Experimental Analysis of the Turbulent Flow Behavior of a Textured Surface Proposed for Asymmetric Heat Exchangers

In this study the Stereoscopic Particle Image Velocimetry (S-PIV) technique was used to analyze the aerodynamic behavior of a textured surface. This textured surface is supposed to cover the inside of the hot wall of asymmetric heat exchangers. A high heat transfer coefficient and a low pressure drop are desired for the studied module receiver. The proposed textured geometry consists of an association of actuators (i.e., vortex generators) and riblets (used as vortex handlers). To determine the flow structure near the walls with good accuracy, an experiment was carried out in a large-scale boundary layer wind tunnel. The post-processing of the velocity fields obtained with the S-PIV technique allows us to obtain indicators of the pressure drop and of the heat transfer coefficient even if the stream is isothermal for these experiments. Nine riblet-actuator couples are studied and compared to the results obtained for an untextured surface. This work points out that the configuration including actuators and riblets of large dimensions is the best performing. This result is qualitatively validated by the analysis of the three components and two-dimensional averaged velocity fields.     

High-Lying Rotational Levels of Water: An Analysis of the Energy Levels of the Five First Vibrational States

As a continuation of the work carried out on the ground and (010) vibrational states of water (R. Lanquetin, L. H. Coudert, and C. Camy-Peyret, 1999, J. Mol. Spectrosc. 195, 54-57), rotational energy levels for these two states are revisited here and new accurate rotational energy levels are considered for the three next vibrational states, that is, the (020), (100), and (001) states. Experimental rotational energies, along with their uncertainties, are retrieved through analyses of already published data sets and of discharge and flame emission spectra. The maximum value of J for the obtained levels is 25 for the ground state, 21 for the (010) state, and 20 for the three next states. Based on the bending-rotation Hamiltonian approach (L. H. Coudert, 1997, J. Mol. Spectrosc. 181, 246-273), a new theoretical approach is proposed to calculate rotational energies in the five interacting vibrational states under consideration and is used to carry out an analysis of the experimental energies. Comparisons with other existing energy level data sets are also presented. Copyright 2001 Academic Press.     

Easy access to new heterocyclic systems: 1,4-oxazine and substituted 1,4-oxazines

In the course of our investigations on the synthesis of new nitrogen heterocyclic derivatives, we were interested in the synthesis and study of new 1,4-oxazine rings. To this aim, the desired bisvinylphosphate was prepared from N-Boc morpholine-3,5-dione and was then engaged in palladium-catalyzed reactions (reduction, Suzuki, and Stille cross-coupling reactions). The 1,4-oxazine and its corresponding 3,5-disubstituted derivatives were obtained in fair to good yields and were then functionalized under anionic conditions.     

In situ calibration of hot wire probes in turbulent flows

A method for in situ calibration of hot-wires in a turbulent flow is presented. The method is particularly convenient (even necessary) for calibrating large probe arrays, like the 143-wire boundary layer rake of the WALLTURB experiment. It is based on polynomial expansion of the velocity statistics in terms of voltage statistics as originally described by George et al. [Exp Ther Fluid Sci 2(2):230–235, 1989]. Application of the method requires knowing reference mean velocity and higher order central moments (with the array in place) of the turbulent velocity at the probe location at only one freestream velocity. These were obtained in our experiment by a stereo PIV plane just upstream of the probe array. Both the procedure for implementing the method and sample results are presented in the article.     

MOF Decomposition and Introduction of Repairable Defects Using a Photodegradable Strut

Photoswitchable components can modulate the properties of metal organic frameworks (MOFs); however, photolabile building blocks remain underexplored. A new strut NPDAC (2-nitro-1,4-phenylenediacetic acid) that undergoes photodecarboxylation has been prepared and incorporated into a MOF, using post-synthetic linker exchange (PSLE) from the structural analogue containing PDAC (p-phenylenediacetic acid). Irradiation of NPDAC-MOF leads to MOF decomposition and concomitant formation of amorphous material. In addition to complete linker exchange, MOFs containing a mixture of PDAC and NPDAC can be obtained through partial linker exchange. In NPDAC30-MOF, which contains approximately 30 % NPDAC, the MOF retains crystallinity after irradiation, but the MOF contains defect sites consistent with loss of decarboxylated NPDAC linkers. The defect sites can be repaired by exposure to additional PDAC or NPDAC linkers at a much faster rate than the initial exchange process. The photoremoval and replacement process may lead to a more general approach to customizable MOF structures.     

Analysis of the torsional spectrum of monodeuterated methanol CH2DOH

An analysis of the torsional spectrum of monodeuterated methanol CH(2)DOH is presented. Twenty nine torsional subbands have been assigned in the 20-800 cm(-1) region. The newly assigned subbands and those already available in the literature were analyzed with a theoretical approach accounting for internal rotation of an asymmetrical CH(2)D methyl group. Seventy six subband centers were reproduced with an rms value of 0.09 cm(-1). Spectroscopic parameters corresponding to the generalized inertia tensor and to the hindering potential were determined as well as rotation-torsion distortion constants.     

Full 3D correlation tensor computed from double field stereoscopic PIV in a high Reynolds number turbulent boundary layer

The turbulence structure near a wall is a very active subject of research and a key to the understanding and modeling of this flow. Many researchers have worked on this subject since the fifties Hama et al. (J Appl Phys 28:388–394, 1957). One way to study this organization consists of computing the spatial two-point correlations. Stanislas et al. (C R Acad Sci Paris 327(2b):55–61, 1999) and Kahler (Exp Fluids 36:114–130, 2004) showed that double spatial correlations can be computed from stereoscopic particle image velocimetry (SPIV) fields and can lead to a better understanding of the turbulent flow organization. The limitation is that the correlation is only computed in the PIV plane. The idea of the present paper is to propose a new method based on a specific stereoscopic PIV experiment that allows the computation of the full 3D spatial correlation tensor. The results obtained are validated by comparison with 2D computation from SPIV. They are in very good agreement with the results of Ganapthisubramani et al. (J Fluid Mech 524:57–80, 2005a).