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911.
    
Five new lanthanide(III) sandwich and half-sandwich complexes with bulky cyclooctatetraenyl ligands have been prepared and fully characterized, including single-crystal X-ray structure determination. The treatment of anhydrous lanthanide(III) chlorides, LnCl3 (Ln = Pr, Tb, Yb), with 2 equivalents of Li2COT′′ [COT′′ = 1,4-bis(trimethylsilyl)cyclooctatetraene dianion] followed by crystallization in the presence of a coordinating solvent afforded the anionic sandwich complexes [Li(THF)4][Pr(COT′′)2] (1), [Li(DME)3][Tb(COT′′)2] (2; DME = 1,2-dimethoxyethane), and [Li(TMEDA)2][Yb(COT′′)2] (3; TMEDA = N,N,N′,N′-tetramethylethylenediamine). Attempted oxidation of 2 with silver iodide did not afford the neutral terbium(IV) sandwich complex [Tb(COT′′)2]. Instead, the tri(µ-iodido)-bridged dinuclear half-sandwich complex [Li(DME)2][Tb2(µ-I)3(COT′′)2] (4) was isolated in 72 % yield. In this complex, the Li(DME)2 fragment is attached to one of the µ-iodido ligands. A closely related binuclear lutetium complex, [Li(DME)3][Lu2(µ-Cl)3(COTbig)2]·DME (5), was obtained by using the “superbulky“ COTbig ligand [COTbig = 1,4-bis(triphenylsilyl)cyclooctatetraenyl dianion]. In addition to the spectroscopic and structural characterization, the magnetic properties of the paramagnetic terbium(III) derivative 2 have been investigated and further complemented by ab initio computational methods. These results have been used to discuss the structural requirements for potential terbium(III) single-ion magnets.  相似文献   
912.
913.
    
In this study, we successfully report an intimate ternary blend system of polycarbonate (PC)/poly(methyl methacrylate) (PMMA)/poly(vinyl acetate) (PVAc) obtained by the simultaneous coalescence of the three guest polymers from their common γ‐cyclodextrin (γ‐CD) inclusion compound (IC). The thermal transitions and the homogeneity of the coalesced ternary blend were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The observation of a single, common glass transition strongly suggests the presence of a homogeneous amorphous phase in the coalesced ternary polymer blend. This was further substantiated by solid‐state 13C NMR observation of the T(1H)s for each of the blend components. For comparison, ternary blends of PC/PMMA/PVAc were also prepared by traditional coprecipitation and solution casting methods. TGA data showed a thermal stability for the coalesced ternary blend that was improved over the coprecipitated blend, which was phase‐segregated. The presence of possible interactions between the three polymer components was investigated by infrared spectroscopy (FTIR). The analysis indicates that the ternary blend of these polymers achieved by coalescence from their common γ‐CD–IC results in a homogeneous polymer blend, possibly with improved properties, whereas coprecipitation and solution cast methods produced phase separated polymer blends. It was also found that control of the component polymer molar ratios plays a key role in the miscibility of their coalesced ternary blends. Coalescence of two or more normally immiscible polymers from their common CD–ICs appears to be a general method for obtaining well‐mixed, intimate blends. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4182–4194, 2004  相似文献   
914.
    
Summary: Dissociation energy and hydration energy calculations, in water solution, are presented for saline bonds mediated by Ca2+ and Mg2+ ions with Brőnstedt type bases ( COO ,  OSO3 ,  OH). A computationally intensive method, Polarisable Continuum Model (PCM) using 6-31G* basis set, was applied. Hydration energies were computed by various methods, as well as dissociation energies of some L2M complexes. L2Ca complexes result as more stable against dissociation than L2Mg complexes. Hydration energy calculation results, for some of the methods, here used, seem rather reliable as compared to experimental results.  相似文献   
915.
We build upon ideas developed in [9], as well as results of Greither on a strong form of Brumers Conjecture ([2]–[4]), and prove Rubins integral version of Starks Conjecture for imaginary abelian extensions of Q of odd prime power conductor.Mathematics Subject Classification (1991): 11R42, 11R58, 11R27Research on this project was partially supported by NSF grants DMS–9801267 and DMS–0196340Revised version: 11 October 2002  相似文献   
916.
Two different types of erbium-doped silicon nanocrystals, along with undoped, oxide-capped Si dots, are employed to probe the impact of the impurity center location on phase transition pressure. Using a combination of high pressure optical absorption, micro-Raman, and x-ray diffraction measurements in a diamond anvil cell, it is demonstrated that the magnitude of this phase transition elevation is strongly dictated by the average spatial location of impurity centers introduced into the nanocrystal along with the interfacial quality of the surrounding oxide.  相似文献   
917.
Finite automata have been recently used as alternative, discrete models in theoretical physics, especially in problems related to the dichotomy between endophysical/intrinsic and exophysical/ extrinsic perception (see, for instance [3, 6, 18–21]). These studies deal with Moore experiments; the main result states that it is impossible to determine the initial state of an automaton, and, consequently, a discrete model of Heisenberg uncertainty has been suggested. For this aim the classical theory of finite automata — which considers automata with initial states — is not adequate, and a new approach is necessary. A study of finite deterministic automata without initial states is exactly the aim of this paper. We will define and investigate the complexity of various types of simulations between automata. Minimal automata will be constructed and proven to be unique up to an isomorphism. We will build our results on an extension of Myhill-Nerode technique; all constructions will make use of “automata responses” to simple experiments only, i.e., no information about the internal machinery will be considered available.  相似文献   
918.
Phenoxarsin-10-yl derivatives of 2-amino-cyclopent-1-ene-1-carbodithioic acid, (ACDA), and its N-alkyl derivativesO(C6H4)2 AsS2C—C5H6— NHR-2 (R = H, CH2CH3, CH2C6H11,), have been prepared by reacting O(C6H4)2AsCI with the corresponding ACDA 1,1-dithioic acid. The compounds were obtained by stirring stoichiometric amounts of the reagents in ethanol, over 24 h, at room temperature. The scale of the preparations were in the order of 2 mmol and the yields of the compounds ca 75%. The reactions were carried out in absolute ethanol. The compounds were characterized by IR, mass and NMR (1H, 13C) spectroscopy. The molecular structure of O(C6H4)2AsS2C—C5H6—NH2-2 was determined using X-ray diffractometry, achieving an R-value of 6.3%; this compound is monomeric and contains an asymmetric monometallic biconnective 1,1-dithiolato ligand [As—S(1) 2.272(2) å, As … S(2) 3.125(2) å]. An intramolecular hydrogen bond is established between one hydrogen atom of the NH2 group and the sulfur [S(2)] atom involved in the secondary interaction to arsenic. The dihedral angle (150.3(3)°) of the phenoxarsine moiety is practically unaffected by substitution of chlorine on arsenic by the carbodithioato ligand.  相似文献   
919.
920.
Macdonald defined an involution on symmetric functions by considering the Lagrange inverse of the generating function of the complete homogeneous symmetric functions. The main result we prove in this note is that the images of skew Schur functions under this involution are either Schur positive or Schur negative symmetric functions. The proof relies on the combinatorics of Lagrange inversion. We also present a q-analogue of this result, which is related to the q-Lagrange inversion formula of Andrews, Garsia, and Gessel, as well as the operator of Bergeron and Garsia.  相似文献   
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