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61.
An investigation of inclusivepp→π?+? in terms of the covariant Boltzmann factor (BF) including the chemical potential μ indicates a) that the temperatureT increases less rapidly than expected from Stefan's law, b) that a scaling property holds for the fibreball velocity of π? secondaries, leading to a multiplicity law like ~E cm 1/2 at high energy, and c) that μπ is related to the quark mass: μπ=2m q ?m π the quark massm q determined by \(T_{\pi ^ - } \) at \(\bar pp\) threshold beingm q =3Tπ?330 MeV. Because ofthreshold effects \(T_{\bar p}< T_{\pi ^ - } \) , whereas \({{\mu _p } \mathord{\left/ {\vphantom {{\mu _p } {\mu _{\pi ^ - } }}} \right. \kern-0em} {\mu _{\pi ^ - } }} \simeq {3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-0em} 2}\) as expected from the quark contents of \(\bar p\) and π. The antinuclei \(\bar d\) and \({{\bar t} \mathord{\left/ {\vphantom {{\bar t} {\overline {He^3 } }}} \right. \kern-0em} {\overline {He^3 } }}\) observed inpp events are formed by coalescence of \(\bar p\) and \(\bar n\) produced in thepp collision. Semi-empirical formulae are proposed to estimate multiplicities of π?, \(\bar p\) and antinuclei. 相似文献
62.
L. C. Bland F. Bieser R. L. Brown H. J. Crawford A. A. Derevshchikov J. L. Drachenberg J. Engelage L. Eun C. A. Gagliardi S. Heppelmann E. G. Judd V. I. Kravtsov Yu A. Matulenko A. P. Meschanin D. A. Morozov L. V. Nogach S. B. Nurushev A. Ogawa C. Perkins G. Rakness K. E. Shestermanov A. N. Vasiliev 《The European Physical Journal C - Particles and Fields》2005,43(1-4):427-435
Comparisons of particle production from high-energy ion collisions with next-to-leading order perturbative QCD calculations show good agreement down to moderate transverse momentum values. Distributions of azimuthal angle differences between coincident hadrons in these collisions support a partonic origin to the particle production, again down to moderate transverse momentum values. The rapidity dependence of inclusive and coincident particle production can therefore be used to probe parton distribution functions down to small momentum fractions where theory anticipates that parton saturation could be present. This paper describes how such experiments could be completed.Arrival of the final proofs: 27 July 2005PACS:
12.38 Qk, 13.88. + e, 24.85. + p 相似文献
63.
K. S. Sharma R. C. Barber J. E. Crawford J. K. P. Lee R. B. Moore F. Buchinger E. Hagberg J. C. Hardy V. T. Koslowsky G. Savard 《Hyperfine Interactions》1993,81(1-4):217-222
The proposed Penning trap mass spectrometer, to be located at the TASCC facility of the Chalk River Laboratories, is described. The facility will be used for precise atomic mass determinations among both stable and unstable nuclides. The unstable nuclides would be produced in heavy ion reactions using the TASCC facility. The products from these reactions would be collected using an He-jet transport system loaded with NaCl aerosols. After transport to a background free area, the nuclides of interest would be laser desorbed and resonantly ionized. Subsequently, these ions would be accumulated in a Paul trap, cooled and injected into a precision Penning trap mass spectrometer for mass analysis. 相似文献
64.
65.
We have performed computational shock-physics simulations of the hypervelocity (60 km/s) impact of 1–3 km, water-ice spheres entering a hydrogen-helium Jovian atmosphere. These conditions simulate the best current estimates for the collision of fragments of periodic comet Shoemaker-Levy 9 with Jupiter in July, 1994. We used the Eulerian shock-physics code CTH, and its parallel version PCTH to perform 2-D analyses of penetration and breakup, and 3-D analyses of the growth of the resulting fireball during the first 100 seconds after fragment entry. We can use our simulations to make specific predictions of the time interval between fragment entry and fireball arrival into line-of-sight from the earth. For a fragment larger than about 1 km, we believe that the time of fireball arrival above Jupiter's limb will be directly observable from earth. Measurements of this time by observers, in conjunction with our simulations, may allow mass of cometary fragments to be determined.This article was processed using Springer-Verlag TEX Shock Waves macro package 1.0 and the AMS fonts, developed by the American Mathematical Society. 相似文献
66.
Yanfei YangGaurav Arora Fernando A. FernandezJennifer D. Crawford Kazimierz SurowiecEun Kyung Lee Richard A. Bartsch 《Tetrahedron》2011,67(7):1389-1397
Two series of di-ionizable calix[4]arene-crown-5 isomers in the cone conformation are synthesized to probe the effect of the pendant acidic group location on their metal ion extraction properties. In one series, the ionizable groups are attached to the lower rim of the calix[4]arene scaffold, which orients them near the crown ether cavity. In the second series, the ionizable groups are connected to the upper rim positioning them away from the crown ether ring, but close to the hydrophobic pocket of the calix[4]arene unit. The metal ion extraction behaviors of the two series of ligands are compared in extractions of alkaline earth metal cations, Hg2+, and Pb2+. 相似文献
67.
