大气激光通信链路的性能仿真

大气衰减和大气湍流严重影响着大气激光通信的链路质量。建立了大气信道的激光通信链路模型，研究了衰减信道和湍流信道中光链路的传输影响，对最大通信速率、链路功率余量和误码率进行了分析和计算。结果表明，大气湍流严重影响系统误码率，当大气闪烁指数斫是0．07时，可达到的最小误码率为10^-9。分析结果可为系统设计提供参考依据。     

稀土、2,2''''-联吡啶、邻氨基苯基苯甲酸配合物合成、光谱表征及荧光性质

2,2'-联吡啶(bipy)、邻氨基苯基苯甲酸(HL)与稀土离子(RE=Tb,Eu,Sm,Nd)合成了固体稀土配合物.用元素分析、摩尔电导、紫外光谱、红外光谱、差热-热重分析和荧光光谱,对配合物的组成进行了确定和表征,并对TbL3和TbL3·bipy·3H2O的荧光性能进行了测试和讨论.TbL3·bipy·3H2O的荧光强度比TbL3的荧光强度强.     

稀土、2-羟基-3-萘甲酸、邻菲咯啉三元配合物合成及表征

在乙醇溶液中合成了稀土离子(RE=Tb,Eu,Sm,Nd)与2-羟基-3-萘甲酸(HL)、邻菲咯啉(phen)固体配合物。通过元素分析、红外光谱、紫外光谱、差热-热重分析,确定了配合物的组成为REL₄·phen₂·Na·H₂O。初步研究了这些配合物的谱学性质并推测出羧基(—COO—) 与稀土离子和钠离子属于桥式配位, 形成了链状结构的化合物。其中钠离子和稀土离子分别为六配位和八配位模式。     

分子结构振动固有频率与链烷烃热力学性质的定量关系

用分子结构固有频率和分子中的甲基数作为分子结构信息指数,建立链烷烃分子结构与热力学性质的双参数QSPR模型.该模型用于18种链烷烃分子的标准生成焓、标准熵和标准生成自由能实验值的回归分析,得到相关程度大于0.999的标准生成焓、标准熵回归方程和相关程度大于0.99的标准生成自由能回归方程.所得方程用于67种链烷烃的标准生成焓、标准熵和标准生成自由能预测,结果与实验值的相关程度均大于0.9950.     

General Formulae for Two Pseudo-differential Operators

Some general formulas in the Sato theory related to the nonisospectral KP and mKP hierarchies are derived for simplifying calculations.     

A Parametric Dynamic Model of Dark Energy

The double complex symmetric gravitational theory is extended to the parametric symmetric gravitational theory by introducing a parameter β. Hence parametric Friedmann-Robertson-Walker equations are obtained and some characters of dark energy in corresponding spaces are discussed by taking different values of β. In our method some previous results can be included as the special case of our results. It is worth noting that some characters of dark energy can be more intuitively described in our model. By analysis, we can predict that the fate of universe would be a Big Rip in the future, and also find that the state parameters for the two different constraint conditions wФ are consistent with the present cosmological observations.     

免疫纳米金催化氯金酸-盐酸羟胺光度法检测免疫球蛋白G

在pH 2.27的柠檬酸钠-盐酸缓冲溶液中,纳米金对氯金酸-盐酸羟胺生成较大粒径金颗粒这一慢反应具有较强的催化作用。较大粒径金颗粒在600～1 000 nm处有一个较宽的吸收峰。将纳米金标记羊抗人IgG获得免疫纳米金,免疫纳米金也具有相同催化效果。在一定条件下,金标记羊抗人IgG与IgG发生特异性结合生成纳米金免疫复合物。以16 000 rpm速度离心分离获得未反应的纳米金标抗上层溶液。以它作为催化剂催化氯金酸-盐酸羟胺微粒反应,700 nm处的吸光度A_{700 nm}线性降低。其降低值ΔA_{700 nm}与IgG在0.1～10 ng·mL-1范围内呈良好线性关系, 检出限为0.06 ng·mL-1。本法具有灵敏、快速和较高的特异性,用于定量分析人血清IgG,结果满意。     

Enhanced Kerr Nonlinearities Caused by Cross Talk Between Optical and Microwave Transitions

We investigate the enhanced Kerr nonlinearities in four-level atomic vapors driven by a coupling, probe and microwave fields. Under the optical one-photon and two-photon resonant conditions, the linear and nonlinear responses of the weak probe field can be modified by the cross talk among optical and microwave transitions. The enhanced Kerr nonlinearity can form bright optical solitons of the probe field.     

