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231.
Luca Chiodi Renata Mansini Maria Grazia Speranza 《Annals of Operations Research》2003,124(1-4):245-265
Investors consider mutual funds as an interesting investment opportunity. This is the result of the impressive growth shown by these financial products in recent times. In this paper we propose a mixed integer linear programming model dealing with the portfolio selection problem on mutual funds in a single period investment strategy. We propose some heuristics and compare their performance. According to the results obtained on real instances, heuristics have proved to be effective and efficient. 相似文献
232.
Maria Grazia CabidduEnzo Cadoni Stefania De MontisClaudia Fattuoni Stefana Melis Michele Usai 《Tetrahedron》2003,59(24):4383-4387
A re-examination of the methylenation reaction of 1-hydroxy-2-mercapto-, 1,2-dihydroxy- and 1,2-dimercapto-substituted benzenes by bromochloromethane with cesium carbonate shows that these substrates give mixtures of five- and ten-membered benzocondensed heterocyclic compounds and in some cases even dibenzodioxines. 相似文献
233.
Maria Grazia De Angelis Giulio Cesare Sarti Aldo Sanguineti Patrizia Maccone 《Journal of Polymer Science.Polymer Physics》2004,42(10):1987-2006
The permeation, diffusion, and sorption of dimethyl ether into a series of commercial fluoroelastomers were characterized at various pressures and temperatures. The polymers under study were based on tetrafluoroethylene and contained various amounts of other perfluorinated monomers: perfluoromethylvinylether, hexafluoropropylene, and a partially fluorinated monomer, vinylidene fluoride (VDF). These polymers were also filled with inorganic particles and cured with different techniques. The permeation rate of dimethyl ether in the elastomers examined, as well as the solubility value, increased as the content of the nonperfluorinated monomer (VDF) increased, and this was consistent with the solubility parameter theory. The diffusion coefficients, at a fixed concentration, had rather similar values for most of the elastomers examined. Both the permeability and diffusivity increased with temperature, and the corresponding activation energies were obtained for two selected polymers. The solubility of dimethyl ether, at a fixed temperature and activity, showed a linear dependence versus the weight fraction of the partially fluorinated monomer (VDF) in the polymeric matrix. The effect of the filler on the sorption and transport properties was also considered: the addition of the filler lowered the permeability and diffusivity, whereas the solubility was generally increased with respect to the crosslinked rubber. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1987–2006, 2004 相似文献
234.
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236.
Host–Guest Chemistry of Aromatic‐Amide‐Linked Bis‐ and Tris‐Calix[4]pyrroles with Bis‐Carboxylates and Citrate Anion
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Dr. Grazia Cafeo Dr. Giuseppe Gattuso Prof. Franz H. Kohnke Dr. Georgia Papanikolaou Dr. Aldo Profumo Dr. Camillo Rosano 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(6):1658-1668
A small library of polytopic receptors has been synthesized from meso‐p‐ and meso‐m‐aminophenylcalix[4]pyrroles and p‐ or m‐phthaloyl or trimesic chloride. Selected bis‐carboxylates and the citrate anion, which either exhibit altered distribution profiles in cancerous tissues in comparison with healthy tissues or are metabolites of carcinogenic substances (for example, trans,trans‐muconic acid from benzene exposure in humans) were tested as ligands. Varied affinities and binding modes were observed as a function of the number of calix[4]pyrroles and the topology of amide units present in each of the polytopic receptors. The structures of the 1:1 complexes derived by molecular modeling are in excellent agreement with the results of 1H NMR complexation studies. 相似文献
237.
Multiple headspace-solid phase microextraction (MHS-SPME) followed by gas chromatography/mass spectrometry (GC–MS) and flame ionization detection (GC–FID) was applied to the identification and quantification of volatiles released by the mushroom Agaricus bisporus, also known as champignon. MHS-SPME allows to perform quantitative analysis of volatiles from solid matrices, free of matrix interferences. Samples analyzed were fresh mushrooms (chopped and homogenized) and mushroom-containing food dressings. 1-Octen-3-ol, 3-octanol, 3-octanone, 1-octen-3-one and benzaldehyde were common constituents of the samples analyzed. Method performance has been tested through the evaluation of limit of detection (LoD, range 0.033–0.078 ng), limit of quantification (LoQ, range 0.111–0.259 ng) and analyte recovery (92.3–108.5%). The results obtained showed quantitative differences among the samples, which can be attributed to critical factors, such as the degree of cell damage upon sample preparation, that are here discussed. Considerations on the mushrooms biochemistry and on the basic principles of MHS analysis are also presented. 相似文献
238.
Darwin Toledo Arnau Cordomí Maria Grazia Proietti Maurizio Benfatto Luis J. Del Valle Juan J. Pérez Pere Garriga Francesc Sepulcre 《Photochemistry and photobiology》2009,85(2):479-484
For the first time to our knowledge, X‐ray absorption spectroscopy (XAS) has been used to investigate the environment of putative Zn2+ binding sites in rhodopsin. We studied native purified nondeionized rhodopsin without any further addition of Zn2+, as well as with 1.5 mol of Zn2+—as zinc chloride—per mole of protein. Three different binding sites in rhodopsin were considered based on computational chemistry studies, and a quantitative analysis of the XAS signal was performed by fitting the experimental data to their simulated XAS spectra. Our results demonstrate that Zn2+ is intrinsically bound to rhodopsin and are compatible with the existence of an octahedral coordination involving six oxygen atoms in the first shell (average Zn‐O distance of 2.08 Å), and with a second coordination shell containing one or two phosphorus or sulfur atoms at an average distance of 2.81 Å. 相似文献
239.
Carlos Calle Anandaram Sreekanth MatveyV. Fedin Jrg Forrer Ins Garcia‐Rubio IgorA. Gromov Dariush Hinderberger Besnik Kasumaj Patrick Lger Bruno Mancosu George Mitrikas MariaGrazia Santangelo Stefan Stoll Arthur Schweiger Ren Tschaggelar Jeffrey Harmer 《Helvetica chimica acta》2006,89(10):2495-2521
This review discusses the application of pulse EPR to the characterization of disordered systems, with an emphasis on samples containing transition metals. Electron nuclear double‐resonance (ENDOR), electron‐spin‐echo envelope‐modulation (ESEEM), and double electron–electron resonance (DEER) methodologies are outlined. The theory of field modulation is outlined, and its application is illustrated with DEER experiments. The simulation of powder spectra in EPR is discussed, and strategies for optimization are given. The implementation of this armory of techniques is demonstrated on a rich variety of chemical systems: several porphyrin derivatives that are found in proteins and used as model systems, otherwise highly reactive aminyl radicals stabilized with electron‐rich transition metals, and nitroxide–copper–nitroxide clusters. These examples show that multi‐frequency continuous‐wave (CW) and pulse EPR provides detailed information about disordered systems. 相似文献
240.
We prove that certain integers n cannot occur as degrees of linear series without base points on the normalization of a plane
curve whose only singularities are a “small” number of nodes and ordinary cusps. As a consequence we compute the gonality
of such a curve.
Work done with financial support of M.U.R.S.T. while the authors were members of C.N.R. 相似文献