Properties of In situ polymerized poly(3,4‐ethylenedioxythiophene)/alumina composites for energy storage applications

Composites formed by poly(3,4‐ethylenedioxythiophene) and alumina (PEDOT/Al₂O₃) have been prepared by in situ anodic polymerization. For this purpose, the stability of 1:1 and 4:1 monomer:alumina aqueous solutions has been examined as a function of the pH (2.3, 4.0, 7.0, 8.8, or 10.8). Results indicate that the monomer behaves as a dispersant that remains stable at the studied basic pHs despite they are close to the isoelectric point of alumina. Although the thermal stability of the composites is considerably affected by the pH of the reaction medium, its influence on the surface morphology is very small. Independently, of the synthetic conditions, the electrochemical properties were better for PEDOT/Al₂O₃ than for pure PEDOT, reflecting that alumina particles promote the charge mobility. The highest specific capacitance (SC; 141 F/g), which was 55% higher than that obtained for pure PEDOT, was achieved for the composite prepared at pH = 8.8 using a 4:1 monomer:alumina ratio. These conditions favor the participation of OH^– groups as secondary doping agents without degrading the polymer matrix and enhance the specific surface of the films, facilitating the ionic mobility. On the other hand, application of a multi‐step polymerization strategy has shown that interfaces originated by consecutive steps enhance the SC. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1131–1141     

SU(1,1) Coherent States for Position-Dependent Mass Singular Oscillators

The Schr?dinger equation for position-dependent mass singular oscillators is solved by means of the factorization method and point transformations. These systems share their spectrum with the conventional singular oscillator. Ladder operators are constructed to close the su(1,1) Lie algebra and the involved point transformations are shown to preserve the structure of the Barut-Girardello and Perelomov coherent states.     

Restructuring of force networks

The compaction of granular packings or soils is a collective process which for higher densities becomes increasingly slower reaching glassy behaviour. We present a study of this problem from various points of view, in particular we will represent the evolving force network that percolates through the system by an inverse fiber rupture model. Received 15 March 2002 and Received in final form 29 July 2002     

Comparative study of epithelial and fibroblastic cell lines as an alternative cytotoxicity test to the Draize method

Several methods are being used with considerable advantage as alternatives to the Draize test, although some technical difficulties still persist. This work compared the sensitivity of HeLa and NCTC L 929 cells to evaluate the cytotoxicity of shampoos used by adults and children (undiluted and diluted to 25, 5, 1, and 0.1%), and eye drops and their containers and surfactants (diluted to 30, 10, 1, and 0.1%). Nondiluted adult shampoos and their 25 and 5% dilutions were cytotoxic for both cell lines. When diluted to 1%, only one of the shampoos was noncytotoxic, whereas among those diluted to 0.1%, only one was cytotoxic. Children's shampoos were cytotoxic when not diluted or diluted to 25%. From those diluted to 5%, only one was noncytotoxic for both cell lines. The cytotoxic tests showed that the eye drops and their containers were noncytotoxic. Surfactants were cytotoxic when diluted to 30 and 10% and noncytotoxic when diluted to 1 and 0.1%. An excellent correlation (r = 0.95) was demonstrated between the sensitivity of the HeLa and NCTC L929 cells in the evaluation of cytotoxicity reactions.     

On the Stackelberg strategy in nonzero-sum games

The properties of the Stackelberg solution in static and dynamic nonzero-sum two-player games are investigated, and necessary and sufficient conditions for its existence are derived. Several game problems, such as games where one of the two players does not know the other's performance criterion or games with different speeds in computing the strategies, are best modeled and solved within this solution concept. In the case of dynamic games, linear-quadratic problems are formulated and solved in a Hilbert space setting. As a special case, nonzero-sum linear-quadratic differential games are treated in detail, and the open-loop Stackelberg solution is obtained in terms of Riccati-like matrix differential equations. The results are applied to a simple nonzero-sum pursuit-evasion problem.This work was supported in part by the US Air Force under Grant No. AFOSR-68-1579D, in part by NSF under Grant No. GK-36276, and in part by the Joint Services Electronics Program under Contract No. DAAB-07-72-C-0259 with the Coordinated Science Laboratory, University of Illinois, Urbana, Illinois.     

Electrical resistance of epitaxial crystalline films of (SN)x

The electrical resistance of oriented (SN)_x-films has been measured from 300 to 0.07 K. The results indicate a finite intrinsic conductivity in the direction perpendicular to the chains, supporting that (SN)_x is a strong anisotropic conductor rather than a quasi-one-dimensional system.     

Surface normal regions in superconducting Zr70Cu30 induced by thermal relaxation

Penetration depth measurements show that thermal heat treatment in amorphous Zr₇₀Cu₃₀ induces a normal region 5000 Å thick at the surface of ultrarapid quenched ribbons. Upper critical field measurements indicate that the new induced phase is a normal one while the rest of the sample remains as a homogeneous superconducting phase.     

A critical study of the application of graphite-furnace non-flame atomic absorption spectrometry to the deter-mination of trace base metals in complex heavy-matrix sample solutions

Because of the extravagant claims made for the usefulness of non-flame atomic absorption spectroscopy, a critical evaluation of its performance in heavy matrix solutions, for selected trace heavy metals, was made. Studies of physical and chemical interference problems are presented for a range of inorganic and organic matrices. Often quoted remedies (e.g. selective volatilization, standard addition etc.) for solution of the more serious problems were found to be of little help in most cases. The influence of variables such as nature and flow rate of purge gas, ashing temperature and atomization temperature are also evaluated. Analyses for Cd, Cu, Pb, Zn, Ni, Co were done on samples by flame and nonflame methods in high solids solutions. While there appears to be an advantage to the non-flame method in dealing with sample solutions of high organic content, no advantage is apparent for either technique with highly inorganic matrices.