Crystal Structure and Thermodynamic Study of Ephedrine Hydrochloride C10H16NOCI（s）

The crystal structure of ephedrine hydrochloride was determined by means of X-ray crystallography.The crystal system of the compound is monoclinic,and the space group is P21.Unit cell parameters are a=0.7308(6) nm,b=0.6124(5) nm,and c=1.2618(11) nm;α=90°,β=102°,and γ=90°;Z=2.Low-temperature heat capacities of the title compound were measured with an improved precision automated adiabatic calorimeter over a temperature range from 77 K to 396 K.A polynomial equation of the heat capacities as a function of temperature in the temperature region was fitted by the least-squares.Based on the fitted polynomial equation,the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at the intervals of 5 K.     

梯度磁场中薄膜厚度梯度的形成机理

借助于基片下方放置的磁铁，在溅射的放电空间中引入了纵向的梯度磁场，辉光放电时，其外貌发生了显著的收缩，由此沉积的薄膜在平面内存在明显的厚度梯度，用磁场中带电粒子的运动理论解释了此种薄膜的形成机制。     

Global stability for n-species lotka-volterra systems with delay,ii: reducible cases,sufficiency

In this paper an n-species delayed Lotka-Volterra system without de1ayed intraspecific competitions is considered. It is proved that the system is globally stable for all off-diagonal delays T_ij≥0 provided the interaction matrix A of the system satisfies the weakly diagonally dominant Condition (WDD)     

数域Q(P_1~(1/2),…,P_t~(1/2))(t≥4)的类数为偶数

设t≥4，ｐ１，…，ｐｔ为不同的模４余１的素数，本文证明了数域P1~(1/2)，…，Pt~(1/2)的类数为偶数．     

跨层级性别多样性变量在工作满意度和离职意图之间的调节作用

本研究在国外研究的基础上,将不同职务层级的性别多样性变量引入离职意图的前因变量模型中,并检验了多样性变量对于工作满意度和离职意图之间的调节效应。在对298个样本做回归分析后,发现了高层管理者和中层管理者性别多样性变量对离职意图的显著影响作用,以及基层管理者和上级性别多样性变量对于工作满意度和离职意图的调节作用。     

Revêtements modérés et groupe fondamenttal de graphe de groupes

Let R be a discrete complete valuation ring, with algebraically closedresidue field. Let X be a semi-stable R-curve, with smooth generic fibre. In this paper we study tame coverings of X.     

非平稳随机过程模拟的一个谱表示方法

本文由Priestley渐进谱理论导出了非平稳随机过程蒙特卡罗模拟的一个谱表示方法.按照该方法,样本过程可直接由一余弦级数公式计算产生.可以证明,当级数项数足够大时,模拟的样本过程可准确地反映非平稳随机过程规定的性质;当产生的样本过程足够多时,其总体均值和总体自相关函数均趋于相应目标函数;样本过程随着级数项数趋于无穷而渐近呈正态分布.本文方法最显著的特点在于可以借助随机相位角产生具有某些预期特征的样本过程.     

α-四(对磺酸钠苯氧基)酞菁锌(钴,镍)光敏剂的光动力性质研究

采用UV-Vis光谱、红外吸收光谱、CHN元素分析及激光解析飞行时间质谱对α-四(对磺酸钠苯氧基)酞菁锌(钴,镍)[α-PhSPcZn(Co,Ni)]进行表征.在光诱导条件下,采用四甲基偶氮唑蓝比色法(MTT法),考察了光敏剂的中心原子、浓度和光照时间等条件下对癌细胞的抑制作用.结果显示,光照15min、浓度为0~100mg·L-1范围内时,α-PhSPcZn的抑瘤率高于α-PhSPcCo和α-PhSPcNi.抑瘤率均随光照时间和配合物浓度的增加而升高,α-PhSPcZn的抑制率可达54%,其IC50值为75mg·L-1.     

1,3-双[3-(1-甲氧基-2-羟基丙氧基)丙基]封端聚硅氧烷的合成

以1,3-双[3-(1-甲氧基-2-羟基丙氧基)丙基]四甲基二硅氧烷和八甲基环四硅氧烷(D4)为原料,通过阳离子催化开环聚合制备了1,3-双(3-(1-甲氧基-2-羟基丙氧基)丙基)封端聚硅氧烷,研究了反应温度,反应时间,催化剂种类及加入量对于聚合反应的影响,结果表明,最佳反应条件为:反应温度65℃,反应时间24h,浓硫酸作为催化剂加入量为反应物质量的0.3%,此时反应拥有最高的转化率。通过红外光谱与核磁共振光谱对产物进行了表征。     

Deoxygenation of methyl laurate to hydrocarbons on silica-supported Ni-Mo phosphides: Effect of calcination temperatures of precursor

SiO2-supported Ni-Mo bimetallic phosphides were prepared by temperature-programmed reduction(TPR) method from the phosphate precursors calcined at different temperatures. Their properties were characterized by means of ultraviolet-visible diffuse reflectance spectroscopy(UV-Vis DRS), H2temperature-programmed reduction(H2-TPR), X-ray diffraction(XRD), transmission electron microscopy(TEM), CO chemisorption, H2 and NH3temperature-programmed desorptions(H2-TPD and NH3-TPD). Their catalytic performances for the deoxygenation of methyl laurate were tested in a fixed-bed reactor. When the precursors were calcined at 400 and 500?C, respectively, Ni Mo P2 phase could be formed apart from Ni2 P and Mo P phases in the prepared C400 and C500 catalysts. However, when the precursors were calcined at600, 700 and 800°C, respectively, only Ni2 P and Mo P phases could be detected in the prepared C600, C700 and C800 catalysts. Also, in C400, C500 and C600 catalysts, Mo atoms were found to be entered in the lattice of Ni2 P phase, but the entering extent became less with the increase of calcination temperature. As the calcination temperature of the precursor increased, the interaction between Ni and Mo in the prepared catalysts decreased, and the phosphide crystallite size tended to increase, subsequently leading to the decrease in the surface metal site density and the acid amount. C600 catalyst showed the highest activity among the tested ones for the deoxygenation of methyl laurate. As the calcination temperature of the precursor increased, the selectivity to C12 hydrocarbons decreased while the selectivity to C11 hydrocarbons tended to increase. This can be mainly attributed to the decreased Ni-Mo interaction and the increased phosphide particle size. In sum, the structure and performance of Ni-Mo bimetallic phosphide catalyst can be tuned by the calcination temperature of precursor.