Electric generators of singlet delta oxygen for an oxygen-iodine laser

Experimental and theoretical research into electric generators of singlet delta oxygen (SDO) for an oxygen-iodine laser made at the Lebedev Physics Institute and TRINITI is discussed. Breakdown and current-voltage characteristics of self-sustained electric discharge in SDO were studied both experimentally and theoretically, indicating that SDO and pure oxygen have quite different electric features. The electric properties and spectroscopy of an e-beam sustained discharge (EBSD) in oxygen and oxygen gas mixtures were experimentally studied. A comprehensive numerical model describing SDO kinetics in different kinds of discharge was developed. The pulsed EBSD in pure oxygen and its mixtures with noble gases was shown to be very unstable and characterized by low input energy. When adding small amounts of carbon monoxide or hydrogen, the electric stability of the EBSD increases, the specific input energy (SIE) per molecular component being more than order of magnitude higher and coming to 6.5 kJ/(l atm(O₂ + CO)) for the gas mixture O₂: Ar: CO = 1: 1: 0.1. Theoretical calculations demonstrated that, for an SIE of 6.5 kJ/(l atm), the SDO yield may reach ∼20%, exceeding its threshold value needed for oxygen-iodine laser operation at room temperature. The calibration of the optical scheme for measuring the SDO absolute concentration and yield using the detection of luminescence of the SDO going from a chemical SDO generator was performed. The measurement of the SDO yield demonstrated that it was ∼10.5% for an SIE of ∼3.0 kJ/(l atm(O2 + CO)), which is about 1.5 times less than the results of theoretical calculations for such an SIE. SDO production in RF slab discharge ignited in oxygen gas mixtures was experimentally studied, experimental SDO yield being about 10%. The choice of electrode material was demonstrated to be very important. Original Text ? Astro, Ltd., 2006.     

Benzotriazole is thermally more stable than 1,2,3-triazole

TGA, DTA and DSC analyses indicate that benzotriazole is significantly more stable thermally than 1,2,3-triazole.     

Organotellurides as a source of organometallics: application in the synthesis of (+/−)-frontalin

A masked lithium homoenolate, generated by tellurium/lithium exchange, was reacted with epoxides. The lithium compound was also converted into other organometallics such as Grignard, and cuprates and the reactivity of those organometallics with epoxides was evaluated. The same building block was employed in the synthesis of (+/−)-frontalin.     

Logarithmic L 2-Small Ball Asymptotics with Respect to a Self-Similar Measure for Some Gaussian Processes

We find logarithmic small ball asymptotics for the L₂-norm with respect to self-similar measures for a certain class of Gaussian processes including Brownian motion, Ornstein-Uhlenbeck process, and their integrated counterparts. Bibliography: 46 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 311, 2004, pp. 190–213.     

On the distribution of the number of real zeros of a random polynomial

In this note, we find the distibution of the number of real zeros of a random polynomial. We also derive a formula for the expected number of complex zeros lying in a given domain of the complex plane. Bibliography: 7 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 320, 2004, pp. 69–79.     

Transport in two dimensional electronic micro-emulsions

In two dimensional electron systems with Coulomb or dipolar interactions, a direct transition, whether first or second order, from a liquid to a crystalline state is forbidden. As a result, between these phases there must be other (micro-emulsion) phases which can be viewed as a meso-scale mixture of the liquid and crystalline phases. We investigate the transport properties of these new electronic phases and present arguments that they are responsible for the various transport anomalies that have been seen in experiments on the strongly correlated 2DEG in high mobility semiconductor devices with low electron densities.     

The matrix equation AX-YB=C and related problems

The main result of the paper is a theorem, using which a new proof of Roth’s theorem is obtained, a new solvability criterion for the matrix equation AX-YB = C is proved, a formula for a particular solution of the latter is derived, and the least of the orders of square nonsingular matrices containing a given rectangular matrix as a submatrix is determined. Bibliography: 5 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 323, 2005, pp. 15–23.     

Scattering of surface plasmon polaritons by a nanoparticle with the inclusion of the magnetic dipole contribution

Using the method of the tensor Green’s function of the wave equation, the differential and total cross sections for the scattering of surface optical electromagnetic waves (surface plasmon polaritons) by a spherical nanoparticle into surface plasmon polaritons and light have been obtained with the inclusion of the magnetic dipole contribution. Using the example of noble metal systems, it has been shown that the magnetic dipole contribution may significantly affect the angular dependence of the differential cross sections and increase their anisotropy as the plasmon wavelength increases.     

Dielectric and optical properties of polymer-liquid crystal composite

Dielectric properties of polymer-liquid crystal mixture, having constituent polymer, poly-butyl methacrylate (PBMA) and liquid crystal, cholesteryl nonanoate, are reported as a function of frequency and temperature. The measurement has been done in a temperature range of 300-375 K and frequency range of 100 Hz-10 MHz. The dielectric permittivity and dielectric loss shows significant changes with the addition of polymer molecules in liquid crystal. The significant feature of composite formation is that the pure liquid crystal and polymer do not show dielectric relaxation in the frequency range covered, while the composite shows relaxation peak at a particular frequency. The optical transmittance of pure liquid crystal and composite has also been measured and compared.     

Onset of crater formation during short pulse laser ablation

We report morphologic changes of metallic surfaces at the onset of ablation, starting from gentle ablation to the emergence of ablation craters. The evolution of both observed melting zones and of ablation craters therein are investigated in dependence of the ablation laser fluence for nanosecond ultraviolet laser pulses. Further, consequences of crater formation for cluster synthesis within the released atomic vapor are pointed out. PACS 52.38.Mf; 79.20.Ds; 65.40.De