Boehner CM Frye EC O'Connell KM Galloway WR Sore HF Dominguez PG Norton D Hulcoop DG Owen M Turner G Crawford C Horsley H Spring DR 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(47):13230-13239
The prevalence of the biaryl structural motif in biologically interesting and synthetically important molecules has inspired considerable interest in the development of methods for aryl-aryl bond formation. Herein we describe a novel strategy for this process involving the fluoride-free, palladium-catalysed cross-coupling of readily accessible aryldisiloxanes and aryl bromides. Using a statistical-based optimisation process, preparatively useful reaction conditions were formulated to allow the cross-coupling of a wide range of different substrates. This methodology represents an attractive, cost-efficient, flexible and robust alternative to the traditional transition-metal-catalysed routes typically used to generate molecules containing the privileged biaryl scaffold. 相似文献
68.
A theoretical study of the electronic structure of the photoactive yellow protein (PYP) model chromophore, para-coumaric acid (p-CA), is presented. Electronically excited states of the phenolate and carboxylate isomers of the deprotonated p-CA are characterized by high-level ab initio methods including state-specific and multistate multireference pertrubation theory (SS-CASPT2, and MS-CASPT2), equation-of-motion coupled-cluster methods with single and double substitutions (EOM-CCSD) and with an approximate account of triple excitations (CC3). We found that the two isomers have distinctly different patterns of ionization and excitation energies. Their excitation energies differ by more than 1 eV, in contradiction to the experimental report [Rocha-Rinza et al., J. Phys. Chem. A 113, 9442 (2009)]. The calculations confirm metastable (autoionizing) character of the valence excited states of both phenolate and carboxylate isomers of p-CA(-) in the gas phase. The type of resonance is different in the two forms. In the phenolate, the excited state lies above the detachment continuum (a shape resonance), whereas in the carboxylate the excited π→π(*) state lies below the π-orbital ionization continuum, but is above the states derived from ionization from three other orbitals (Feshbach resonance). The computed oscillator strength of the bright electronic state in the phenolate is higher than in the carboxylate, in agreement with Hu?ckel's model predictions. The analysis of photofragmentation channels shows that the most probable products for the methylated derivatives of the phenolate and carboxylate forms of p-CA(-) are CH(3), CH(2)O and CH(3), CH(2)O, CO(2), respectively, thus suggesting an experimental probe that may discriminate between the two isomers. 相似文献
69.
Fortenberry RC Huang X Francisco JS Crawford TD Lee TJ 《The Journal of chemical physics》2011,135(21):214303
The use of accurate quartic force fields together with vibrational configuration interaction recently predicted gas phase fundamental vibrational frequencies of the trans-HOCO radical to within 4 cm(-1) of experimental results for the two highest frequency modes. Utilizing the same approach, we are providing a full list of fundamental vibrational frequencies and spectroscopic constants for the cis-HOCO system in both radical and anionic forms. Our predicted geometrical parameters of the cis-HOCO radical match experiment and previous computation to better than 1% deviation, and previous theoretical work agrees equally well for the anion. Correspondence between vibrational perturbation theory and variational vibrational configuration interaction for prediction of the frequencies of each mode is strong, better than 5 cm(-1), except for the torsional motion, similar to what has been previously identified in the trans-HOCO radical. Among other considerations, our results are immediately applicable to dissociative photodetachment experiments which initially draw on the cis-HOCO anion since it is the most stable conformer of the anion and is used to gain insight into the portion of the OH + CO potential surface where the HOCO radical is believed to form, and we are also providing highly accurate electron binding energies relevant to these experiments. 相似文献
70.
Samuel Cheeseman Z. L. Shaw Jitraporn Vongsvivut Russell J. Crawford Madeleine F. Dupont Kylie J. Boyce Sheeana Gangadoo Saffron J. Bryant Gary Bryant Daniel Cozzolino James Chapman Aaron Elbourne Vi Khanh Truong 《Molecules (Basel, Switzerland)》2021,26(13)
Biofilms are assemblages of microbial cells, extracellular polymeric substances (EPS), and other components extracted from the environment in which they develop. Within biofilms, the spatial distribution of these components can vary. Here we present a fundamental characterization study to show differences between biofilms formed by Gram-positive methicillin-resistant Staphylococcus aureus (MRSA), Gram-negative Pseudomonas aeruginosa, and the yeast-type Candida albicans using synchrotron macro attenuated total reflectance-Fourier transform infrared (ATR-FTIR) microspectroscopy. We were able to characterise the pathogenic biofilms’ heterogeneous distribution, which is challenging to do using traditional techniques. Multivariate analyses revealed that the polysaccharides area (1200–950 cm−1) accounted for the most significant variance between biofilm samples, and other spectral regions corresponding to amides, lipids, and polysaccharides all contributed to sample variation. In general, this study will advance our understanding of microbial biofilms and serve as a model for future research on how to use synchrotron source ATR-FTIR microspectroscopy to analyse their variations and spatial arrangements. 相似文献