Local adsorption sites and bondlength changes in Ni(1 0 0)/H/CO and Ni(1 0 0)/CO

The local adsorption geometry of CO adsorbed in different states on Ni(1 0 0) and on Ni(1 0 0) precovered with atomic hydrogen has been determined by C 1s (and O 1s) scanned-energy mode photoelectron diffraction, using the photoelectron binding energy changes to characterise the different states. The results confirm previous spectroscopic assignments of local atop and bridge sites both with and without coadsorbed hydrogen. The measured Ni–C bondlengths for the Ni(1 0 0)/CO states show an increase of 0.16 ± 0.04 Å in going from atop to bridge sites, while comparison with similar results for Ni(1 1 1)/CO for threefold coordinated adsorption sites show a further lengthening of the bond by 0.05 ± 0.04 Å. These changes in the Ni–CO chemisorption bondlength with bond order (for approximately constant adsorption energy) are consistent with the standard Pauling rules. However, comparison of CO adsorbed in the atop geometry with and without coadsorbed hydrogen shows that the coadsorption increases the Ni–C bondlength by only 0.06 ± 0.04 Å, despite the decrease in adsorption energy of a factor of 2 or more. This result is also reproduced by density functional theory slab calculations. The results of both the experiments and the density functional theory calculations show that CO adsorption onto the Ni(1 0 0)/H surface is accompanied by significant structural modification; the low desorption energy may then be attributed to the energy cost of this restructuring rather than weak local bonding.     

Gaussian Chaos Laws on Banach Function Spaces

We give a characterization of Gaussian chaos laws on Banach function spaces which do not contain ℓ _∞ ⁿ 's uniformly. The result is applied to describe the convergence in law of U-processes with sample paths in certain Banach function spaces. __________ Published in Lietuvos Matematikos Rinkinys, Vol. 45, No. 4, pp. 553–566, October–December, 2005.     

Mechanical Properties of Blends of Low-Density Polyethylene with Chlorinated Polyethylene

The results of experimental investigation into the mechanical properties of blends of low-density polyethylene (LDPE) with chlorinated polyethylene (CPE) in tension are presented. The specimens of pure LDPE, CPE, and nine types of LDPE/CPE blends, with different content of components at 10 wt.% intervals, were examined. Data on the influence of blend composition on the tensile stress-strain diagram, elastic modulus, yield stress, breaking stress, and ultimate elongation are obtained. The results of investigations of creep are also reported. It is found that the creep compliance (the total current compliance minus the elastic compliance) obeys the power law of creep.__________Translated from Mekhanika Kompozitnykh Materialov, Vol. 41, No. 3, pp. 391–404, May–June, 2005.     

Multi-Item Scheduling by Benders' Decomposition

Scheduling the production of several items requires the determination of production quantities in different periods in the presence of resource constraints. Several approximate and heuristic algorithms have been proposed to solve this problem. However, no method for finding an optimal solution has as yet been developed. It is shown that the problem may be solved advantageously using Benders' decomposition. The subproblem in Benders' decomposition is shown to be a transportation problem, and some strategies for solving the master problem are indicated. The paper concludes with a sample problem demonstrating the application of the method.     

Non-Trivial t-Intersection in the Function Lattice

The function lattice, or generalized Boolean algebra, is the set of ℓ-tuples with the ith coordinate an integer between 0 and a bound n_i. Two ℓ-tuples t-intersect if they have at least t common nonzero coordinates. We prove a Hilton–Milner type theorem for systems of t-intersecting ℓ-tuples.Received September 29, 2004     

Karhunen–Loeve representations of turbulent channel flows using the method of snapshots

For three‐dimensional flows with one inhomogeneous spatial coordinate and two periodic directions, the Karhunen–Loeve procedure is typically formulated as a spatial eigenvalue problem. This is normally referred to as the direct method (DM). Here we derive an equivalent formulation in which the eigenvalue problem is formulated in the temporal coordinate. It is shown that this so‐called method of snapshots (MOS) has some numerical advantages when compared to the DM. In particular, the MOS can be formulated purely as a matrix composed of scalars, thus avoiding the need to construct a matrix of matrices as in the DM. In addition, the MOS avoids the need for so‐called weight functions, which emerge in the DM as a result of the non‐uniform grid typically employed in the inhomogeneous direction. The avoidance of such weight functions, which may exhibit singular behaviour, guarantees satisfaction of the boundary conditions. The MOS is applied to data sets recently obtained from the direct simulation of turbulence in a channel in which viscoelasticity is imparted to the fluid using a Giesekus model. The analysis reveals a steep drop in the dimensionality of the turbulence as viscoelasticity is increased. This is consistent with the results that have been obtained with other viscoelastic models, thus revealing an essential generic feature of polymer‐induced drag reduced turbulent flows. Published in 2006 by John Wiley & Sons, Ltd.     

The Convergence and Stability of Splitting Finite-Difference Schemes for Nonlinear Evolutionary Equations

We consider a splitting finite-difference scheme for an initial-boundary value problem for a two-dimensional nonlinear evolutionary equation. The problem is split into nonlinear and linear parts. The linear part is also split into locally one-dimensional equations. We prove the convergence and stability of the scheme in L ₂ and C norms. Printed in Lietuvos Matematikos Rinkinys, Vol. 45, No. 3, pp. 413–434, July–September, 2005.     

Secondary ion emission from binary Fe-Cr,Fe-Ni,Cr-Ni and ternary Fe-Cr-Ni alloys: Chemical and physical matrix effects

Secondary ion emission from Fe-Cr, Fe-Ni, Cr-Ni binary alloys and Fe-Cr-Ni ternary alloys (concentration range 10–90% of the alloying element) bombarded with 3 keV Xe⁺ ions has been investigated as a function of concentration of the studied element in the multicomponent system. The linear increase of the secondary ion intensity with concentration of the element in the sample was found only for a low-concentration region. There are pronounced nonlinearities in the medium and high-concentration regions. A possible explanation for such nonlinearities based on chemical and physical matrix effects is proposed.     

In-plane loading of a cracked elastic solid by a disc inclusion with a Mindlin-type constraint

The paper examines the problem related to the axisymmetric interaction between an external circular crack and a centrally placed penny-shaped rigid inclusion located in the plane of the crack. The interface between the inclusion and the elastic medium exhibits a Mindlin-type imperfect bi-lateral contact. Analytical results presented in the paper illustrate the manner in which the lateral translational stiffness of the inclusion and the stress intensity factor at the boundary of the external circular crack are influenced by the inclusion/crack radii ratio.