in the long wavelength limit. The two-scale analysis should be employed in view of the fact that the eigenfunctions vary over the connection width scale with an envelope varying over a secular scale. The results show that the slab branch of trapped ion modes, corresponding to the aperiodic trapped ion instability discovered by Kadomtzev, propagates along ion diamagnetic direction. The toroidd branch is also obtained in low-frequency and long wavelength limit. In this case, besides the unstable one propagating in ion diamagnetic direction, there exists a marginally stable toroidal odd mode propagating in electron diamagnetic direction. The eigenfrequencies and perturbative structures of these unstable modes are given analytically and numerically. The numerical results are in good agreement with the analytical ones.     

1-芳基-5-苯并三唑基-1-戊烯的合成及其位置异构体的GC-MS研究

本文研究了1-芳基-5-苯并三唑基-1-戊烯(3和3')的两种通用合成方法, 并用色谱-质谱联用仪分析了四种不同异构体的组成。根据其MS谱图中[M-29]^+^·及[M-57]^+^·峰的强度, 可以方便地区分1-N和2-N烷基化产物。     

The Unitarity of the W(3) Algebra from SU(3) Parafermion

We express the vacuum expectation value of the SU(3)k parafermion fields by that of two bosons and SU(3)_k current algebra. When k = 1,2,3, the SU(3)_k current algebra becomes an inner product of a unitary representation, and T(z), W⁽³⁾(z) are equivalent to "quasiself-adjoint" operators in this represen tation.     

2,5-噻吩齐聚物链结构的表征

本文合成、分离和纯化了一系列2,5-噻吩齐聚物(n=2-5),作为聚噻吩的模型化合物.首次系统报道了这类化合物的质谱、^1H、^1^3C核磁共振谱和红外光谱,以对其结构进行表征,所得结果与用电化学方法制备的中性聚噻吩的相应结果进行比较,表面聚噻也具有α-α'连结的结构.     

铀的三元协萃规律研究-HTTA-HPMBA-(C8H5)4AsCl三元协萃高氯酸铀酰的机理

本文研究α-噻吩甲酰三氟丙酮(HTTA),1-苯基-3-甲基-4-苯甲酰基-5吡唑啉酮(HPMBP)与四苯基砷氯(C5H5)4AsCl的氯仿溶液从高氯酸中萃取U(VI).该体系属螯合,离子缔合AAC类,测定了其二元及三元协同萃取体系平衡常数.用亚甲基蓝光度法测定了萃合物中ClO4^-的存在,用斜率法确定二元协萃物组成为(C6H5)4As^+[UO2(ClO4)(TTA)2]^-和C6H5)4As^+[UO2(ClO4)(PMBP)2]^-三元协萃配合物为(C6H5)4As^+[UO2(ClO4)(TTA)(PMBP)]^-.     

甲烷、氮、硫化氢、氨和水混合物的放电反应

以CH4、N2加热含氨、硫化氢水相混合物, 在3500V高压、电火花连续放电24h, 考察H2S在化学进化中的作用. 气相用质谱分析 , 水相经浓缩纯化并制成衍生物, 气相色谱测定有14种氨基酸. 体系中若无硫化氢时, 只生成六种氨基酸. 这表明硫是合成生命基础分子的必需元素, 可能在原始地球空间的化学进化过程中起重要作用.     

SOME REPRESENTATIONS FOR TIME-DEPENDENT HARMONIC OSCILLATOR

In terms of the IWOP (integration within ordered product) technique, we construct squeezed state formulatiion for the time-dependent harmonic oscillator.The formulation is based on the Lewis-Riesenfeld quantum theory.Some other representations are also found with the same technique.     

第五 六族元素的有机化合物在有机合成中应用的研究XXXI. 应用稳定胂叶立德合成β-酮酸酯和β-二酮的一种简便方法

本文报道一种在温和条件下使稳定胂叶立德(1)砷-碳键断裂的方法,从而合成了β-酮酸酯和β-二酮类化合物,特别是相应的含氟化合物,该方法操作简便,产物容易分离提纯,得率较好。     

THE SYMMETRY BREAKING IN LIVING SYSTEMS Ⅱ. MULECULAR CHIRALITY AfdD MORPHOLOGICAL CHIRALITY

This article is a further study on the chiral symmetry breaking in living systems.Even when the instability of racemic thermodynamic branch and parity violating force exist simultaneously, the preferred synthesis of handed molecules can not be guaranteed.The coupling between a chiral field and macroscopic mode of a morphologically chiral symmetry in molecular sense. The specific conditions which ensure the molecular sense.The specific condition which ensure the molecular chiral symmetry breaking are elabrated.