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121.
122.
提出一种利用萃取法间接测定Lewis碱性萃取剂碱度的简便方法, 选择常用的Lewis碱性萃取剂TOA/正辛醇和TRPO/煤油, 测定了其碱度, 为今后络合萃取剂的选择及其机理的研究提供理论指导. 相似文献
123.
β-烟酰胺腺嘌呤二核苷酸(NADH),俗称还原型辅酶, 是参与酶催化反应中的一种重要的辅酶, 大约有几百种脱氢酶催化底物反应后能引起NADH含量的变化,因此,电化学检测NADH是传感器研究中1个重要的课题.由于在电极上的氧化有较大的过电位并且不可逆[1],如果在高电位下检测 NADH,试样中其他的电活性物质就会干扰测定,并且NADH在高电位氧化过程中会发生副反应而污染电极,使测定重复性变差[2].人们正努力寻找能够降低NADH氧化过电位的新的材料.近来,介孔分子筛子以其独特的结构和催化作用能够为电子传递提供环境以及可以抵抗生物降解而受到关注[3].介孔分子筛具有大的比表面, 高机械、热、化学稳定性, 好的吸附和渗透性,有着适度的维度能够作为一种通用的纳米反应器.这里采用Ti-MCM-41修饰GCE来降低NADH的过电位.实验表明该修饰电极对NADH的催化电流很大,稳定性好,响应速度快,实现了对NADH的低电位检测. 相似文献
124.
Cotton FA Liu CY Murillo CA Villagrán D Wang X 《Journal of the American Chemical Society》2003,125(44):13564-13575
Reactions of Mo(2)(O(2)CCH(3))(DAniF)(3), DAniF = N,N'-di-p-anisylformamidinate, with oxamidate dianions [ArNC(O)C(O)NAr](2-), Ar = C(6)H(5) and p-anisyl, give pairs of isomeric compounds where the [Mo(2)] units are bridged by the oxamidate anions. For the alpha isomers, the C-C unit of the dianion is nearly perpendicular to the Mo-Mo bonds, and these are essentially perpendicular to each other. For the beta isomers, the corresponding C-C unit and the Mo-Mo bonds are essentially parallel to each other. Each type of isomer is stable in solution. The electronic communication as measured by the DeltaE(1/2) for the oxidation of each of the Mo(2) units is significantly better for the beta isomers. This is supported also by the appearance of what is conventionally called an intervalence charge-transfer band in the near infrared region upon oxidation of the beta isomers but not the alpha isomers. Molecular mechanics and DFT calculations help explain the relative conformations in the alpha isomers and the relative energy differences between the alpha and beta isomers. 相似文献
125.
In this paper, pressurized CEC was used for the separation and determination of seven fluoroquinolones (FQs). The effect of different experimental conditions, such as the concentration and pH of the buffer, the organic modifier concentration, the surfactant and ion-paring agents added to the electrolyte, and applied voltage were studied. All the seven FQs were baseline separated using mobile phase containing 27% v/v ACN, 5 mmol/L Na2HPO4 buffer (pH 4.0 adjusted using citric acid), 11 mmol/L SDS, and 0.01% TEA v/v at detection wavelength of 287 nm and at an applied voltage of -10 kV. The calibration curves were linear (r>0.9991) over a concentration range of 1.0-50.0 mg/L for norfloxacin (NFLX); 2.5-50.0 mg/L for fleroxacin (FLX), ciprofloxacin (CPFX), and lomefloxacin (LMX); and 5.0-50.0 mg/L for enoxacin (ENX), ofloxacin (OFLX), and gatifloxacin (GFLX). The detection limits (S/N = 3) for ENX, OFLX, FLX, NFLX, CPFX, LMX, and GFLX were 0.5, 0.8, 0.4, 0.2, 0.4, 0.5, and 1.0 mg/L, respectively. The method is simple, rapid, and reproducible. It was successfully applied to the analysis of fish muscle samples spiked with FQs. Mean recoveries ranged from 81.6 to 97.6%. 相似文献
126.
DNA分子在气液界面的组装相变特性及其LB膜结构研究 总被引:5,自引:0,他引:5
对十八胺与DNA在气液界面上组装及其相变过程进行了研究,利用AFM观察了不 同压力下转移的DNA复合LB膜结构。发现在低表面压时,DNA复合单分子膜表现为技 术发散的分形结构;随着压力的升高,DNA复合膜逐渐由紧密的网状排布结构变为 团聚的块状和团簇结构。表明通过调节膜压,可使膜内DNA分子的构象发生大的变 化,从而生成具有特定形态的二维纳米图案。这种具有特殊形态和结构的DNA LB膜 可望为合成新型生物纳米结构有序功能体系提供模板。 相似文献
127.
