Growth of single-crystal magnetite nanowires from Fe3O4 nanoparticles in a surfactant-free hydrothermal process

Single-crystal magnetite nanowires with average diameter of ca. 20 nm and length of up to several micrometers were prepared by a simple alkaline surfactant-free hydrothermal process. The crystallinity, purity, morphology, and structural features of the as-prepared magnetite nanowires were investigated by powder X-ray diffraction, transmission electron microscopy (TEM) and selected area electron diffraction. The composition and length of nanowires depends on the pH, with higher pH favoring longer nanowires composed entirely of Fe₃O₄. A mechanism for nanowire growth is proposed.     

D.C.隶属函数模糊集及其应用(Ⅱ)--D.C.隶属函数模糊集的万能逼近性

本文是D．C．隶属函数模糊集及其应用系列研究的第二部分。指出在实际问题中普遍选用的三角形、半三角形、梯形、半梯形、高斯型、柯西型、S形、Z形、π形隶属函数模糊集等均为D．C．隶属函数模糊集，建立了D．C．隶属函数模糊集对模糊集的万有逼近性。探讨了D．C．隶属函数模糊集与模糊数之间的关系，给出了用D．C．隶属函数模糊集逼近模糊数的e-Cellina逼近形式，得到模糊数与D．C．函数之间的一个对应算子，指出了用模糊数表示D．C．函数的问题。     

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By using Fluent software with the Eulerian multiphase model and Non-equilibrium boiling model, the subcooled flow boiling heat transfers was numerically simulated in the plain upward vertical tubes under the condition of one-side heating. The influences of the different mass flux, inlet temperatures and heat flux on the heat transfer coefficient, the void fraction and heat transfer deterioration were investigated.     

First Total Synthesis of 12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one

12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one 9 was isolated from the twigs ofCroton salutaris1. Many diterpenes exhibit significant bioactivities, such as antibac-terial and antitumour and 9 has a rare structure. In order to study the relationshipb…     

Investigation of a liquid-liquid extraction system based on non-ionic surfactant-salt-H2O and mechanism of drug extraction

Based on the investigation of a non-ionic surfactant-salt-H₂O liquid-liquid extraction system, general rules concerning salt selection are concluded and the mechanism of phase separation is explained. The extraction behavior of chlorpromazine hydrochloride (CPZ) and procaine hydrochloride (PCN) in such a system is studied. Research shows that the extraction efficiency of CPZ can amount to 96% by twice extraction, which means that quantitative extraction is realized, while that of PCN is 77%. This system produces distribution coefficients (K_D) of 12.3 and 2.6, respectively, for CPZ and PCN. Extraction mechanism is deduced according to ultraviolet absorbance; and molecular fluorescence spectra change of the drugs in the system studied.     

晶化温度对中孔分子筛（M41S）结构转变的影响

在低表面活性剂浓度及低表面活性剂与氧化硅比的条件下，研究了十六烷基三甲基溴化铵－硅酸钠体系中晶化温度对中孔分子筛Ｍ４１Ｓ材料结构转变的影响。结果有，晶化温度提高至１３５℃改变了原六方晶相ＭＣＭ－４１的结构，晶化温度提高到１５０℃后，中孔结构六方ＭＣＭ－４１晶格转变为变不稳定的层状相，     

希土Eu(Ⅲ)与2-丙酰-茚满二酮-1,3的二元、三元配合物的合成、表征及发光性能研究

合成2-丙酰-茚满二酮-1,3及其Eu(Ⅲ)的二元、三元固态配合物,经化学分析、元素分析确定了配合物的化学组成,通过红外光谱、紫外光谱进行表征,用配合物的荧光光谱和配体低温磷光光谱分析了配合物的荧光强度和能有效发光的原因.     

The Purification and Rapid Identification of Heavy Metal-binding Peptides of Water Hyacinth

This paper studies the rapid identification of heavy metal-binding peptides (phytochelatin) by taking Water Hyacinth as a model plant. Plants were cultured in water containing 2 μg/ml Cd2+ for 13 days. The Sephadex G-50 chromatography of root extract under low salt concentration (0. 01 mol/L PBS) gave a Cd-binding peak with MW of 10 ,000 determined by SEC HPLC. After oxidation with performic acid, its SEC HPLC molecular weight decreased to below 1300 and the reverse phase HPLC showed one peptide peak, whose amino acid composition is the same as that of the sample never undertaking oxidation, and (Glu/Gln):Cys:Gly=2:2:1. According to the general structure of phytochelatin (γ-Glu-Cys)n-Gly, n is 2 in this case. The protocol including the sequential steps of Sephadex G-50 chromatography→performic acid oxidation→reverse phase HPLC→amino acid analysis is a rapid and effective method to identify the existence of phytochelatin and determine its values of n.     

二、三分枝甘露糖簇衍生物的合成

采取一种有效途径合成了二、三分支的甘露糖簇分子．甘露糖经烯丙苷化、乙 酰基保护后，将其烯丙基的双键氧化得到带有羧基连接臂的甘露糖衍生物，然后再 分别与l，6-己二胺和三(2-氨乙基)胺进行缩合反应，最后脱掉保护基，得到二分 枝甘露糖簇化合物6和三分枝甘露糖簇化合物8．     

双波长分光光度法同时测定岩石矿物中的微量金和钯

本文提出以硫代米蚩酮为显色剂，用双波长分光光度法同时测定岩石矿物中的微量金和钯的方法，消除了测定金钯的相互干扰，该方法简便，快速，选择性好，用于矿石样品中金和钯的测定，结果满意。