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821.
M. Faucher D. Garcia E. Antic-Fidancev M. Lemaitre-Blaise 《Journal of Physics and Chemistry of Solids》1989,50(12)
Some structural and spectroscopic features of rare earth orthoaluminates are examined.The trigonal→ orthorhombic transition is studied in a series of NdxSm1−xAlO3 compounds. The evolution of the crystal structure is followed by X-ray analysis and optical absorption. The free ion and crystal field parameters of Nd3+ (4f3 configuration) are determined in LuAlO3:Nd3+.The anomaly of the calculated splitting of the
levels is slight, but well characterized in NdAlO3. The spin correlated crystal field and orbitally correlated crystal field models are tested as well as an empirical correction which was proposed earlier. 相似文献
822.
The influence of an electrical field on the charge transfer in crystals with orbital degeneration is investigated. An expression is obtained for the current density in crystals with narrow d-conduction bands in transition metal compounds. As the electrical field intensity increases, a current density maximum is observed with a subsequent section of negative differential conductivity. The results of the investigation agree qualitatively with experimental data.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 14–18, February, 1989. 相似文献
823.
V. A. Popova I. V. Podgornaya V. G. Lundina L. I. Kurnikova A. I. Tarasov 《Russian Chemical Bulletin》1987,36(11):2361-2364
Conclusions Complex compounds of bisacyl derivatives of diaminodibenzo-18-crown-6 ether are active catalysts of the two stages of the synthesis of poly(ethylene terephthalate).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2544–2547, November. 1987. 相似文献
824.
J. Giroire T. Ha‐Duong V. Moumas 《Mathematical Methods in the Applied Sciences》2005,28(13):1527-1552
This article deals with a boundary value problem for Laplace equation with a non‐linear and non‐local boundary condition. This problem comes from petroleum engineering and is used to obtain an estimation of well productivity. The non‐linear and non‐local boundary condition is written on the well boundary. On the outer reservoir boundaries, we have both Dirichlet and Neumann conditions. In this paper, we prove the existence and uniqueness of a solution to this problem. The existence is proved by Schauder theorem and the uniqueness is obtained under more restricted conditions, when the involved operator is a contraction. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
825.
826.
A brief review of the potential functions used in the molecular dynamics modeling of liquid benzene is presented. The structural characteristics of liquid benzene obtained from the correlation distribution functions are discussed. It is demonstrated that, within the framework of this approach, the predicted structure of liquid benzene is virtually independent of the form of the potential used. 相似文献
827.
Settling of a large solid particle in bioconvection flow caused by gyrotactic microorganisms is investigated. The particle is released from the top of the bioconvection chamber; its settling pattern depends on whether it is released in the centre of the bioconvection plume or at its periphery. The Chimera method is utilized; a subgrid is generated around a moving particle. The method suggested by Liu and Wang (Comput. Fluid 2004; 33 :223–255) is further developed to account for the presence of a moving boundary in the streamfunction‐vorticity formulation using the finite‐difference method. A number of cases for different release positions of the particle are computed. It is demonstrated that bioconvection can either accelerate or decelerate settling of the particle depending on the initial position of the particle relative to the plume centre. It is also shown that the particle impacts bioconvection plume by changing its shape and location in the chamber. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
828.
D. B. Kayumova Yu. P. Syrnikov N. V. Penkina M. N. Rodnikova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(10):1634-1635
The structural relaxation time for series of various liquids (alkanes, aliphatic alcohols, and diols) are calculated from published data on the shear viscosity and the heat of evaporation per unit volume. Liquids having a 3D H-bond network (diols) are characterized by relaxation times one to two orders of magnitudes longer than those typical of liquids without such a network (alkanes and aliphatic alcohols). 相似文献
829.
830.
Flávio A. Pavan Yoshitaka Gushikem Celso C. Moro Tania M. Costa Edilson V. Benvenutti 《Colloid and polymer science》2003,281(2):173-177
Anilinepropylsilica xerogel was obtained by using an appropriate organosilane and tetraethyl orthosilicate as precursor reagents. The gelation was carried out using HF and NaF as catalysts. The presence of Na+ (when NaF was used) resulted in a decrease in the final organic content of the materials. This effect was interpreted as an inhibition of the organosilane polycondensation possibly due to the Na+ interaction with the SiO- groups of the hydrolyzed organosilane. The presence of Na+ also results in morphological changes in the xerogels. 相似文献