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121.
D. F. Ruppert Ph. K. Hopke P. Clute W. Metzger D. Crowley 《Journal of Radioanalytical and Nuclear Chemistry》1974,23(1-2):159-169
In order to describe the occurrence and to investigate the sources of arsenic found in Chautauqua Lake sediments, 98 grab
samples have been analyzed by neutron activation analysis. The arsenic concentrations were found to range from <0.5 to 58.75
ppm for 96 of the 98 samples with an overall average value of 22.10 ppm. The two other samples had concentrations of 140.0
and 306.0 ppm. High arsenic concentrations have been positively correlated with a decrease in the sediment particle size.
Natural arsenic concentrations found in the soil and bedrock in the area do not explaint the observed concentrations in the
lake sediment. The increase in arsenic appears to be related to the spraying of sodium arsenite as an aquatic pesticide during
the period 1955–1963. 相似文献
122.
V. Z. Goldberg W. H. Trzaska G. V. Rogachev J. J. Kolata A. Andreyev C. Angulo M. J. G. Borge S. Cherubini G. Chubarian G. Crowley A. S. Fomichev M. Gorska M. Gulino M. S. Golovkov M. Huyse K. -M. Källman M. Lattuada T. Lönnroth M. Mutterer R. Raabe A. M. Rodin S. Romano M. V. Rozhkov B. B. Skorodumov C. Spitaleri O. Tengblad G. M. Ter-Akopian A. Tumino P. Van Duppen R. Wolski 《Acta Physica Hungarica A》2003,18(2-4):215-222
We consider various possibilities for studies of nuclear structure in resonance reactions induced by radioactive beam. We discuss investigations on both sides of nuclear stability as well as studies of the α-cluster structure of light nuclei applying the reverse geometry thick target method. 相似文献
123.
Roan A. S. Vasdev Dr. James A. Findlay Dr. David R. Turner Prof. James D. Crowley 《化学:亚洲杂志》2021,16(1):39-43
A new ferrocene-containing [Pd3( L4EFc )6]6+(X−)6 ( C ⋅ BF4 and C ⋅ SbF6 where X=BF4− or SbF6−) self-assembled double-walled triangle has been synthesized from the known, rotationally flexible, 1,1′-bis(4-pyridylethynyl)ferrocene ligand ( L4EFc ), and characterized by 1H, 13C and diffusion ordered (DOSY) NMR spectroscopies, high-resolution electrospray ionization mass spectrometry (HR−ESI−MS), X-ray crystallography and cyclic voltammetry (CV). The molecular structures confirmed that double-walled triangle cage systems ( C ⋅ BF4 and C ⋅ SbF6 ) were generated. C ⋅ BF4 was shown to interact with the anionic guest, p-toluenesulfonate. CV experiments revealed that the triangles were redox active, however addition of the guest did not influence the redox potentials. 相似文献
124.
Microscale Crystals of Cytochrome c and Calixarene on Electrodes: Interprotein Electron Transfer between Defined Sites 下载免费PDF全文
Dr. Róise E. McGovern Dr. Sven C. Feifel Prof. Dr. Fred Lisdat Dr. Peter B. Crowley 《Angewandte Chemie (International ed. in English)》2015,54(21):6356-6359
The assembly of redox proteins on electrodes is an important step in biosensor development. Recently, p‐sulfonato‐calix[4]arene was shown to act as “molecular glue” for the assembly and crystallization of cytochrome c (cyt c). Electrochemical data are presented for microscale cyt c–calixarene crystals grown on self‐assembled monolayers (SAM)‐modified Au electrodes. The crystals were characterized by cyclic voltammetry and exceptionally high concentrations of electroactive cyt c were obtained. The peak currents were found to increase linearly with the square root of the scan rate, thus allowing an evaluation of the rate constant for electron self‐exchange. This study revealed high electroactivity accompanied by fast interprotein electron transfer in crystals, which may have implications for the construction of novel bioelectronic devices. 相似文献
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Electron spectra resulting from collisions of thermal 23S metastable helium atoms with HF, HCl, HBr and HI are compared with the respective 584 相似文献
130.
Methyl-2-phenylethylpolysiloxane polymers have been synthesized for comparison with methylphenylpolysiloxane stationary phases for gas chromatography. The 50% 2-phenylethyl polysiloxane was found to be autocrosslinkable at 260°C without addition of free redical initiator. Although the selectivity of this phase appears to be similar to the 50% phenyl polysiloxane, its thermal stability is not as high. 相似文献