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71.
COMPONENT ALLEE EFFECTS AND STAGE‐SPECIFIC PREDATION: A BRIEF INSIGHT INTO CONSERVATION AND BIOLOGICAL CONTROL ISSUES
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In this paper, we propose a two‐stage structured population model subject to component Allee effects in fecundity and maturation, and with two disturbances (predation only and harvest and predation) acting on both stages. It is shown that this combination leads to a demographic Allee effect—a characteristic that could be exploited in pest biological control, but on the other hand, it represents a bane in conservation biology. The analysis is performed for disturbances with functional responses type 2 and 3, and the models show that they yield qualitatively similar results. This characteristic is discussed from the species conservation and biological control point of view, together with possible extensions of this work. 相似文献
72.
D. P. Krut’ko S. A. Belov R. S. Kirsanov D. A. Lemenovskii A. V. Churakov 《Russian Chemical Bulletin》2010,59(2):329-336
New functionalized indenyl ligands IndX = 1,3-C9H5(Pri)(CH2CH2X) (X = OMe or NMe2) and 1,3-C9H5(Pri)[CMe2CH2(2′-py)] and the zirconium sandwich complexes (IndX)Cp*ZrCl2 (Cp* is pentamethylcyclopentadienyl) were synthesized. The photochemical behavior and the reduction reactions of zirconocene
dichlorides were investigated. The properties of these compounds are determined mainly by the high lability of Zr-Ind bonds.
The reduction of (IndX)Cp*ZrCl2 (X = NMe2) selectively affords the complex Cp*[η5:η2-(C,N)-C9H5(Pri)CH2CH2N(Me)CH2]ZrH as the intramolecular NCH2-H bond activation product. The molecular structures of the complex (IndX)Cp*ZrCl2 (X = OMe) and its photochemical decomposition product [Cp*ZrCl2(OMe)]2 were established by X-ray diffraction. 相似文献
73.
74.
H. Mengmeng S. S. Karlov M. V. Zabalov K. V. Zaitsev D. A. Lemenovskii G. S. Zaitseva 《Russian Chemical Bulletin》2009,58(8):1576-1580
Geometries of 20 germylenes and 18 stannylenes based on dialkanolamines, diethylenetriamines, and related compounds were optimized
by the DFT method. It was found that the most of the germylenes and stannylenes studied are more stable as dimeric structures
of different types. The dimerization is possible due to either additional Ge-O(N) interactions or Ge-Ge bonding. The factors
leading to the stabilzation of one or another isomer are examined. 相似文献
75.
76.
Monomeric dicyclopentadienylniobium, Cp2Nb, was shown to form in high yield in solution by the action of electron donors on Cp2NbCl2. Two compounds Cp2NbCl2 and [Cp2Nb(Me)I]I are obtained from niobocene in oxidative addition reactions. 相似文献
77.
Osipov AL Vyboishchikov SF Dorogov KY Kuzmina LG Howard JA Lemenovskii DA Nikonov GI 《Chemical communications (Cambridge, England)》2005,(26):3349-3351
The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to NMR (J(H-Si)= 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane sigma-complex Cp*(iPr3P)Ru(Cl)(eta2-HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand RuCl...SiCl hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group. 相似文献
78.
A fluorocarbon-modified poly(N-isopropylacrylamide) has been synthesized by copolymerization of N-isopropyl acrylamide with a small amount of acrylate or methacrylate containing a perfluoroalkyl group. It was found that the hydrophilicity of macromolecular backbone is an important factor to the solution properties of the copolymers and that hydrophobic association between fluorocarbon groups is stronger than that between the corresponding hydrocarbon analogies. The viscosity of some of the copolymer solutions was very sensitive to temperature. It was dilatant at higher fluorocarbon comonomer content ( > 0.20-1.0 mol%) and was Newtonian at very low fluorocarbon comonomer content (0.03-0.2 mol% ) . Evidence for hydrophobic association of the fluorocarbon groups was obtained from the effects of adding Nad and surfactants on the solution viscosity. The LC-ST properties of these copolymers were studied by DSC method and this was also found to be consistent with hydrophobic association between the fluorocarbo 相似文献
79.
80.
D. A. Kissounko M. V. Zabalov Yu. F. Oprunenko D. A. Lemenovskii 《Russian Chemical Bulletin》2000,49(7):1282-1286
Reactions of 2-ethyl-5-methylcyclopenta[b]thienyllithium (thiopentalenyllithium) (2) with various electrophilic reagents afford σ-element-substituted thiopentalenes. However, the reaction with Ph3SnCl yields only one of two possible isomers,viz, triphenyl(4H-cyclopenta[b] thiophen-4-yl)stannane (4c), whereas the reactions with Me3SiCl, Me3SiCl, or Ph2PCl give both possible isomers,viz., trimethyl(6H-cyclopenta[b]thiophen-6-yl)silane (3a) and trimethyl(4H-cyclopental[b]thiophen-4-yl)silane (4a), trimethyl(6H-cyclopenta[b]thiophen-6-yl)stannane (3b) and trimethyl(4H-cyclopental[b]thiophen-4-yl)stannane (4b), or diphenyl(6H-cyclopenta[b]thiophen-6-yl)phosphine (3d) and diphenyl(4H-cyclopenta[b]thiophen-4-yl)phosphine (4d) in ratios of 1∶2, 1∶2, or 1∶1, respectively. The structure of compound4c was established by X-ray diffraction analysis. The observed regioselectivity of formation of compound4c is attributed to the specific precoordination of the tin atom by the sulfur atom of the thiopentalenyl ligand and to the
steric overcrowding of the Sn atom in organotin electrophiles.
Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1285–1289, July, 2000. 相似文献