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251.
Yonggang Shangguan Li Zhao Liyang Tao Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2007,45(13):1704-1712
The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007 相似文献
252.
1,6-烯炔底物在过渡金属催化剂作用下的化学行为得到了广泛的研究,重点是关于过渡金属催化的1,6-烯炔环异构化反应.从反应机理角度入手,把1,6-烯炔环异构化反应按启动方式总结为三类,并对这三种方式启动的1,6-烯炔环异构化反应进行了详细地总结和阐述. 相似文献
253.
研究了非相干辐照对LiNbO3:Fe晶体中从自散焦到自聚焦的动态转换过程的影响和控制作用.无论是从前向还是从背向加入非相干辐照,都能加快自散焦、自聚焦过程以及从自散焦到自聚焦的转换过程,增大折射率的变化值.当非相干辐照以一定的时间间隔重复辐照在晶体上时,透射功率能迅速地上升和下降,具有明显的开关效应.这种在非相干辐照控制下折射率的迅速改变有望应用于全光学开关器件.
关键词:
非相干辐照
光伏效应
自散焦
自聚焦 相似文献
254.
255.
Hong-jun Liu Wei Zhao Guo-fu Chen Yi-shan Wang Lian-jun Yu Chi Ruan Xue-feng Li 《Optics & Laser Technology》2004,36(4):3482-314
Experimental investigations of a type-I noncollinear phase-matched optical parametric amplification based on lithium triborate, which was pumped by a 5-ns second-harmonic pulses from a Q-switched Nd:YAG, seeded by a cw Ti:sapphire laser at 800 nm, was presented. The experiments generated 2-ns signal output pulses at 800 nm, the maximum signal output pulse energy reached 19 μJ, the corresponding parametric gain was 44 dB. Furthermore, the experiments demonstrate that the 65 nm-FWHM parametric fluorescence gain spectrum could also be observed. A quantitative account of the ultrabroadband parametric fluorescence gain spectrum was given with our theory. The experimental measurements are in agreement with theoretical calculations. 相似文献
256.
Juguan Gu Juguan Gu Daomu Zhao Zhangrong Mei Zhangrong Mei Haidan Mao Haibin Xu 《Optik》2004,115(11-12):529-532
By means of Collins diffraction integral formula in the paraxial approximation and based on the fact that a hard aperture function can be expanded into a finite sum of complex Gaussian functions, an approximate analytical expression for linearly polarized Bessel-Gaussian beams passing through a paraxial ABCD optical system with an annular aperture has been derived. The results provide more convenient for studying their propagation and transformation than the usual way by using diffraction integral directly. By using the analytical expression and the diffraction integral formula some numerical simulations are done to illustrate for the propagation characteristics of a linearly polarized Bessel-Gaussian beam through an optical system with an annular aperture. 相似文献
257.
在变缓冲层高迁移率晶体管(MM_HEMT)器件中,二维电子气的输运性质对器件性能起着决定作用.通过低温下二维电子气横向电阻的量子振荡现象,结合变温度的Hall测量,系统研究了不同In组分沟道MM_HEMT器件中子带电子迁移率和浓度随温度的变化关系.结果表明,沟道中In组分为0.65的样品,材料电学性能最好,In组分高于0.65的样品,严重的晶格失配将产生位错,引起迁移率下降,大大影响材料和器件的性能.
关键词:
变缓冲层高迁移率晶体管
Shubnikov_de Hass 振荡 相似文献
258.
Bao Tong Cui Maoan Han Huizhong Yang 《Journal of Computational and Applied Mathematics》2005,180(2):365-375
This paper deals with the oscillation problems of delay hyperbolic systems with impulses. Some sufficient conditions for oscillations of impulsive delay hyperbolic systems with Robin boundary conditions are obtained and the criteria of oscillation of the systems are established. 相似文献
259.
LI Na ZHAO Degang & YANG Hui State Key Laboratory on Integrated Optoelectronics Institute of Semiconductors Chinese Academy of Sciences Beijing China 《中国科学G辑(英文版)》2004,47(6):694-701
Because of their large band-gap, large high-field electron velocity, large breakdownfield, and large thermal conductivity, GaN and its heterojunction with AlGaN and InGaNhave foreseeable potential in the applications of high-power/temperature electronics, andoptoelectronic devices operative in UV and visible wavelength. Polarization inducedelectric field can reach the magnitude of ~MV/cm[1,2]. For AlGaN/GaN based FETs theconcentration of sheet carrier induced by polarization in the cha… 相似文献
260.