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131.
Yuxiang Zhao Hui Liang Yuan Zuzana Zají
kov Cyril Prknyi 《Journal of heterocyclic chemistry》2006,43(6):1729-1731
132.
Yuldashev P Ollivier S Averiyanov M Sapozhnikov O Khokhlova V Blanc-Benon P 《The Journal of the Acoustical Society of America》2010,128(6):3321-3333
The propagation of nonlinear spherically diverging N-waves in homogeneous air is studied experimentally and theoretically. A spark source is used to generate high amplitude (1.4 kPa) short duration (40 μs) N-waves; acoustic measurements are performed using microphones (3 mm diameter, 150 kHz bandwidth). Numerical modeling with the generalized Burgers equation is used to reveal the relative effects of acoustic nonlinearity, thermoviscous absorption, and oxygen and nitrogen relaxation on the wave propagation. The results of modeling are in a good agreement with the measurements in respect to the wave amplitude and duration. However, the measured rise time of the front shock is ten times longer than the calculated one, which is attributed to the limited bandwidth of the microphone. To better resolve the shock thickness, a focused shadowgraphy technique is used. The recorded optical shadowgrams are compared with shadow patterns predicted by geometrical optics and scalar diffraction model of light propagation. It is shown that the geometrical optics approximation results in overestimation of the shock rise time, while the diffraction model allows to correctly resolve the shock width. A combination of microphone measurements and focused optical shadowgraphy is therefore a reliable way of studying evolution of spark-generated shock waves in air. 相似文献
133.
Cyril Mauger Lo?c Méès Marc Michard Alexandre Azouzi Stéphane Valette 《Experiments in fluids》2012,53(6):1895-1913
Cavitation plays an important role in fuel atomization mechanisms, but the physics of cavitation and its impact on spray formation and injector efficiency are not well documented yet. Experimental investigations are required to support the development and the validation of numerical models and the design of tomorrow??s injectors, in the context of pollutant and fuel consumption reduction. The complexity of modern injectors and the extreme conditions of injection do not facilitate experimental investigations. In this paper, experiments are conducted in a simplified geometry. The model nozzle consists of a transparent 2D micro-channel supplied with a test oil (ISO 4113). Three different optical techniques are proposed to investigate the channel flow, with the pressure drop between upstream and downstream chambers as a parameter. A shadowgraph-like imaging technique allows the observation of cavitation inception and vapor cavities development throughout the channel. The technique also reveals the presence of density gradients (pressure or temperature) in the channel flow. However, this additional information is balanced by difficulties in image interpretation, which are discussed in the paper. In addition, a combination of Schlieren technique and interferometric imaging is used to measure the density fields inside the channel. The three techniques results are carefully analyzed and confronted. These results reveal a wealth of information on the flow, with pressure waves generated by bubble collapses, turbulence in the wake of vapor cavities and bubble survival in flow regions of high pressure. Our results also show that cavitation inception is located in the shear layers between the recirculation zones and the main flow, relatively far from the inlet corner, where the pressure is minimum in average. To explain this behavior, we propose a scenario of cavitation inception based on the occurrence and the growing of instabilities in the shear layers. 相似文献
134.
Irina Piazza Antonio Cupane Emmanuel L. Barbier Claire Rome Nora Collomb Jacques Ollivier Miguel A. Gonzalez Francesca Natali 《Frontiers of Physics》2018,13(1):138301
With the aim of studying the effect of water dynamics on the properties of biological systems, in this paper, we present a quasi-elastic neutron scattering study on three different types of living cells, differing both in their morphological and tumor properties. The measured scattering signal, which essentially originates from hydrogen atoms present in the investigated systems, has been analyzed using a global fitting strategy using an optimized theoretical model that considers various classes of hydrogen atoms and allows disentangling diffusive and rotational motions. The approach has been carefully validated by checking the reliability of the calculation of parameters and their 99% confidence intervals. We demonstrate that quasi-elastic neutron scattering is a suitable experimental technique to characterize the dynamics of intracellular water in the angstrom/picosecond space/time scale and to investigate the effect of water dynamics on cellular biodiversity. 相似文献
135.
Tone noise radiated through the inlet of a turbofan is mainly due to rotor-stator interactions at subsonic regimes (approach flight), and to the shock waves attached to each blade at supersonic helical tip speeds (takeoff). The axial compressor of a helicopter turboshaft engine is transonic as well and can be studied like turbofans at takeoff. The objective of the paper is to predict the sound power at the inlet radiating into the free field, with a focus on transonic conditions because sound levels are much higher. Direct numerical computation of tone acoustic power is based on a RANS (Reynolds averaged Navier–Stokes) solver followed by an integration of acoustic intensity over specified inlet cross-sections, derived from Cantrell and Hart equations (valid in irrotational flows). In transonic regimes, sound power decreases along the intake because of nonlinear propagation, which must be discriminated from numerical dissipation. This is one of the reasons why an analytical approach is also suggested. It is based on three steps: (i) appraisal of the initial pressure jump of the shock waves; (ii) 2D nonlinear propagation model of Morfey and Fisher; (iii) calculation of the sound power of the 3D ducted acoustic field. In this model, all the blades are assumed to be identical such that only the blade passing frequency and its harmonics are predicted (like in the present numerical simulations). However, transfer from blade passing frequency to multiple pure tones can be evaluated in a fourth step through a statistical analysis of irregularities between blades. Interest of the analytical method is to provide a good estimate of nonlinear acoustic propagation in the upstream duct while being easy and fast to compute. The various methods are applied to two turbofan models, respectively in approach (subsonic) and takeoff (transonic) conditions, and to a Turbomeca turboshaft engine (transonic case). The analytical method in transonic appears to be quite reliable by comparison with the numerical solution and with available experimental data. 相似文献
136.
