全文获取类型
收费全文 | 602篇 |
免费 | 49篇 |
国内免费 | 1篇 |
专业分类
化学 | 501篇 |
晶体学 | 3篇 |
力学 | 13篇 |
数学 | 55篇 |
物理学 | 80篇 |
出版年
2023年 | 12篇 |
2022年 | 8篇 |
2021年 | 14篇 |
2020年 | 35篇 |
2019年 | 29篇 |
2018年 | 15篇 |
2017年 | 10篇 |
2016年 | 27篇 |
2015年 | 28篇 |
2014年 | 29篇 |
2013年 | 31篇 |
2012年 | 59篇 |
2011年 | 65篇 |
2010年 | 29篇 |
2009年 | 21篇 |
2008年 | 34篇 |
2007年 | 29篇 |
2006年 | 33篇 |
2005年 | 36篇 |
2004年 | 26篇 |
2003年 | 17篇 |
2002年 | 12篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 5篇 |
1998年 | 6篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有652条查询结果,搜索用时 15 毫秒
101.
102.
Georgios Velkos Denis S. Krylov Kyle Kirkpatrick Lukas Spree Vasilii Dubrovin Bernd Büchner Stanislav M. Avdoshenko Valeriy Bezmelnitsyn Sean Davis Paul Faust James Duchamp Harry C. Dorn Alexey A. Popov 《Angewandte Chemie (International ed. in English)》2019,58(18):5891-5896
The azafullerene Tb2@C79N is found to be a single‐molecule magnet with a high 100‐s blocking temperature of magnetization of 24 K and large coercivity. Tb magnetic moments with an easy‐axis single‐ion magnetic anisotropy are strongly coupled by the unpaired spin of the single‐electron Tb?Tb bond. Relaxation of magnetization in Tb2@C79N below 15 K proceeds via quantum tunneling of magnetization with the characteristic time τQTM=16 462±1230 s. At higher temperature, relaxation follows the Orbach mechanism with a barrier of 757±4 K, corresponding to the excited states, in which one of the Tb spins is flipped. 相似文献
103.
104.
Development of the Vinylogous Pictet–Spengler Cyclization and Total Synthesis of (±)‐Lundurine A
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Aaron Nash Xiangbing Qi Pradip Maity Kyle Owens Prof. Dr. Uttam K. Tambar 《Angewandte Chemie (International ed. in English)》2018,57(23):6888-6891
A novel vinylogous Pictet–Spengler cyclization has been developed for the generation of indole‐annulated medium‐sized rings. The method enables the synthesis of tetrahydroazocinoindoles with a fully substituted carbon center, a prevalent structural motif in many biologically active alkaloids. The strategy has been applied to the total synthesis of (±)‐lundurine A. 相似文献
105.
Generation of Turbulent Inflow Data for Spatially-Developing Boundary Layer Simulations 总被引:4,自引:0,他引:4
A method for generating three-dimensional, time-dependent turbulent inflow data for simulations of complex spatially developing boundary layers is described. The approach is to extract instantaneous planes of velocity data from an auxiliary simulation of a zero pressure gradient boundary layer. The auxiliary simulation is also spatially developing, but generates its own inflow conditions through a sequence of operations where the velocity field at a downstream station is rescaled and re-introduced at the inlet. This procedure is essentially a variant of the Spalart method, optimized so that an existing inflow–outflow code can be converted to an inflow-generation device through the addition of one simple subroutine. The proposed method is shown to produce a realistic turbulent boundary layer which yields statistics that are in good agreement with both experimental data and results from direct simulations. The method is used to provide inflow conditions for a large eddy simulation (LES) of a spatially evolving boundary layer spanning a momentum thickness Reynolds number interval of 1530–2150. The results from the LES calculation are compared with those from other simulations that make use of more approximate inflow conditions. When compared with the approximate inflow generation techniques, the proposed method is shown to be highly accurate, with little or no adjustment of the solution near the inlet boundary. In contrast, the other methods surveyed produce a transient near the inlet that persists several boundary layer thicknesses downstream. Lack of a transient when using the proposed method is significant since the adverse effects of inflow errors are typically minimized through a costly upstream elongation of the mesh. Extension of the method for non-zero pressure gradients is also discussed. 相似文献
106.