基于时序多光谱影像的干旱草原区开采扰动信息提取方法

露天开采会彻底改变原有土地利用景观格局,直接破坏当地生态环境,甚至会影响附近居民的生产和生活,因此越来越多的学者开始关注开采扰动。先前有关利用时序多光谱影像提取开采扰动的研究区集中于扰动形式单一的森林区。而我国露天煤矿大多集中于草原区,且我国东北部的草原矿区因其脆弱的生态环境以及其他多种扰动形式的存在,使得开采扰动识别更加困难。为明确我国东北部生态脆弱区草原露采场的开采扰动,以胜利矿区为例,利用1986年-2017年27期Landsat多光谱遥感影像,基于归一化植被指数NDVI（normalized difference vegetation index）的长时间序列轨迹变化特征（为了去除物候、云和阴影等对时序多光谱影像的影响,利用BISE-WT滤波器对原始NDVI时间序列进行滤波处理, 有效地去除时序NDVI数据中的噪声并同时保留有效信息）,经过样本点训练,获得CV阈值（变异系数coefficient of variation）和Max阈值（植被阈值）,构建CV-Max扰动识别模型,提取研究区的扰动分布。并利用植被阈值,分析NDVI时序轨迹,获得扰动年际信息,重构扰动历史地图;进而通过分析研究区典型地物的光谱特征,构建裸煤提取规则,以此来提取研究区的裸煤分布;最后通过构建裸煤及扰动区两者间的拓扑关系,进行空间拓扑叠置分析,从而获得开采扰动信息。经过精度验证,开采扰动的提取精度达到93.17%（Kappa系数=0.85）,扰动年际信息提取精度达到83.35%（Kappa系数=0.81）。结果表明：在研究期间,空间上,开采扰动面积占研究区总面积的8.90%;时间上,开采扰动的发生集中于2000年-2009年,期间开采扰动像元占开采扰动总像元的76.70%;1988年-1998年矿区属于土地损毁初始期,2000年-2005年矿区属于土地损毁加速期,2006年-2009年矿区属于土地损毁高峰期,2010年-2017年开采扰动像元占比趋势比较平缓且持续处于较低水平,矿区土地损毁范围基本稳定。所提出的针对我国东北部生态脆弱性草原矿区,基于时序多光谱影像,利用植被指数NDVI和裸煤光谱特征提取开采扰动信息的方法是可行的,该研究结果可为干旱、半干旱草原露天矿区的可持续发展提供数据和理论方法支撑。     

Chebyshev spectral variational integrator and applications

The Chebyshev spectral variational integrator(CSVI) is presented in this paper. Spectral methods have aroused great interest in approximating numerically a smooth problem for their attractive geometric convergence rates. The geometric numerical methods are praised for their excellent long-time geometric structure-preserving properties.According to the generalized Galerkin framework, we combine two methods together to construct a variational integrator, which captures the merits of both methods. Since the interpolating points of the variational integrator are chosen as the Chebyshev points,the integration of Lagrangian can be approximated by the Clenshaw-Curtis quadrature rule, and the barycentric Lagrange interpolation is presented to substitute for the classic Lagrange interpolation in the approximation of configuration variables and the corresponding derivatives. The numerical float errors of the first-order spectral differentiation matrix can be alleviated by using a trigonometric identity especially when the number of Chebyshev points is large. Furthermore, the spectral variational integrator(SVI) constructed by the Gauss-Legendre quadrature rule and the multi-interval spectral method are carried out to compare with the CSVI, and the interesting kink phenomena for the Clenshaw-Curtis quadrature rule are discovered. The numerical results reveal that the CSVI has an advantage on the computing time over the whole progress and a higher accuracy than the SVI before the kink position. The effectiveness of the proposed method is demonstrated and verified perfectly through the numerical simulations for several classical mechanics examples and the orbital propagation for the planet systems and the Solar system.