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981.
We report simultaneous observation of coherent resonance Raman scattering and incoherently broadened resonance fluorescence following excitation of cytochrome c in the α(0, 0) region. The influence of incoherent broadening processes on resonance Raman scattering experiments is considered. 相似文献
982.
F. Ruttens R. oedeweeck F. Lopez-Arbeloa F. C. De Schryver 《Photochemistry and photobiology》1985,42(4):341-346
Abstract— The synthesis, absorption and emission properties of erythro (e) and threo (t) Na-acetyl-1-pyrenylalanyl-1-methyltryptophan methylester (APTE) are reported. From the dependency of the exciplex emission maximum on the solvent polarity, the exciplex dipole moment of erythro and threo APTE were calculated. The evolution of the ratio of the quantum yield of exciplex emission and the quantum yield of emission from the locally excited state is correlated with solvent polarity and with the tendency of the solvent to interact with the peptide chain through hydrogen bonding. It is shown that solvents, inert towards the peptide function, shift the equilibrium between the two ground state conformations towards C7 , in which an exciplex geometry can be reached. Hydrogen accepting solvents shift the conformational equilibrium towards C5 , which cannot form an exciplex directly within the lifetime of excited pyrene. 相似文献
983.
Kenneth R. Seddon 《Journal of organometallic chemistry》1985,293(1):C21-C25
A close examination of the ESR spectrum of a paramagnetic complex formed from bis(ethoxythiocarbonyl)sulfide and dimanganese decacarbonyl has revealed, for the first in this type of radical adduct, 13C hyperfine coupling in natural abundance from the carbonyl ligands. 相似文献
984.
Ta4P4S29 was prepared from the elements heated together in stoichiometric proportions in an evacuated Pyrex tube for 10 days at 500°C. The crystal symmetry is tetragonal, space group P43212, with the cell parameters: a = b = 15.5711(7) Å, c = 13.6516(8) Å, V = 3309.9(5) Å3, and Z = 4. The structure calculations were conducted from 2335 reflections and 146 variables, leading to R = 0.033. The structure basic framework, corresponding to the chemical composition [TaPS6], is made of biprismatic bicapped [Ta2S12] units (average dTaS = 2.539 Å), including sulfur pairs (average dSS = 2.039 Å), bonded to each other through [PS4] tetrahedral groups (average dPS = 2.044 Å) sharing sulfurs. This framework leaves large tunnels running along the c axis of the cell and in which (S10)∞ sulfur chains are found to be inserted (average dSS = 2.052 Å and SSS = 105.75°). Diamagnetic and semiconducting Ta4P4S29 can be formulated: TaV4PV4(S?II)16(S?II2)4(S05). 相似文献
985.
986.
The photoelectron asymmetry parameter, β, is reported for individual vibrational levels of H2+(X2Σg+) formed by photoionization of H2(X1Σg+) at wavelengths of 736, 584, 461 and 304 Å. At 584 Å, β, exhibits a monotonic increase with vibrational quantum number (decreasing photoelectron kinetic energy) confirming the trend predicted by Itikawa. 相似文献
987.
About Perrhenates. 1. On LiReO4 For the very first time anhydrous LiReO4 was prepared in transparent, colourless single crystals from Li2O2 and Re2O7 (closed Au-pipe; 350°C; 14 d). The crystal structure, P1 , with a = 9.652(1), b = 8.455(1), c = 6.928(1) Å, α = 101,53° (1), β = 106.55° (1), γ = 97.22° (1), Z = 6, dx = 4.92 g/cm3, dpyk = 4,81 g/cm3 was solved (four-circle-diffractometer data PW 1100, 2151 I0 (hkl), AgKα; R = 0.073, Rw = 0.076). There are three kinds of functionally different Li+. The Madelung Part of the Lattice Energy, MAPLE, was calculated. 相似文献
988.
Abstract —Virus-host cell interactions may be investigated by study of the enhancement of infectivity of ultraviolet (UV)-irradiated virus obtained by UV-irradiating the host cell [ultraviolet reactivation (UVR)]. This phenomenon was studied with Herpes simplex virus and normal (embryonic lung) and malignant (HeLa) human cells. Although the lung cells displayed no UVR, both the HeLa cells and a Sendai-virus carrier culture of HeLa cells demonstrated UVR capabilities. This UVR persisted at equal or increased levels for at least 24 h. Since the lung cells and HeLa cells have similar host-cell-reactivation (HCR) abilities, the differences in UVR suggests that UVR and HCR may operate by different mechanisms. 相似文献
989.
Polymorphic transformations of CoMoO4 were studied by means of high temperature X-ray measurements within the temperature range 25–1200°C. On heating phase a obtained from low temperature modification b a new modification a′ was discovered. Phase a obtained by thermal decomposition of solvated α-CoMoO4 shows different behaviour. At 700–930°C depending on the conditions of preparation it transforms irreversibly into still another modification a″. On cooling, a mixture of phases a + a″ is obtained, the presence of a″ being responsible for the explosionwise transition into b, observed around the room temperature. 相似文献
990.
Friedel-Crafts reaction of benzylic or tertiary nitro compounds with benzene gave normal alkylation products. Similarly, 2-nitropropane (2-NP) gave cumene (1) which underwent further transformation affording a mixture whose behaviour with time was investigated : results were consistent with oxidative formation of the cumyl carbonium ion (7'). 相似文献