Rheological and Electrical Properties of Oxidized Carbon Black Suspensions in Vaseline Oil under Shear and Vibration

The results of investigations of the rheological characteristics and electrical resistance of the suspensions of carbon black in vaseline oil under the effects of shear and vibration were presented. The investigations are carried out on an original unit that allowed one to simultaneously subject the suspensions to shear deformation and orthogonal vibration. The electrical resistance was also measured in an ac pulsed low-voltage mode. Possible mechanisms of the suspension conductivity were considered depending on the regime of dynamic action.     

Closed-form solutions for a rectangular layer with central crack under anti-plane shear stress

We consider the problem of determining the stress distributionin a finite rectangular elastic layer containing a Griffithcrack which is opened by internal shear stress acting alongthe length of the crack. The mode III crack is assumed to belocated in the middle plane of the rectangular layer. The followingtwo problems are considered: (A) the central crack is perpendicularto the two fixed lateral surfaces and parallel to the othertwo stress-free surfaces; (B) all the lateral surfaces of therectangular layer are clamped and the central crack is parallelto the two lateral surfaces. By using Fourier transformations,we reduce the solution of each problem to the solution of dualintegral equations with sine kernels and a weight function whichare solved exactly. Finally, we derive closed-form expressionsfor the stress intensity factor at the tip of the crack andthe numerical values for the stress intensity factor at theedges of the cracks are presented in the form of tables.     

Reaction of 3,3,3-trifluoropropene-1 with bromoform and methylene bromide

The radical telomerization of 3,3,3-trifluoropropene with bromoform and methylens bromide has been studied. The nature of the products with bromoform depends substantially on the method of initiation. In the presence of Fe(CO)₅ + DMF, telomers of CHBr₂(CH₅₂CHCF₃)_nBr are formed, while with initiation with benzoyl peroxide other compounds are also formed that contain two, three, or four bromine atoms per molecule. To elucidate the formation of these products a reaction scheme is proposed that involves rearrangement of CHBr₂CH₂CH(CF₃)CH₃CHCF₃ radicals to CBr₂CH₂CH(CF₃)CH₂CH₂CF₃ radicals.Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2558–2562, November, 1989.     

Determination of trace elements in Brazilian rice grains and in biological reference materials by neutron activation analysis

Instrumental neutron activation analysis was applied to the determination of the elements Na, K, Br, As, Rb, Zn, Co, Fe and Sc in Brazilian rice samples and in biological standards. Hg and Se concentrations were determined by using a simple radiochemical separation. The chemical procedure was carried out by means of distillation of Hg and Se in HBr medium and subsequent precipitation of selenium by sodium metabisulfite and mercury by thioacetamide. The accuracy of the instrumental and radiochemical methods was evaluated by means of analysis of the Reference Materials NBS-Bovine Liver, Bowen's Kale and NBS-Rice Flour.     

Effect of rare-earth oxides on the magnetic properties of anisotropic barium ferrites

The effect of rare-earth oxides on the properties of anisotropic barium ferrites has been studied by x-ray structural and Mössbauer methods. Additions of SrCO₃, as well as SrCO₃ and La₂O₃, SrCO₃ and Pr₆O₁₁, SrCO₃ and Nd₂O₃, SrCO₃ and Sm₂O₃ in amounts of 7.5 mole % Sr and 10 mole % rare-earth element to grade-A barium powder results in the substitution of barium ions by Sr and rare-earth ions; consequently, the energy of magnetic anisotropy changes and the technically important parameters B_r and (BH)_max increase.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 34–39, January, 1989.     

Structural relaxation time for various liquids

The structural relaxation time for series of various liquids (alkanes, aliphatic alcohols, and diols) are calculated from published data on the shear viscosity and the heat of evaporation per unit volume. Liquids having a 3D H-bond network (diols) are characterized by relaxation times one to two orders of magnitudes longer than those typical of liquids without such a network (alkanes and aliphatic alcohols).     

An algebra of meromorphic corner symbols

Operators on manifolds with corners that have base configurations with geometric singularities can be analysed in the frame of a conormal symbolic structure which is in spirit similar to the one for conical singularities of Kondrat'ev's work. Solvability of elliptic equations and asymptotics of solutions are determined by meromorphic conormal symbols. We study the case when the base has edge singularities which is a natural assumption in a number of applications. There are new phenomena, caused by a specific kind of higher degeneracy of the underlying symbols. We introduce an algebra of meromorphic edge operators that depend on complex parameters and investigate meromorphic inverses in the parameter-dependent elliptic case. Among the examples are resolvents of elliptic differential operators on manifolds with edges.     

Roles of rhenium diimine complexes as metal‐ion probes and photosensitizers in functional polyurethanes

Polyurethanes incorporated with rhenium diimine complexes were synthesized. The polymers exhibited interesting morphologies and solution properties. Results from gel permeation chromatography suggested the formation of polymer aggregates in solutions. The polymers could act as probes for metal ions. The addition of metal ions to polymer solutions led to significant changes in the electronic absorption properties of the polymer solutions. This was attributed to the interactions between the polyether moieties and metal ions. The metal complexes could also act as efficient photosensitizers. After doping with charge‐transport viologens, the photoconductivity of the polymers was greatly enhanced. The experimental quantum efficiency was simulated with Onsager's theory. The thermalization distances and the primary yields were typically 12–14 Å and 10^?3, respectively. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1708–1715, 2003     

Two-Variable Identities in Groups and Lie Algebras

We study two-variable Engel-like relations and identities characterizing finite-dimensional solvable Lie algebras and, conjecturally, finite solvable groups and introduce some invariants of finite groups associated with such relations. Bibliography: 29 titles.     

A transform method for linear evolution PDEs on a finite interval

We study initial boundary value problems for linear scalar evolutionpartial differential equations, with spatial derivatives ofarbitrary order, posed on the domain {t > 0, 0 < x <L}. We show that the solution can be expressed as an integralin the complex k-plane. This integral is defined in terms ofan x-transform of the initial condition and a t-transform ofthe boundary conditions. The derivation of this integral representationrelies on the analysis of the global relation, which is an algebraicrelation defined in the complex k-plane coupling all boundaryvalues of the solution. For particular cases, such as the case of periodic boundaryconditions, or the case of boundary value problems for even-orderPDEs, it is possible to obtain directly from the global relationan alternative representation for the solution, in the formof an infinite series. We stress, however, that there existinitial boundary value problems for which the only representationis an integral which cannot be written as an infinite series.An example of such a problem is provided by the linearized versionof the KdV equation. Similarly, in general the solution of odd-orderlinear initial boundary value problems on a finite intervalcannot be expressed in terms of an infinite series.