Paul Blowers Kyle Franklin Tetrault Yirla Trujillo-Morehead 《Theoretical chemistry accounts》2008,119(4):369-381
Global warming potentials are predicted using computational chemistry and thermodynamics approaches for four hydrofluoroethers
where no data have previously been available. We also compare results with the same methodology for six other species. We
combine predictions of radiative forcing values from density functional theory computations at the B3LYP/6-31g* level of theory
with previous experimentally determined or newly estimated hydroxyl radical-hydrogen abstraction rate constants to obtain
these global warming potentials. We find that many of the HFEs studied have lower global warming potentials than the hydrofluorocarbons
and chlorofluorocarbons they may soon replace, although other environmental and technical issues may need to be addressed
first.
Electronic Supplementary Material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
107.
108.
Crabtree KN Hostetler KJ Munsch TE Neuhaus P Lahti PM Sander W Poole JS 《The Journal of organic chemistry》2008,73(9):3441-3451
The photochemistry of azidopyridine 1-oxides was studied using an array of glass and matrix isolation techniques. As with room temperature, the photochemistry of 4-azidopyridine 1-oxide is dominated by triplet nitrene chemistry. However, in the case of the 3-azide, matrix photolysis indicates the formation of diazabicyclo[4.1.0]hepta-2,4,6-triene N-oxide and diazacycloheptatetraene N-oxide intermediates as well as triplet nitrene. 相似文献
109.
Ramona Luna Daniel Heineck Juan Pablo Hinestrosa Irina Dobrovolskaia Sean Hamilton Anna Malakian Kyle T. Gustafson Katherine T. Huynh Sejung Kim Jason Ware Ella Stimson Christian Ross Carolyn E. Schutt Stuart D. Ibsen 《Electrophoresis》2023,44(15-16):NA-NA
Dielectrophoresis (DEP) is a successful method to recover nanoparticles from different types of fluid. The DEP force acting on these particles is created by an electrode microarray that produces a nonuniform electric field. To apply DEP to a highly conducting biological fluid, a protective hydrogel coating over the metal electrodes is required to create a barrier between the electrode and the fluid. This protects the electrodes, reduces the electrolysis of water, and allows the electric field to penetrate into the fluid sample. We observed that the protective hydrogel layer can separate from the electrode and form a closed domed structure and that collection of 100 nm polystyrene beads increased when this occurred. To better understand this collection increase, we used COMSOL Multiphysics software to model the electric field in the presence of the dome filled with different materials ranging from low-conducting gas to high conducting phosphate-buffered saline fluids. The results suggest that as the electrical conductivity of the material inside the dome is reduced, the whole dome acts as an insulator which increases electric field intensity at the electrode edge. This increased intensity widens the high-intensity electric field factor zone resulting in increased collection. This informs how dome formation results in increased particle collection and provides insight into how the electric field can be intensified to the increase collection of particles. These results have important applications for increasing the recovery of biologically-derived nanoparticles from undiluted physiological fluids that have high conductance, including the collection of cancer-derived extracellular vesicles from plasma for liquid biopsy applications. 相似文献
110.
In this paper we report on the kinetics of hydrogen abstraction for the OH + alkene reaction class, using the reaction class transition state theory (RC-TST) combined with the linear energy relationship (LER) and the barrier height grouping (BHG) approaches. Parameters for the RC-TST were derived from theoretical calculations using a set of 15 reactions representing the hydrogen abstractions from the terminal and nonterminal carbon sites of the double bond of alkene compounds. Both the RC-TST/LER, where only reaction energy is needed at either density functional theory BH&HLYP or semiempirical AM1 levels, and RC-TST/BHG, where no additional information is required, are found to be promising methods for predicting rate constants for a large number of reactions in this reaction class. Detailed error analyses show that, when compared to explicit theoretical calculations, the averaged systematic errors in the calculated rate constants using both the RC-TST/LER and RC-TST/BHG methods are less than 25% in the temperature range 300-3000 K. The estimated rate constants using these approaches are in good agreement with available data in the literature. 相似文献