全文获取类型
收费全文 | 415篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 264篇 |
晶体学 | 10篇 |
力学 | 20篇 |
数学 | 81篇 |
物理学 | 49篇 |
出版年
2022年 | 3篇 |
2021年 | 7篇 |
2019年 | 3篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 8篇 |
2014年 | 6篇 |
2013年 | 22篇 |
2012年 | 11篇 |
2011年 | 23篇 |
2010年 | 14篇 |
2009年 | 18篇 |
2008年 | 18篇 |
2007年 | 26篇 |
2006年 | 13篇 |
2005年 | 13篇 |
2004年 | 12篇 |
2003年 | 9篇 |
2002年 | 15篇 |
2001年 | 3篇 |
1999年 | 8篇 |
1998年 | 3篇 |
1997年 | 7篇 |
1996年 | 13篇 |
1995年 | 8篇 |
1994年 | 15篇 |
1993年 | 10篇 |
1992年 | 7篇 |
1990年 | 9篇 |
1989年 | 11篇 |
1988年 | 6篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1975年 | 2篇 |
1970年 | 3篇 |
1969年 | 2篇 |
1967年 | 3篇 |
1948年 | 2篇 |
1918年 | 2篇 |
1910年 | 2篇 |
1887年 | 2篇 |
1884年 | 4篇 |
排序方式: 共有424条查询结果,搜索用时 15 毫秒
101.
102.
103.
Euro Solari Stefania De Angelis Mario Latronico Carlo Floriani Angiola Chiesi-Villa Corrado Rizzoli 《Journal of Cluster Science》1996,7(4):553-566
The function of the solvent in the self-assembling mode of [CuCl] with tetrahydrothiophene is reported. Copper(l) chloride has been used in the form of [CuCOCl]
n
, which is slightly soluble in the most common solvents, and to allow an homogeneous phase reaction. The reaction of [CuCOCl]
n
with THT gave [(CuCl)2(THT)3]
x
,1, in CH3OH, [(CuCl)(THT)2]
x
,2 in THF [(CuCl)(THT)]
x
,3, in CH2Cl2, and [(CuCl)3(THT)2]
x
,4, in DME. Compound1 consists of polymeric chains of centrosymmetric Cu2Cl2 dinuclear units bridged by THIT molecules running parallel to the [101] axis. In the structure of2 we found polymeric layers generated from the [(CuCl)(THT)] asymmetric unit by the center of symmetry and by the twofold axis. In compound3 the structure consists of layers generated through the center of symmetry by the [(Cu2Cl2)(THT)2] asymmetric unit, while4 consists of layers generated through the center of symmetry by the [(Cu3Cl3)(THT)2] asymmetric unit. Crystallographic details are as [ollows:2 is monoclinic, space group P21/c.a=9.657(3) A,b=6.441(2) A,c=11.459(3) A,\=111.96(2)°,V=661.0(4) A3. andR=0.075;3 is monoclinic, space group P21/n,a=19.327(7) A,b=6.703(2) A,c=10.116(3) A,ß=103.04(3)°,V=1276.7(7) A3 andR=0.043:4 is triclinic, space group Pl,a=12.513(2) A,b=6.698(1) A,c=9.651(1) A,=91.98(1)°,\=107.86(1)°,=74.59(1)°,V=741.2(2) A3, andR=0.044. 相似文献
104.
105.
Gabriele Bocelli Liberato Cardellini Giovanni De Meo Adolfo Ricci Corrado Rizzoli Giorgio Tosi 《Journal of chemical crystallography》1990,20(6):561-569
Benzofused heterocycles like 10H-[1]benzo thieno[3,2-b] indole and thieno[3,2-b]benzo[b]thiophene form molecular associations with * organic acceptors. The weak interactions involved are viewed in terms of UV-Vis and IR techniques. The results, mainly in the case of complexes of 10H-[1]benzo thieno[3,2-b] indole, are in some disagreement with the literature. The structure of the complex 10H-[1]benzo thieno[3,2-b] indole/tetracyanoethylene is also reported. The four condensed rings constitute a conjugate system with significant lengthenings of the aromatic ring bonds and a shortening of those of the five-membered rings. The fragment as a whole is almost planar, and forms a dihedral angle of 39.9(1)° with the planar tetracyanoethylene molecule. 相似文献
106.
It is shown that there are differentiable manifolds which can be characterized only by the geometric and topological structure of their linear subspaces. More precisely, such a characterization is possible for Grassmann and C. Segre's product manifolds. The starting point of this investigation was a paper by J. Misfeld, G. Tallini and the author [10], the ideas in which were further developed in [15,16,17].Dedicated to Professor Giuseppe Tallini on his 60th birthday 相似文献
107.
Mario Nardelli Corrado Pelizzi Glancarlo Pelizzi 《Journal of organometallic chemistry》1975,85(3):C43-C44
A compound of formula [SnII(NO3) [(C6H5)3 SnIV], containing a tin(IV)tin(II) bond, has been prepared, and its crystal structure is determined. 相似文献
108.
109.
Novel poly(arylene thioether)s were synthesised using the one pot polymerisation method from the bis(N,N-dimethyl-S-carbamate) of 2,2-bis(4-mercaptophenyl)propane and activated difluoro aromatic compounds. Each of the polymers, obtained in good yields and with fairly high molecular weights, were characterised by IR, GPC and NMR analyses. In particular, the NMR characterisation was performed using 1H NMR, 13C NMR, DEPT, 2D COSY and 2D HSQC experiments. To study the effect on the thermal properties of replacing the ethereal oxygen atoms with sulfur atoms, we have synthesised the counterparts, the poly(arylene ether)s, with similar molecular weights. We observed that the substitution of the ethereal oxygen atoms with sulfur atoms results in a slightly lower thermal stability for the poly(thioether ketone)s, both under nitrogen and in air, and does not modify the Tg values. For the poly(thioether sulfone), on the other hand, the thermal stability is equal to that of the poly(ether sulfone), while the Tg is 10 °C lower. Furthermore, each sample is completely amorphous, with the exception of one of the poly(thioether ketone)s (sample 1b), which shows the capacity to crystallise, even if with a very slow crystallisation kinetics. 相似文献
110.
Corrado Testa 《Analytica chimica acta》1970,50(3):447-455
Revised-phase partition chromatography is a very useful tool for selective isolation of radionuclides from biological materials. Some new applications of this technique to the resolution of practical problems in radiation protection are reported. Natural thorium and enriched uranium can be determined separately and together in urine by means of a column of Microthene-710 supporting a solution of tri-n-octyl-phosphine oxide (TOPO) in cyclohexane; batchwise extraction processes with Microthene supporting TOPO are also successful. Strontium-90 is determined in urine by a batch extraction of yttrium-90 with a slurry of Microthene supporting the liquid cation exchanger di-(2-ethylhexyl)phosphoric acid. Only a wet mineralization of the urines is required and the analyses are simple, rapid and sufficiently accurate. A method for the isolation of iodine from foodstuffs with a Microthene-benzene column is also described. 相似文献