Jessica Dubois Sofya Kulikova Lucie Hertz-Pannier Jean-François Mangin Ghislaine Dehaene-Lambertz Cyril Poupon 《Magnetic resonance imaging》2014
Objective
Diffusion imaging techniques such as DTI and HARDI are difficult to implement in infants because of their sensitivity to subject motion. A short acquisition time is generally preferred, at the expense of spatial resolution and signal-to-noise ratio. Before estimating the local diffusion model, most pre-processing techniques only register diffusion-weighted volumes, without correcting for intra-slice artifacts due to motion or technical problems. Here, we propose a fully automated strategy, which takes advantage of a high orientation number and is based on spherical-harmonics decomposition of the diffusion signal.Material and methods
The correction strategy is based on two successive steps: 1) automated detection and resampling of corrupted slices; 2) correction for eddy current distortions and realignment of misregistered volumes. It was tested on DTI data from adults and non-sedated healthy infants.Results
The methodology was validated through simulated motions applied to an uncorrupted dataset and through comparisons with an unmoved reference. Second, we showed that the correction applied to an infant group enabled to improve DTI maps and to increase the reliability of DTI quantification in the immature cortico-spinal tract.Conclusion
This automated strategy performed reliably on DTI datasets and can be applied to spherical single- and multiple-shell diffusion imaging. 相似文献137.
This study describes the experimental and numerical dynamic analysis of a kinematically excited spherical pendulum. The stability of the response in the vertical plane was analyzed in the theoretically predicted auto-parametric resonance domain. Three different types of the resonance domain were investigated the properties of which depended significantly on the dynamic parameters of the pendulum and the excitation amplitude. A mathematical model was used to represent the nonlinear characteristics of the pendulum, which includes the asymmetrical damping. A special frame was developed to carry out the experiments, which contained the pendulum supported by the Cardan joint and two magnetic units attached to the supporting axes of rotation, and this was able to reproduce linear viscous damping for both of the principal response components. The stability analysis of the system was compared with the numerical solution of the governing equations and experimental observation. The most significant practical outcomes for designers are also summarized. 相似文献
138.
139.
T Courant VG Roullin C Cadiou M Callewaert MC Andry C Portefaix C Hoeffel MC de Goltstein M Port S Laurent LV Elst R Muller M Molinari F Chuburu 《Angewandte Chemie (International ed. in English)》2012,51(36):9119-9122
Do not tumble dry: Gadolinium-DOTA encapsulated into polysaccharide nanoparticles (GdDOTA?NPs) exhibited high relaxivity (r(1) =101.7?s(-1) mM(-1) per Gd(3+) ion at 37?°C and 20?MHz). This high relaxation rate is due to efficient Gd loading, reduced tumbling of the Gd complex, and the hydrogel nature of the nanoparticles. The efficacy of the nanoparticles as a T(1) /T(2) dual-mode contrast agent was studied in C6 cells. 相似文献
140.
Kenfack CA Klymchenko AS Duportail G Burger A Mély Y 《Physical chemistry chemical physics : PCCP》2012,14(25):8910-8918
The electronic transitions occurring in 4-(N,N-dimethylamino)-3-hydroxyflavone (DMAF) and 2-furanyl-3-hydroxychromone (FHC) were investigated using the TDDFT method in aprotic and protic solvents. The solvent effect was incorporated into the calculations via the PCM formalism. The H-bonding between solute and protic solvent was taken into account by considering a molecular complex between these molecules. To examine the effect of the H-bond on the ESIPT reaction, the absorption and emission wavelengths as well as the energies of the different states that intervene during these electronic transitions were calculated in acetonitrile, ethanol and methanol. The calculated positions of the absorption and emission wavelengths in various solvents were in excellent agreement with the experimental spectra, validating our approach. We found that in DMAF, the hydrogen bonding with protic solvents makes the ESIPT reaction energetically unfavourable, which explains the absence of the ESIPT tautomer emission in protic solvents. In contrast, the excited tautomer state of FHC remains energetically favourable in both aprotic and protic solvents. Comparing our calculations with the previously reported time-resolved fluorescence data, the ESIPT reaction of DMAF in aprotic solvents is reversible because the emitting states are energetically close, whereas in FHC, ESIPT is irreversible because the tautomer state is below the corresponding normal state. Therefore, the ESIPT reaction in DMAF is controlled by the relative energies of the excited states (thermodynamic control), while in FHC the ESIPT is controlled probably by the energetic barrier (kinetic control). 相似文献