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Stella K. Papadopoulou Ioannis Karapanagiotis Costas Panayiotou 《European Polymer Journal》2010,46(2):202-78
A fluorinated methacrylic homopolymer, poly(2,2,3,3,3-pentafluoropropyl methacrylate) (PPFPMA) was synthesized by a free radical polymerization reaction. The dispersive component of the surface energy () of PPFPMA was determined by contact angle measurements and inverse gas chromatography (IGC). An extensive surface characterization was conducted by means of IGC. Surface characterization demonstrated that PPFPMA has low value, even at 35 °C and is a Lewis amphoteric polymer with predominantly basic character, as confirmed by the Lewis acidity and basicity constants KA and KB, respectively. The values of obtained by IGC are slightly higher than those obtained by the contact angle method. This trend can be attributed to the fact that IGC evaluates, primarily, high energy sites of a surface. 相似文献
83.
Company A Lamata D Poater A Solà M Rybak-Akimova EV Que L Fontrodona X Parella T Llobet A Costas M 《Inorganic chemistry》2006,45(14):5239-5241
Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation. 相似文献
84.
The initial value problem solution of the nonlinear shallow water-wave equations is developed under initial waveforms with and without velocity. We present a solution method based on a hodograph-type transformation to reduce the nonlinear shallow water-wave equations into a second-order linear partial differential equation and we solve its initial value problem. The proposed solution method overcomes earlier limitation of small waveheights when the initial velocity is nonzero, and the definition of the initial conditions in the physical and transform spaces is consistent. Our solution not only allows for evaluation of differences in predictions when specifying an exact initial velocity based on nonlinear theory and its linear approximation, which has been controversial in geophysical practice, but also helps clarify the differences in runup observed during the 2004 and 2005 Sumatran tsunamigenic earthquakes. 相似文献
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Koehntop KD Rohde JU Costas M Que L 《Dalton transactions (Cambridge, England : 2003)》2004,(20):3191-3198
Peroxo intermediates are implicated in the catalytic cycles of iron enzymes involved in dioxygen metabolism. X-ray absorption spectroscopy has been used to gain insight into the iron coordination environments of the low-spin complex [Fe(III)(Me-TPEN)(eta(1)-OOH)](2+)(1) and the high-spin complex [Fe(III)(Me-TPEN)(eta(2)-O(2))](+)(2)(the neutral pentadentate N-donor ligand Me-TPEN =N-methyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine) and obtain metrical parameters unavailable from X-ray crystallography. The complexes exhibit relatively large pre-edge peak areas of approximately 15 units, indicative of iron centers with significant distortions from centrosymmetry. These distortions result from the binding of peroxide, either end-on hydroperoxo for 1 (r(Fe-O)= 1.81A) or side-on peroxo for 2 (r(Fe-O)= 1.99 A). The XAS analyses of 1 strongly support a six-coordinate low-spin iron(III) center coordinated to five nitrogen atoms from Me-TPEN and one oxygen atom from an end-on hydroperoxide ligand. However, the XAS analyses of 2 are not conclusive: Me-TPEN can act either as a pentadentate ligand to form a seven-coordinate peroxo complex, which has precedence in the DFT geometry optimization of [Fe(III)(N4Py)(eta(2)-O(2))](+)(the neutral pentadentate N-donor ligand N4Py =N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine), or as a tetradentate ligand with a dangling pyridylmethyl arm to form a six-coordinate peroxo complex, which is precedented by the crystal structure of [Fe(2)(III)(Me-TPEN)(2)(Cl)(2)(mu-O)](2+). 相似文献
87.
Optimized structures and total molecular energy density functional theory calculations for the 14 possible neutral allopurinol tautomers give the decreasing stability order for the three most stable forms. Several molecular and electronic structure properties, the stabilities in oxidation and reduction processes, the tautomeric equilibrium constants, and the IR vibrational spectra were obtained for these. Those properties corresponding to the ketonic forms are discussed and compared with the theoretical ones for the two most stable species of the isomer hypoxanthine. A noticeable agreement is found between the predicted properties and the experimental behavior known up to date for both isomers. ©1999 John Wiley & Sons, Inc. J Comput Chem 20: 200–206, 1999 相似文献
88.
Costas S. Patrickios Clive Forder Steven P. Armes Norman C. Billingham 《Journal of polymer science. Part A, Polymer chemistry》1996,34(8):1529-1541
Water-soluble diblock copolymers of methyl tri(ethylene glycol) vinyl ether (hydrophilic block) and isobutyl vinyl ether (hydrophobic block) of different molecular weights and composition were synthesized by living cationic polymerization. The molecular weight and comonomer composition of these copolymers were determined by GPC and 1H NMR spectroscopy, respectively. Aqueous solutions of the copolymers were characterized in terms of their micellar behavior using dynamic light scattering, aqueous GPC, and dye solubilization. All the copolymers formed aggregates with the exception of a diblock copolymer with only two hydrophobic monomer units. The micellar hydrodynamic size scaled with the 0.61 power of the number of hydrophobic units, in good agreement with a theoretical exponent of 0.73. An increase in the length of the hydrophobic block at constant hydrophilic block length or an increase in the overall polymer size at constant block length ratio both resulted in lower critical micelle concentrations (cmcs). The cloud points of 1% w/w aqueous solutions of the polymers were determined by turbidimetry. An increase in the length of the hydrophobic block at constant hydrophilic block length caused a decrease in the cloud points of the copolymers. However, an increase in the overall polymer size at constant block length ratio led to an increase in the cloud point. © 1996 John Wiley & Sons, Inc. 相似文献
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