Two compounds of a new type, [Mo(2)](CH(3)O)(2)M(CH(3)O)(2)[Mo(2)] where [Mo(2)] is an abbreviation for Mo(2)[(p-MeOC(6)H(4))NCHN(p-MeOC(6)H(4))](3) and M = Zn (1) and Co (2), are reported. Discrete [M(OR)(4)](2-) ions, either as such or in the mu(2),eta(4) role, have not heretofore been described. In these compounds they have distorted tetrahedral structures and bridge two [Mo(2)] groups in much the same way as did SO(4)(2-), MoO(4)(2-), and WO(4)(2-) ions in other recently reported compounds (Cotton, F. A.; Donahue, J. P.; Murillo, C. A. Inorg. Chem. 2001, 40, 2229). The (1)H NMR spectrum of 1 and the visible spectrum and magnetic properties of 2 are consistent with these structures. The M(OCH(3))(4) bridges are moderately effective in coupling the two [Mo(2)] redox centers. Compounds 1 and 2 may also be viewed as having Zn(II) and Co(II) centers tetrahedrally coordinated by the bidentate ligand [Mo(2)[(p-MeOC(6)H(4))NCHN(p-MeOC(6)H(4))](3)(OMe)(2)](-). From that point of view they may be compared with Zn(DPM)(2) and Co(DPM)(2) (3), where DPM is the anion of dipivaloylmethane. For purposes of comparison, 3 has been fully characterized structurally, spectroscopically, and magnetically. Close analogies between 2 and 3 are shown to exist. 相似文献
128.
The interaction of Methylthymol Blue(MTB)-Zinc(Ⅱ) compound and Alizarin Red S(ARS)-Aluminum(Ⅲ) compound with Bovine serum albumin (BSA) was investigated by UV-Vis spectrophotometric method in acidic buffer solution. MTB-Zn(Ⅱ)-BSA was a blue color compound, which possesses maximum absorption at 613 nm with 172 nm, 174 nm and 18 nm of red shift compared to the MTB, MTB-BSA and MTB-Zn(Ⅱ) complexes respectively. Dual wavelength substantial amount ratio method, balance dialysis substantial amount ratio method and unity wavelength substantial amount ratio method were compared. The following results were obtained: the apparent molar absorptivity of MTB-Zn(Ⅱ) with BSA was ε=2.20×104 L·mol-1·cm-1. Conditional proportion were defined, nMTB∶nZn(Ⅱ)∶nBSA=2∶2∶1; condition combination constant, K=2.07×1010. Combination proportion were defined, nARS∶nAl(Ⅲ)∶nBSA=6∶4∶1. Condition equilibrium constant of reaction of ARS-Al(Ⅲ) with BSA was K=8.80×108. The apparent molar absorptivity of ε=2.65×104 L·mol-1·cm-1. It is suggested that combination between BSA and MTB-Zn(Ⅲ) is due to coordination force. That combination between BSA and ARS-Al(Ⅲ) is due to the coordination bond and electrostatic force. 相似文献
129.
高速逆流色谱与质谱联用在中药分析中的应用 总被引:10,自引:0,他引:10
高速逆流色谱 ( High- speed countercurrent chromatography,HSCCC)是新型的液 -液分配色谱技术 ,它利用多层螺旋管同步行星式离心运动 ,在短时间内实现样品在互不相溶的两相溶剂系统中的高效分配 ,从而实现样品分离[1] . HSCCC分离纯化后 ,若用 MS离线检测 ,此时须挥发原 HSCCC的溶剂体系 ,才能实现样品转移 ,还可能会带来样品污染 .HSCCC与 MS的联用克服了这些缺陷 ,具有很强的实用价值 .丹参酮 A( Tashinone A)是一种结晶性菲醌类化合物 [2 ] ,在丹参乙醚提取物中含量丰富 .本文采用正己烷 -乙醚 -乙醇 -水体系 ,将 HSCC… 相似文献
130.
In the reaction of methane and carbon dioxide to C2 hydrocabons under non-equilibrium plasma, methane conversion was decreased,but selectivity of C2 hydroxarbons was increased when using La2O3/γ-Al2O3 as catalyst. So the yield of C2 hydrocarbons was higher than using plasma alone. The synergism of La2O3/γ-Al2O3 and plasma gave methane conversion of 24.9% and C2 yield of 18.1%. The distribution of C2 hydrocarbons changed when Pd-La2O3/γ-Al2O3 was used as catalyst,the major C2 product was ethylene. 相似文献