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101.
102.
Sandra Cruz Sylvain Bernès Pankaj Sharma Rosa Vazquez Guadalupe Hernández Roberto Portillo René Gutiérrez 《应用有机金属化学》2010,24(1):8-11
Optically pure α‐diimines quantitatively obtained in solvent‐free conditions starting from 2,3‐butanedione and (S)‐(?)‐1‐phenylethylamine and (S)‐(?)‐1‐(4‐methylphenyl)ethylamine, respectively, yielded the new chiral mono‐Pd complexes 2a–b, which have been partly characterized by IR, 1H‐ and 13C‐NMR spectroscopies along with MS‐FAB+ spectrometry. The crystal and molecular structure for palladacycle 2a has been fully confirmed by single‐crystal X‐ray studies. Studies in vitro of 2a–b have displayed growth inhibition against different classes of cancer: leukemia (K‐562 CML), colon cancer (HCT‐15), breast cancer (MCF‐7), central nervous system (U‐251 Glio) and prostate cancer (PC‐3) cell lines. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
103.
High‐density polyethylene/expanded graphite nanocomposites produced by polymerization‐filling technique using an industrial heterogeneous catalyst
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Kátia Z. C da Cruz Adriana C. A. Casagrande Osvaldo L. Casagrande Jr 《Journal of polymer science. Part A, Polymer chemistry》2017,55(7):1260-1267
High‐density polyethylene nanocomposites with different expanded graphite (EG) contents (0.34–1.80 wt %) were prepared by polymerization‐filling technique using an industrial heterogeneous catalyst ( cat K ), and characterized using a range techniques: melting flow index (MFI), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and transmission electron microscopy (TEM). The MFI data showed that EG acts as a plasticizer decreasing melt viscosity in comparison to neat HDPE produced exclusively by cat K . DSC results showed that EG nucleated the HDPE crystallization as established by the increased crystallization temperature, and the degree of crystallinity. HDPE/EG nanocomposites displayed a significant improvement in the flexural (increased from 1458 to 1831 MPa), and storage modulus (increased from 122 to 1627 MPa) at only 1.80 wt % EG content. TEM images confirmed a homogeneous distribution of EG into the polymer matrix with the presence of dispersed, intercalated and aggregated EG nanofillers. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 55, 1260–1267 相似文献
104.
105.
R. Salazar Moreno F. Szidarovszky A. Rojano Aguilar I. López Cruz 《Journal of Optimization Theory and Applications》2010,144(3):557-573
A multiobjective optimization model is developed for the Mexican Valley to find optimal water distribution scenarios for three
water users: agriculture, industry and domestic. Surface, ground, treated and imported water supplies are considered. The
model with three objectives and 15 constraints was solved by the distance based method with distance l
1.
Three scenarios and two priorities were analyzed for this problem. In Scenario 1, actual aquifer overexploitation and treated
water usage were allowed. Scenario 2 considered the reduction of water extraction from the aquifer to one billion m3 (59%), and increased usage of treated water in agriculture by 50%. In Scenario 3, we assume aquifer sustainability and increasing
surface water usage by 857 mill m3/year. The last scenario is the best because, in the worst case, the farmers can cover one season and also some crops in the
second season, and the domestic users can get more water than their minimum demand. In addition, aquifer sustainability is
implemented, which can reduce aquifer overexploitation. The waste water disposal problem, which is critical in this area,
also can be reduced. 相似文献
106.
Javier Ramos Víctor L. Cruz Javier Martínez‐Salazar Mikael Brasse Pilar Palma Juan Campora 《Journal of polymer science. Part A, Polymer chemistry》2010,48(5):1160-1165
The present computational study was designed to study the polymerization of ethylene catalyzed by a new Ni‐based PymNox organometallic compound. Recently, we have synthesized and tested the behavior of this type of catalyst in olefin polymerization. It has been experimentally observed that the unsubstituted catalyst Ni2 (aldimino PymNox catalyst ) is less active than the methyl substituted Ni1 (acetaldimino PymNox catalyst ) analogue. The reactivity of both catalysts was examined using density functional theory (DFT) models. Our results indicate that the methyl substituted Ni1 introduces some additional steric hindrance that probably renders a more suitable catalyst conformation for the monomer incorporation. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1160–1165, 2010 相似文献
107.
E. Cruz Z A. Negr n A. Ramos A S. Ramos B J. Hern ndez A F Jaque H. Murrieta S 《Radiation Physics and Chemistry》2001,61(3-6):443-444
The amount of the first stage coloration in KCl1−xBrx doped with Pb2+ has been investigated as a function of the dose rate and impurity concentration. For a dose rate of 12.88 kGy/h, the F color center production was independent of the quantity of Pb2+, and varied according to the ratio KCl/KBr. At a proportion of 50% of each halogen the typical stages were observed. However, if the dose rate is less than 3.22 kGy/h, the coloration production depends on the quantity of Pb2+. 相似文献
108.
Omar De la Cruz Eric Hall Paul Howard Kyriakos Keremedis Jean E. Rubin 《Mathematical Logic Quarterly》2003,49(1):57-71
This is a continuation of [2]. We study the Tychonoff Compactness Theorem for various definitions of compactness and for various types of spaces (first and second countable spaces, Hausdorff spaces, and subspaces of ?K). We also study well ordered Tychonoff products and the effect that the multiple choice axiom has on such products. 相似文献
109.
María E. Noble-Terán Dr. José-Manuel Cruz Dr. Hugo I. Cruz-Rosas Dr. Thomas Buhse Dr. Jean-Claude Micheau 《Chemphyschem》2023,24(18):e202300318
Attrition-enhanced chiral symmetry breaking in crystals, known as Viedma deracemization, is a promising method for converting racemic solid phases into enantiomerically pure ones under non-equilibrium conditions. However, many aspects of this process remain unclear. In this study, we present a new investigation into Viedma deracemization using a comprehensive kinetic rate equation continuous model based on classical primary nucleation theory, crystal growth, and Ostwald ripening. Our approach employs a fully microreversible kinetic scheme with a size-dependent solubility following the Gibbs–Thomson rule. To validate our model, we use data from a real NaClO3 deracemization experiment. After parametrization, the model shows spontaneous mirror symmetry breaking (SMSB) under grinding. Additionally, we identify a bifurcation scenario with a lower and upper limit of the grinding intensity that leads to deracemization, including a minimum deracemization time within this window. Furthermore, this model uncovers that SMSB is caused by multiple instances of concealed high-order autocatalysis. Our findings provide new insights into attrition-enhanced deracemization and its potential applications in chiral molecule synthesis and understanding biological homochirality. 相似文献
110.
We consider a mixture of two immiscible oppositely charged molecules strongly adsorbed to an interface, with a neutral nonselective molecular background. We determine the coexistence between a high density ionic periodic phase and a dilute isotropic ionic phase. We use a strong segregation approach for the periodic phase and determine the one-loop free energy for the dilute phase. Lamellar and hexagonal patterns are calculated for different charge stoichiometries of the mixture. Molecular dynamics simulations exhibit the predicted phase behavior. The periodic length scale of the solid phase is found to scale as epsilon/(lB psi3/2), where psi is the effective charge density, lB is the Bjerrum length, and epsilon is the cohesive energy. 相似文献